Abstract: Provided are a thermoplastic polymer composition having excellent mechanical strength and also having both of abrasion resistance and transparency; shoes, in which the thermoplastic polymer composition is used; and an outer sole, in which the thermoplastic polymer composition is used. The thermoplastic polymer composition contains (I) a hydrogenated product of a block copolymer having a polymer block (A) mainly containing ?-methylstyrene units and a polymer block (B) mainly containing conjugated diene compound units; (II) a hydrogenated product of a block copolymer having a polymer block (A?) mainly containing aromatic vinyl compound units other than ?-methylstyrene and a polymer block (B?) mainly containing conjugated diene compound units, in which the block copolymer has a hydroxyl group; (III) a polypropylene-based polymer; and (IV) a polyethylene-based polymer.
Abstract: A resin composition includes a polyester resin, an alloyed resin of a polycarbonate resin and an acrylonitrile-butadiene rubber-styrene resin, and an acrylic block copolymer containing a polymer block containing an acrylic acid ester monomer unit and a polymer block containing a methacrylic acid ester monomer unit, wherein a weight ratio of a content of the polyester resin and a content of the alloyed resin is in a range of 5:95 to 50:50, and wherein a content of the acrylic block copolymer is in a range of 0.5% by weight to 10% by weight with respect to a total of the content of the polyester resin and the content of the alloyed resin.
Abstract: The invention relates to thermoplastic molding materials based on acrylonitrile-butadiene-styrene, comprising a SAN-polymer matrix and a graft copolymer, structured from an agglomerated rubber-graft base and a SAN-graft envelope. The basis of the graft base is a diene rubber having a vinyl-aromatic ratio of 10.5 to 24.5 wt %. The agglomerated graft base has a bimodal particle size distribution of a fraction x) of non-agglomerated particles having a d50-value in the range from 80 to 120 nm and a fraction y) of agglomerated particles having a d50-value in the range of 350 to 550 nm and a polydispersity U of less than 0.28. The invention further relates to a method for producing the graft copolymer, wherein an acrylate copolymer having a polydispersity U of less than 0.27 and a d50-value of 100 to 150 nm is used for agglomeration. The invention further relates to the use of thermoplastic molding materials for producing molded parts.
Type:
Grant
Filed:
April 16, 2014
Date of Patent:
April 18, 2017
Assignee:
INEOS STYROLUTION GROUP GMBH
Inventors:
Norbert Niessner, SangJun Ahn, Brian J. Banaszak, Roland Walker, Michel Pepers, Johannes Barth, Gisbert Michels, Florian Patcas, YoungHwa Hwang, Rudy Verstraeten
Abstract: A method for producing a thermoplastic elastomer composition comprising using a twin screw kneader to melt-knead a thermoplastic resin and an elastomer; the twin screw kneader having at least two raw material inlets including a first raw material inlet and a second raw material inlet provided at a position separated by 15D to 38D on a downstream side from the first raw material inlet, where D is a cylinder inside diameter of the twin screw kneader; the elastomer being fed in a divided manner from the first and second raw material inlets; a proportion of the elastomer fed from the second raw material inlet being from 10 to 60 vol % of a total amount of the elastomer; and the elastomer being melt-kneaded in a kneading zone having a length of from 0.5D to 20D in a cylinder axis direction of the twin screw kneader.
Abstract: A thermoplastic resin composition including (A) bisphenol A-based polycarbonate, (B) biphenyl group-containing polycarbonate, (C) a biphenyl group-containing or terphenyl group-containing (meth)acryl-based copolymer and (D) a graft copolymer and a molded article manufactured from the same.
Type:
Grant
Filed:
May 8, 2014
Date of Patent:
March 28, 2017
Assignee:
Samsung SDI Co., Ltd.
Inventors:
Kee-Hae Kwon, In-Chol Kim, Joo-Hyun Jang, Jun-Ho Chi, Chang-Min Hong
Abstract: One or more fly ash materials or other optimized mineral fillers having a particle size distribution that may include cinders of selected sizes is mixed to form a filler. The filler is then mixed with an acid scavenger, an antioxidant, a compatibilizer and an impact modifier into a resin to form either a final composition or a masterbatch. A blowing agent may be added to both. Either the masterbatch or the final composition is mixed with a blend of a mineral oil and a styrenic block copolymer. Thereafter the masterbatch if prepared is mixed into or with a base resin to form the final composition. Fractional melt may be used in the masterbatch and in the final composition. The physical properties of the resulting products can be controlled by varying the ingredients. Some masterbatches are combined to produce products that have improved impact strength and/or that have enhanced toughness when compared to products made using naked or virgin resins.
