Patents Examined by John S. Y. Chu
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Patent number: 6440632Abstract: A photosensitive resin composition comprises a base resin (e.g., novolak resins, polyvinylphenol-series polymers), a first photoactive ingredient (e.g., diazobenzoquinone derivatives, diazonaphthoquinone derivatives) and a second photoactive ingredient (e.g., mixtures with azide compounds) each having an absorption range at wavelength &lgr;1 or &lgr;2, the wavelengths thereof being different from each other. Between the first and second photoactive ingredients, at least one photoactive ingredient is substantially inert at the absorption wavelength of the other. After exposing the photosensitive resin composition to a light to form a pattern, the whole surface of the photosensitive layer is exposed to a light of the other wavelength to make the surface hardly soluble (in the case a positive pattern is formed) or readily soluble (in the case a negative pattern is formed) in a developer, and developed, thereby forming a pattern of high resolution.Type: GrantFiled: August 18, 1999Date of Patent: August 27, 2002Assignee: Kansai Research InstituteInventor: Tokugen Yasuda
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Patent number: 5650261Abstract: A positive-acting photoresist composition which produces crosslinked images and processes for using the photoresist composition are disclosed. The photoresist composition is prepared from a mixture containing a film forming, polymer-containing, acid hardening resin system, an acid or acid generating material (preferably in the form of a thermal acid generator) for crosslinking the acid hardening resin system, and a photobase generating compound. The photoresist composition is applied as a film onto a substrate surface and selectively imagewise exposed through a photomask to actinic radiation. The actinic radiation causes the photobase generator to produce a base in the imagewise exposed portions of the photoresist film. The photochemically generated base neutralizes the acid in the imagewise exposed areas of the photoresist film.Type: GrantFiled: October 27, 1989Date of Patent: July 22, 1997Assignee: Rohm and Haas CompanyInventor: Mark Robert Winkle
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Patent number: 5648194Abstract: A photoresist composition comprising an alkali soluble resin, an o-naphthoquinone diazide sulfonic acid ester photoactive compound, and a vinyl ether compound. The o-naphthoquinone diazide sulfonic acid ester is replaced in part with the vinyl ether composition to decrease the concentration of the photoactive compound while increasing the photospeed of the composition.Type: GrantFiled: August 3, 1995Date of Patent: July 15, 1997Assignee: Shipley Company, L.L.C.Inventors: Daniel Y. Pai, Robert E. Hawkins
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Patent number: 5639586Abstract: The present invention provides a lithographic base comprising on a hydrophobic support a packet of subbing layers contiguous to a hydrophilic layer containing a hydrophilic (co)polymer or (co)polymer mixture and being hardened with a hydrolysed tetraalkyl orthosilicate crosslinking agent characterized in that said packet of subbing layers contains as undermost layer a layer comprising, a polymer latex having hydrophilic functionality and as uppermost layer a layer comprising a hydrophilic binder and silica in a weight ratio of the hydrophilic binder to silica of less than 1.Type: GrantFiled: August 14, 1995Date of Patent: June 17, 1997Assignee: AGFA-Gevaert, N.V.Inventors: Guido Hauquier, Willem Cortens, Paul Coppens, Joan Vermeersch, Erik Mostaert, Eric Verschueren
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Patent number: 5637436Abstract: Ternary mixtures of C.sub.4 to C.sub.8 alkyl acetate, C.sub.4 to C.sub.8 alkyl alcohol, and water, formulated to have a flash point of above 100.degree. F., are disclosed, particularly for use in edge residue removal processes in the fabrication of integrated circuits and like products.Type: GrantFiled: April 4, 1995Date of Patent: June 10, 1997Assignee: Hoechst Celanese CorporationInventor: Donald W. Johnson
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Patent number: 5609980Abstract: A radiation sensitive material comprises particles including a water-insoluble heat-softenable core surrounded by a shell which is soluble or swellable in aqueous medium. The material also includes a radiation sensitive component which, on exposure to radiation, causes the solubility characteristics of the material to change. The material may be positive- or negative-working and may be coated onto a substrate from aqueous media to form a radiation sensitive plate which, after image-wise exposure, can be developed in aqueous media and then heated to cause the particles to coalesce and form a durable printing image.Type: GrantFiled: May 14, 1992Date of Patent: March 11, 1997Assignee: DuPont (U.K.) Ltd.Inventors: Andrew E. Matthews, David E. Murray, Allen P. Gates, John R. Wade, Michael J. Pratt, William A. King
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Patent number: 5597677Abstract: A photoimageable element comprising: a substrate; a layer of a photosensitive composition comprising a photosensitive material coated on the substrate; and a protective overcoating comprising an oxygen barrier component and a moisture resistant component; wherein the oxygen barrier component has an oxygen permeability of no greater than about 10.sup.-14 cc(cm)/cm.sup.2 (sec)(Pa).Type: GrantFiled: November 2, 1994Date of Patent: January 28, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Steven L. Kangas, Emil D. Sprute, Dean J. Stych
