Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.

Abstract: A method of synthesizing a polynucleotide composition includes attaching a compound including at least one initiator or at least one transfer agent for a reversible deactivation radical polymerization to an end of a nucleotide chain assembly immobilized upon a solid phase support during a solid phase synthesis of a polynucleotide so that the initiator or the transfer agent is attacked to the end of a nucleotide chain assembly in a manner which is stable under conditions of deprotection of the polynucleotide, and growing a polymer from the initiator of from a site of the chain transfer agent via the reversible deactivation radical polymerization to form the polynucleotide composition.

Abstract: Described are coating compositions comprising a polyester, the polyester comprising: at least one polyester which comprises a dicarboxylic acid component comprising terephthalic acid residues, and a glycol component comprising 30 to 40 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 60 to 70 mole % cyclohexanedimethanol residues, where the inherent viscosity of the polyester is from 0.10 to 0.70 dL/g, and where the coating composition is made from a film or sheet.

Abstract: An object of the present invention is to provide a rubber composition capable of producing a pneumatic tire with both satisfactory heat build-up reduction and excellent wet skid performance, and a pneumatic tire comprising the rubber composition. The rubber composition of the present invention contains a diene-based rubber containing from 5 to 40 mass % of a modified butadiene rubber and a white filler. The modified butadiene rubber is a modified polymer obtained by modifying an unmodified butadiene rubber (A) with a nitrone compound (B) having a carboxy group.

Abstract: A thermally decomposable polymer composition comprising a polyester of a dicarboxylic acid and a tertiary cyclohexanediols of Formulae V and VI are disclosed, which are useful in the forming of microelectronic assemblies: a representative example of a dicarboxylic acid is an oxalic acid and representative example of thermally decomposable polyester is the polyester of the formula: wherein m is at least about 100.

Abstract: Disclosed herein are vulcanizable and vulcanized rubber compositions comprising a conjugated diene polymer or copolymer, silica, and a substituted imidazole-based silica shielding agent of Formula (I), and methods for preparing such rubber compositions. Also disclosed herein are tire components, such as tire treads, containing the rubber compositions disclosed herein.

Abstract: There are provided an electrically conductive adhesive agent capable of providing good electrical continuity to a substrate to which a preflux treatment has been applied, and a method for connecting electronic components. The electrically conductive adhesive agent to be used includes a polymerizable acrylic compound, an organic peroxide, and the solder particles, the organic peroxide having a one minute half-life temperature lower than the solidus temperature of the solder particles. At the time of thermocompression bonding, the solder particles are crushed and an oxide film is removed, and a preflux layer on the surface of a bump is also removed by melting and flowing thereof, whereby electrical continuity is secured, and then an adhesive component is completely cured.

Abstract: The resin-coated metal sheet for containers includes a resin coating layer (A) having a multilayered structure mainly composed of a polyester resin on at least one surface thereof. The resin coating layer (A) includes a resin layer (a1). The resin layer (a1) adheres to the metal sheet, contains (i) a polyester resin, (ii) a phenolic resin, (iii) a metal alkoxide compound and/or a metal chelate compound, (iv) an epoxy resin, and (v) at least one selected from the group consisting of polyamine resins, polyamidoamine resins, and polyamide resins, and is mainly composed of the polyester resin. Preferably, a polyester film (a2) is disposed on the resin layer (a1).

Abstract: A polysulfide material having reactive vinyl end groups and a method of making a vinyl end-capped polysulfide material are described. The vinyl end-capped polysulfide material has potential applications as a sealant, an adhesive, a coating, a caulking, or the like. In a specific example, the polysulfide material may be used as a precursor material for a sealant resin in the manufacturing of an integral fuel tank of an aircraft. An example method for making polysulfide materials includes contacting a vinyl-functionalized aryl halide and/or a vinyl-functionalized heteroaryl halide with dithiols and/or trithiols in the presence of an organic solvent.

Abstract: Described herein are hemi-aminal ethers and thioethers of N-alkenyl cyclic compounds that may be produced through a reaction comprising: (A) at least one first reactant represented by a structure (I), wherein X is a functionalized or unfunctionalized C1-C5 alkylene group optionally having one or more heteroatoms, and each R1, R2, and R3 is independently selected from the group consisting of hydrogen and functionalized and unfunctionalized alkyl groups optionally having one or more heteroatoms, and (B) at least one second reactant having at least one hydroxyl moiety or thiol moiety. The hemi-aminal ethers and thioethers of N-alkenyl cyclic compounds may comprise a polymerizable moiety, in which case they may be left as-is or used to create homopolymers or non-homopolymers, or they may not comprise a polymerizable moiety. A wide variety of formulations may be created using the hemi-aminal ethers and thioethers of N-alkenyl cyclic compounds, including personal care, oilfield, and construction formulations.