Abstract: Conjugated diene monovinylarene block copolymers containing a terminal conjugated diene end block and having superior kink resistance properties are disclosed. These copolymers can be used to produce tubing and other end-use articles, and can be a replacement for flexible PVC.
Type:
Grant
Filed:
September 18, 2015
Date of Patent:
March 21, 2017
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Jinping Joe Zhou, Walter H Pace, David A Young
Abstract: A polyolefin-based composition made from or containing (A) a first polymer composition made from or containing a polyolefin grafted with an unsaturated monomer, (B) a second polymer composition made from or containing a polyethylene, and (C) a third polymer composition made from or containing (i) a first polyisobutylene and (ii) a second polyisobutylene. The first polyisobutylene has a Viscosity Average Molecular Weight (VAMW1), and the second polyisobutylene has a Viscosity Average Molecular Weight (VAMW2), wherein VAMW1?VAMW2. The polyolefin-based composition is useful as an adhesives or a tie-layer adhesive composition for multi-layered structures. In particular, the composition is useful as an adhesive to bind a metal layer to a dissimilar substrate.
Abstract: Provided are a preparation method of a thermoplastic resin composition and a thermoplastic resin composition prepared therefrom. The preparation method includes: feeding a first thermoplastic resin in a molten state into a first hopper and feeding an impact reinforcing agent including a predetermined content of moisture into a second hopper, followed by kneading and extruding processes, and removing the moisture in a first vent port and a second vent port, wherein the first hopper, the first vent port, the second hopper, a first kneading zone, and the second vent port are sequentially formed in a moving direction of an extruder. The thermoplastic resin composition prepared therefrom can have improved appearance property and improved color property by removing moisture of an impact reinforcing agent added to the thermoplastic resin composition.
Type:
Grant
Filed:
December 29, 2014
Date of Patent:
March 14, 2017
Assignee:
Samsung SDI Co., Ltd.
Inventors:
Jae Keun Hong, Beom Ho Kim, Jun Hong Park, Ki Bo Chang, Sung Hun Kim, Gwang Hwan Lee
Abstract: Acetoacetyl group-containing polyvinyl alcohol resin powder composition containing a C1 to C3 alcohol in an amount of 0.5 to 4 wt % is produced by allowing a powdery polyvinyl alcohol resin to react with diketene, washing the resulting acetoacetyl group-containing polyvinyl alcohol resin particles with the C1 to C3 alcohol to remove an unreacted portion of the diketene, and drying the intermediate acetoacetyl group-containing polyvinyl alcohol resin particles composition at a temperature of 40° C. to 120° C. at a pressure of not higher than 20 kPa after the washing. The acetoacetyl group-containing polyvinyl alcohol resin powder composition thus produced is highly soluble in water.
Type:
Grant
Filed:
October 10, 2014
Date of Patent:
March 14, 2017
Assignee:
THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.
Abstract: The present invention relates to a composition comprising polymer particles and functionalized stimulus responsive polymer; the polymer particles (i) comprising block co-polymer, and (ii) having a core-shell structure, said block co-polymer comprising (a) a non-stimulus responsive polymer block that forms at least part of the core structure, and (b) a stimulus responsive polymer block that forms at least part of the shell structure; wherein the stimulus responsive polymer of both the polymer particles and the functionalized stimulus responsive polymer are responsive to at least one common stimulus.
Type:
Grant
Filed:
June 7, 2013
Date of Patent:
March 7, 2017
Assignee:
The University of Queensland
Inventors:
Peter Gray, Michael John Monteiro, Trent Phillip Munro, Andrew Benjamin James Prowse
Abstract: To provide An adhesive composition for a protective film to suppress a surface pollution and adhesive residue on a painting surface. The adhesive composition comprises: 100 weight parts of given block copolymer, and 1 to 20 weight parts of a given polar tackifier resin compound, wherein the polar tackifier resin compound has a solubility parameter (SP value) of 8.2 to 9.2 calculated by the Small method using Hoy's constant.
Abstract: A hydrogel material for use in three-dimensional scaffold printing is disclosed. The material is formed from a first triblock polymer having a formula ABA and a second triblock polymer having a formula AmaBAma, wherein A is a first polymer, B is a second polymer, and Ama is a methacrylate of the first polymer. The material is thermosensitive and photocrosslinkable. A method of manufacturing the material is also disclosed.