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Patent number: 5593814Abstract: A device for controlling cell arrangement having a pattern composed of a cell adhesive surface and a cell non-adhesive surface, which has a good selectivity of cell adhesion and which can provide a fine pattern of cells in high resolution by culturing cells in a usual manner.Type: GrantFiled: September 19, 1994Date of Patent: January 14, 1997Assignee: Kanegafuchi kagaku kogyo Kabushiki KaishaInventors: Takehisa Matsuda, Kazuhiko Inoue, Nobutaka Tani
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Patent number: 5593802Abstract: A method of forming a spacer for supporting two substrates which constitute a liquid crystal panel, wherein the spacer is disposed between the two substrates, at least one of which has thereon an alignment layer which has been subjected to aligning treatment, comprising the steps of: (1) laminating the substrate having the alignment layer on a transfer sheet comprising projections of substantially uniform thickness on a temporary support in such a manner that the projections closely contact the alignment layer, and (2) peeling-off the temporary support to transfer the projections onto the alignment layer. The inventive method forms a spacer through a simple step and at a uniform density, and prevents damage of an aligning layer.Type: GrantFiled: October 7, 1994Date of Patent: January 14, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Morimasa Sato, Fumiaki Shinozaki
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Patent number: 5594086Abstract: A compound, method of manufacture and method for use of an alternating copolymer having the structure ##STR1## wherein X is independently H, C.sub.1 to C.sub.10 alkyl or alkoxy, primary or secondary amino or halogen, and R is aliphatic, cycloaliphatic, or aliphatic heterocyclic, and wherein the molecular weight ranges from about 1,000 to 50,000.Type: GrantFiled: June 7, 1995Date of Patent: January 14, 1997Assignee: Hoechst Colanese CorpInventor: Richard Vicari
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Patent number: 5589315Abstract: A photosensitive composition containing a polyfunctional aromatic diazo compound having at least two groups of Formula (uD) in the molecule, and a photosensitive composition using the same. The diazo compound can be handled under visible light free from ultraviolet, is highly photosensitive, has good shelf life, and lithographic printing plates and screen printing plates formed with the same: ##STR1## wherein G.sup.1 is a substituent derived from alcoholic hydroxyl group; R.sup.1 and R.sup.2 are hydrogen, or alkyl or alkyloxy of 1 to 8 carbon atoms;R.sup.3 is alkyl or substituted alkyl of 1 to 8 carbon atoms, aralkyl or substituted aralkyl of 7 to 14 carbon atoms, or --CH.sub.2 CHG.sup.2 --CH.sub.2 --;X.sup.- is an anion based on protonic acid from which a proton is removed.Type: GrantFiled: January 6, 1995Date of Patent: December 31, 1996Assignee: Toyo Gosei Kogyo Co., Ltd.Inventors: Hirotada Iida, Noriaki Tochizawa, Yasuo Kuniyoshi, Masaharu Watanabe, Katsuyo Tokuda, Ichiro Hozumi
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Patent number: 5587278Abstract: A polyester support prepared by the step of subjecting a polyester film to bulk rolling and heating the bulk rolled polyester film to a temperature of from 50.degree. C. to the glass transition point of said polyester film, or subjecting a polyester film to bulk rolling at a temperature of from 50.degree. C. to the glass transition point of said polyester film, resulting in the polyester support, wherein the glass transition point of said polyester film is 90.degree. to 200.degree. C., and wherein the step of bulk rolling has a start tension of 3 to 75 kg/m per unit width of the polyester film and an end tension of 3 to 75 kg/m per unit width of the polyester film.Type: GrantFiled: December 10, 1993Date of Patent: December 24, 1996Assignee: Fuji Photo Film Co., Ltd.Inventor: Fumio Kawamoto
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Patent number: 5584953Abstract: A method of manufacturing a photographic printing paper support wherein a composition consisting essentially of polyethylene terephthalate is hot extruded so as to cover at least one surface of the raw paper, this method being characterized in that after a hot extruded film of the aforesaid composition is discharged onto the raw paper on the nip roll, it is pressed in contact with the chilled roll.Type: GrantFiled: September 30, 1994Date of Patent: December 17, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahito Miyoshi, Yasuo Nishikawa, Sugihiko Tada
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Patent number: 5580709Abstract: Disclosed is a film constituted of a polyester, said film having a degree of roll set curl of not higher than 135 m.sup.-1 after being subjected to heat treatment, and having a degree of recovery curl of not higher than 45 m.sup.-1 after being subjected to hot water bath treatment.Type: GrantFiled: September 14, 1994Date of Patent: December 3, 1996Assignee: Konica CorporationInventors: Hideyuki Kobayashi, Takatoshi Yajima, Kenji Nakanishi, Hiromitsu Araki, Hiroshi Naito, Yoshioki Okubo, Tetsutaro Hashimura