Abstract: Inorganic polymer/organic polymer composites and methods for their preparation are described herein. The inorganic polymer/organic polymer composites comprise a first layer comprising an inorganic polymer and a second layer adhered to the first layer comprising an organic polymer. The inorganic polymer is formed by reacting, in the presence of water, a reactive powder, an activator, and optionally a retardant. The reactive powder comprises 85% by weight or greater fly ash and less than 10% by weight portland cement. Also described herein are building materials including the composites.

Abstract: Tire having improved wet grip performance and improved resistance to breaking or chipping along with good fuel economy. The tire includes a tire component (preferably, a tire tread) formed of a vulcanized rubber composition. The vulcanized rubber composition is obtained by vulcanizing a specific unvulcanized rubber composition. The unvulcanized rubber composition comprises (a) a rubber component composed of natural rubber, polybutadiene rubber, and two different types of styrene-butadiene rubber, (b) a filler that includes silica, and (c) a silane coupling agent that incorporates a —C(?O)—S— moiety.

Abstract: Disclosed herein are glycidol-based polymers, nanoparticles, and methods related thereto useful for a variety of applications, including, but not limited to, drug delivery. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: Photodegradable polymers derived from biomass are provided, together with methods of making and methods of using the polymers. The photodegradable polymers can be derived from at least a first monomeric unit and a second monomeric unit and an optional third monomeric unit. The first monomeric unit is a dicarboxylic acid and includes a furan group and the second monomeric unit includes a nitrobenzyl group. Methods of recycling the polymers including irradiating the polymers to yield recycled monomers and oligomers are also disclosed.

Abstract: Amphiphilic macromolecules having repeating structural units: structural units to adjust molecular weight and molecular weight distribution and charging property effects, high stereo-hindrance structural units, and amphiphilic structural units, which are suitable for fields such as oil field well drilling, well cementation, fracturing, oil gathering and transfer, sewage treatment, sludge treatment and papermaking, etc., and can be used as an oil-displacing agent for enhanced oil production, a heavy oil viscosity reducer, a fracturing fluid, a clay stabilizing agent, a sewage treatment agent, a papermaking retention and drainage aid or a reinforcing agent, etc.

Abstract: Polymer compositions containing conjugated diene monovinylarene block copolymers and styrenic thermoplastic elastomers are disclosed. These compositions can be used to produce tubing having superior kink resistance properties, and can be a replacement for flexible PVC in various end-use applications, such as in sheet products, film products, tubing products, and adhesive products.

Abstract: A thermoplastic resin composition having good balance among impact resistance, flame retardancy, heat resistance and flowability all of which are required for thin molded articles high-dimensionally. The flame retardant resin composition comprises 100 parts by weight of a resin component comprising (A) a polycarbonate resin and (B) a polycarbonate-polydiorganosiloxane copolymer resin obtained by copolymerizing a dihydric phenol with a hydroxyaryl-terminated polydiorganosiloxane, (C) 3 to 35 parts by weight of an organic phosphorus-based flame retardant or 0.005 to 5 parts by weight of an organic metal salt-based flame retardant, (D) 0.1 to 30 parts by weight of a silicate mineral and (E) 0.1 to 3 parts by weight of a dripping inhibitor, and, if necessary, (F) 3 to 45 parts by weight of a styrene resin wherein the polydiorganosiloxane content of the component (B) in the composition is 0.2 to 0.6 wt %.

Abstract: The present invention relates to a process for the production of thermoplastic molding compositions, in particular styrene copolymer compositions, to a process for production of these, and also to use thereof. The thermoplastic molding compositions produced by a process of the invention offer improved temperature-resistance and mechanical properties, which have better flow properties than known molding compositions.

Abstract: Curable silsesquioxane polymers are described comprising a core comprising a first silsesquioxane polymer and an outer layer comprising a second silsesquioxane polymer bonded to the core. The silsesquioxane polymer of the core, outer layer, or combination thereof comprises ethylenically unsaturated groups. The first silsesquioxane polymer of the core is bonded to the second silsesquioxane polymer of the outer layer via silicon atoms bonded to three oxygen atoms. In some embodiments, the outer layer has a higher concentration of ethylenically unsaturated groups than the core. In this embodiment, the core may be substantially free of ethylenically unsaturated groups. In other embodiments, the core has a higher concentration of ethylenically unsaturated groups than the core. In this embodiment, the outer layer may be substantially free of ethylenically unsaturated groups. The core and outer layer each comprise a three-dimensional branched network of a different silsesquioxane polymer.

Abstract: To provide a liquid composition capable of forming a coating film which has sufficient ultraviolet-absorbing ability and infrared-absorbing ability. A liquid composition for forming a coating film comprising an infrared absorber selected from indium tin oxide, antinomy tin oxide and a composite tungsten oxide, an ultraviolet absorber selected from a benzophenone compound, a triazine compound and a benzotriazole compound, a dispersing agent having an acid value and/or an amine value, a binder component and a liquid medium, wherein the dispersing agent is contained in a content such that the product of the sum (mgKOH/g) of the acid value and the amine value of the dispersing agent, and the mass ratio of the dispersing agent to the infrared absorber, is from 2 to 30 (mgKOH/g).