Abstract: The present invention relates to an epoxy-resin composition comprising the following components (A), (B), (C) and (D), a film made of the epoxy resin composition, a prepreg and a fiber-reinforced plastic. The present invention can provide an epoxy-resin composition that cures at a low temperature in a short period of time. Also, the present invention can provide a fiber-reinforced plastic having excellent mechanical characteristics, especially excellent fracture toughness and heat tolerance, is made from the epoxy-resin composition. component (A): an epoxy resin having a monomer unit represented by formula (1) in the molecule; component (B): a bifunctional epoxy resin with a number-average molecular weight of at least 600 but no greater than 1300, which does not have a monomer unit represented by formula (1) below in the molecule; component (C): a triblock copolymer; and component (D): a curing agent.
Abstract: The present invention relates to a carrier-based bonding adhesive agent, which is equipped for bonding adhesion on one or both sides or a carrier-free bonding adhesive agent, in the form of an adhesive strip or stamped part having a bonding adhesive consisting substantially of a blend of polyacrylate and a synthetic rubber as well as one or more adhesive resins. By comparison with previously known adhesive systems such an adhesive exhibits a significant improvement in adhesion on hard, non-polar surfaces such as for example new paint surfaces in the automobile industry.
Type:
Grant
Filed:
August 13, 2013
Date of Patent:
February 14, 2017
Assignee:
Lohmann GmbH & Co. KG
Inventors:
Patrik Kopf, Patricia Petrick, Axel Kamelgan
Abstract: We disclose a monovinylarene-conjugated diene block copolymer containing a plurality of monovinylarene-conjugated diene mixed blocks, wherein each mixed block contains conjugated diene units and monovinylarene units in a weight ratio of about 0.05 to about 0.33. We also disclose a composition containing (a) from about 50 parts by weight to about 95 parts by weight of the monovinylarene-conjugated diene block copolymer and (b) from about 5 parts by weight to about 50 parts by weight of polystyrene; wherein the monovinylarene-conjugated diene block copolymer and the polystyrene total 100 parts by weight.
Type:
Grant
Filed:
April 15, 2015
Date of Patent:
January 24, 2017
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
John Mark Brown, Nathan E. Stacy, Carleton E. Stouffer, John D. Wilkey, Michael A. Smith
Abstract: There are provided a hot-melt adhesive, which is excellent in solvent resistance and is excellent in adhesion to an adherend (specifically, a polyimide film) containing an electrolytic solution of a battery therein, and also can contribute to an improvement in performances of electric instruments; and an electric instrument produced by using such hot-melt adhesive. A hot-melt adhesive for electric instruments, comprising an olefin based modified polymer (A), the olefin based modified polymer (A) being a modified polymer having a functional group containing silicon, is excellent in resistance to an electrolytic solution of a battery (that is, electrolytic solution resistance or solvent resistance), and also exhibits improved adhesion of the hot-melt adhesive to an adherend (plastic film such as a polyimide film) containing the electrolytic solution therein.
Type:
Grant
Filed:
October 24, 2014
Date of Patent:
January 24, 2017
Assignee:
HENKEL IP & HOLDING GMBH
Inventors:
Itsuro Tomatsu, Kenji Matsuda, Ai Takamori
Abstract: A thermoplastic molding compound that has proved to be extremely weather-resistant and low-emission containing the following components: A) 3-77% by weight of one or more styrene copolymers, component A; B) 15-89% by weight of one or more polyamides, component B; C) 5-50% by weight of two or more graft rubbers without olefinic double bonds in the rubber phase, component C; D) 1-25% by weight of a terpolymer of styrene, acrylonitrile and maleic anhydride, component D; E) 2-30% by weight of rubber based on olefinic monomers, component E; F) 0-50% by weight of fibrous or particulate filler or mixtures thereof, component F; G) 0-40% by weight of further additives, component G.
Abstract: Conjugated diene monovinylarene block copolymers having superior kink resistance properties are disclosed. These copolymers can be used to produce tubing and other end-use articles, and can be a replacement for flexible PVC.
Type:
Grant
Filed:
March 11, 2016
Date of Patent:
January 10, 2017
Assignee:
Chevron Phillips Chemical Company LP
Inventors:
Jinping Joe Zhou, Walter H. Pace, David A. Young
Abstract: The invention provides a composition comprising at least the following: A) an anhydride and/or carboxylic acid functionalized ethylene/alpha-olefin interpolymer having the following properties: i) a melt viscosity (177° C.) less than, or equal to, 200,000 cP, ii) a density from 0.855 to 0.900 g/cc; B) an ethylene-based polymer; and C) a polar polymer.
Type:
Grant
Filed:
March 15, 2013
Date of Patent:
December 27, 2016
Assignee:
Dow Global Technologies LLC
Inventors:
Didem Oner-Deliormanli, Brian W. Walther, Rajen M. Patel, Gregory Bunker, John W. Garnett, IV