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Patent number: 5580693Abstract: Disclosed is a light-heat converting type heat mode recording process using a recording material and an image receiving material, which comprises the steps of:(a) transferring an ink image from a recording material to an image receiving material by exposing from a back of the recording material or the receiving material; and(b) transferring the ink image from the image receiving material to a final recording medium by applying heat or pressure.The light-heat converting type heat mode recording material and the light-heat converting type heat mode image receiving material are capable of forming excellent transferred images.Type: GrantFiled: May 28, 1993Date of Patent: December 3, 1996Assignee: Konica CorporationInventors: Atsushi Nakajima, Shinji Matsumoto, Katsumi Maejima, Sota Kawakami, Shozo Kikugawa
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Patent number: 5580702Abstract: Disclosed herein is a resist for forming patterns, which is greatly sensitive to ultraviolet rays an ionizing radiation, and which can therefore form a high-resolution resist pattern if exposed to ultra violet rays or an unionizing radiation. Hence, the resist is useful in a method of manufacturing semicon ductor devices having high integration densities. The resist comprises tert-butoxycarbonyl methoxypolyhydroxy styrene and an o-quinonediazide compound.Type: GrantFiled: December 13, 1994Date of Patent: December 3, 1996Assignee: Kabushiki Kaisha ToshibaInventors: Rumiko Hayase, Yasunobu Onishi, Hirokazu Niki, Noahiko Oyasato, Yoshihito Kobayashi, Shuzi Nayase
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Patent number: 5578413Abstract: A photosensitive transfer material is disclosed including a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the transfer material having an interlaminar adhesion which is lowest between the thermoplastic resin layer and the temporary substrate, wherein the alkali-soluble thermoplastic resin layer contains (A) an alkali-soluble thermoplastic resin having a weight average molecular weight of from 50,000 to 500,000 and a glass transition temperature of from 0.degree. to 140.degree. C. and (B) an alkali-soluble thermoplastic resin layer having a weight average molecular weight of from 3,000 to 30,000 and a glass transition temperature of from 30.degree. to 170.degree. C. at an (A)/(B) weight ratio of from 5/95 to 95/5. The transfer material can be transferred to a permanent substrate at a high speed without entrapping air bubbles due to unevenness on the permanent substrate.Type: GrantFiled: March 15, 1996Date of Patent: November 26, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Fujikura, Minoru Wada
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Patent number: 5576136Abstract: According to the present invention the storage stability of a diazo based imaging element can be improved by controlling the amount of free water in the imaging element. Thus the present invention provides an imaging element comprising on a support a hydrophilic layer containing a hydrophilic (co)polymer or (co)polymer mixture and having been hardened with a hydrolyzed tetraalkyl orthosilicate and a light sensitive layer containing a diazo resin or a diazonium salt characterized in that the total amount of free water in said imaging element satisfies the following formula (I):FW (g/m.sup.2).ltoreq.0.0043 * WS (g/m.sup.2)+0.46 (g/m.sup.2) (I)wherein FW represents the amount of free water and WS represents the weight of the support of the imaging element.Type: GrantFiled: June 29, 1994Date of Patent: November 19, 1996Assignee: Agfa-Gevaert, N.V.Inventors: Joan Vermeersch, Eric Verschueren, Guido Hauquier
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Patent number: 5576137Abstract: The invention relates to a non-continuous matte layer that can be used with a recording material having a substrate and a radiation-sensitive layer which contains a 1,2-naphthoquinone-2-diazide and an organic, polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions. This matte layer comprises 100 to 10,000 particles per square centimeter which have a mean diameter of less than 40 .mu.m and a maximum diameter of less than 80 .mu.m and a mean height of 2 to 6 .mu.m and a maximum height of 10 .mu.m, and contains a resin which has up to 0.80 mmol of acid groups and/or salt groups per gram. The matte layer is obtained by spraying on and drying an aqueous, anionically or anionically/nonionically stabilized dispersion of the resin.Type: GrantFiled: September 14, 1994Date of Patent: November 19, 1996Assignee: Agfa-Gevaert AGInventors: Werner Frass, Otfried Gaschler, Klaus Joerg, Guenter Hultzsch, Andreas Elsaesser
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Patent number: 5576139Abstract: A novel positive type photoresist composition is provided, comprising an alkali-soluble novolak resin obtained by the condensation of substituted or unsubstituted phenols and aldehydes in the presence of a silica-magnesia solid catalyst and a light-sensitive material containing 1,2-naphthoquinone-diazido-5-(and/or -4-) sulfonate as main component.Type: GrantFiled: October 28, 1991Date of Patent: November 19, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuya Uenishi, Shiro Tan, Yasumasa Kawabe, Tadayoshi Kokubo