Abstract: A non alpha controlled plating bath including Tin species and a trace amount of Polonium species is utilized in a plating tool. The plating tool includes a Polonium filter element to remove Polonium species from the plating bath to selectively plate Tin upon a plating cathode. The filter may include a Titanium inner portion surrounding by a stannic oxide exterior. The filter may reduce the Polonium species by having the polonium absorb and then enter within the stannic oxide matrix. The filter may be located within the plating tool reservoir or filter housing. The filter may be fabricated by forming Tin upon a Titanium filter backbone and converting the Tin to stannic oxide.
Type:
Grant
Filed:
November 24, 2015
Date of Patent:
January 17, 2017
Assignee:
International Business Machines Corporation
Abstract: A vacuum refining furnace, including a furnace body, a graphite heater, an electrode, and a sealed furnace housing. The furnace body includes an evaporation laminate, a graphite condensing casing, and a graphite insulating casing. The evaporation laminate includes a plurality of evaporators. The evaporation laminate is nested within the graphite insulating casing, and the graphite insulating casing includes a plurality of through holes. At least two graphite condensing casings having different diameters are provided. The graphite insulating casing is nested within the graphite condensing casing having a smallest diameter, and the graphite condensing casing having a relatively small diameter is nested within the graphite condensing casing having a relatively large diameter. All the graphite condensing casings except for the graphite condensing casing having the largest diameter include a plurality of through holes.
Type:
Grant
Filed:
March 18, 2014
Date of Patent:
January 10, 2017
Assignee:
Kunming Diboo Technology Co., Ltd.
Inventors:
Bin Yang, Bin Su, Jianren Pan, Wentong Tang, Wei Chen, Zefei Fan, Wenlin Li, Menglin Li
Abstract: The present invention relates to the field of phosphating for corrosion-protective pretreatment of zinc surfaces, being directed toward the use of largely nickel- and cobalt-free zinc phosphating solutions. The present invention makes available an alternative to trication zinc phosphating, in which the zinc surfaces of a component are firstly, before zinc phosphating, passivated with an alkaline composition containing iron(III) ions, and thereby preconditioned for a largely nickel- and cobalt-free zinc phosphating operation. In a further aspect, the invention relates to a component, in particular an automobile body, that comprises at least in part surfaces made of zinc, the zinc surfaces being covered by a two-layer system made up of a first, inner passive layer containing iron and resting on the zinc surface, and a second, outer crystalline zinc phosphate layer resting on the inner layer.
Abstract: A system for energy optimization in a plant (3) for producing direct-reduced metal ores (3). The plant (3) has at least one reduction unit (12), a device for separating gas mixtures (7, 7a, 7b) having an associated compressing device (4, 4a, 4b), and a gas-heating device (10) upstream of the reduction unit (12). Part of the process gases (2, 2a, 2b) is fed by a feed line from a smelting reduction plant to the plant for producing direct-reduced metal ores (3). A turbine (8, 8a, 8b) is fit between the device for separating gas mixtures (7, 7a, 7b) and the gas-heating device (10) upstream of the reduction unit (12) such that a pressure drop between the device for separating gas mixtures (7, 7a, 7b) and the reduction unit (12) is converted into forms of energy that can be used to operate additional components (4, 4a, 4b, 15, 15a, 15b) of the plant (3), in particular electrical energy and/or mechanical energy. Energy consumption of the plant (3) is reduced.
Type:
Grant
Filed:
August 28, 2012
Date of Patent:
January 3, 2017
Assignee:
PRIMETALS TECHNOLOGIES AUSTRIA GMBH
Inventors:
Robert Millner, Gerald Rosenfellner, Harald Sprenger
Abstract: A surface treating composition for copper or a copper alloy comprising an imidazole compound and means for using the composition in the soldering of electronic parts to printed wiring boards are disclosed.
Abstract: The invention relates to use of an aqueous composition for pretreating can body stock, whereby an inorganic-organic conversion layer is formed, which effects outstanding sliding behavior of the shaped can body stock and in addition offers an outstanding holding primer for subsequent coating. The invention comprises a process in which can body stock which is deep-drawn to form a half-open can cylinder, before further shaping processes, is contacted with an acidic aqueous composition which contains water-soluble inorganic compounds of Zr, Ti, Si, Hf or Ce, water-soluble polymers having carboxyl groups or hydroxyl groups and also a dispersed wax. Both outer and inner surfaces of metallic can cylinders can be pretreated in the process. The invention also relates to an acidic aqueous composition for use in the pretreatment process, which contains water-soluble polymers selected from condensation products of glycoluril and aldehydes.
Abstract: The invention relates to a method for applying manages phosphate layers to iron or steel surfaces using phosphating solutions containing manganese, phosphate, iron (II) ions as well as nitroguinidine, as well as its application to workpieces that are subject to sliding friction.
Abstract: A method of coating an iron-based article includes a first heating step of heating a substrate that includes an iron-based material in the presence of an aluminum source material and halide diffusion activator. The heating is conducted in a substantially non-oxidizing environment, to cause the formation of an aluminum-rich layer in the iron-based material. In a second heating step, the substrate that has the aluminum-rich layer is heated in an oxidizing environment to oxidize the aluminum in the aluminum-rich layer.
Type:
Grant
Filed:
September 13, 2012
Date of Patent:
November 29, 2016
Assignee:
United Technologies Corporation
Inventors:
Neal Magdefrau, James T. Beals, Ellen Y. Sun, Jean Yamanis
Abstract: The invention concerns a solution for pretreating copper surfaces, and a method for pre-treating copper surfaces allowing the formation of a tight bond to plastic substrates. The solution comprises: a) hydrogen peroxide, b) at least one acid, and c) at least one nitrogen-containing, five-membered, heterocyclic compound, and d) additionally at least one nitrogen containing, adhesion-promoting compound, said compound comprising, or consisting of, lactams, non-quaternary fatty amines, amides and polyamides, connected at one or more of its nitrogen atoms with at least one residue of formula (I).
Type:
Grant
Filed:
October 24, 2011
Date of Patent:
November 22, 2016
Assignee:
ATOTECH DEUTSCHLAND GMBH
Inventors:
Christian Sparing, Thomas Huelsmann, Arno Clicque, Patrick Brooks, Adrian Zee, Heiko Brunner
Abstract: A low sludge trivalent chromium based conversion coating bath is provided which forms corrosion resistant coatings on aluminum and aluminum alloys by immersion in aqueous solutions containing trivalent chromium ions and fluorometallate ions followed by optional rinsing. Trivalent chromium coated aluminum also serves as an effective base for paint primers.
Abstract: A chromium-free conversion coating is prepared by the addition of inorganic metallic salts and one or more silanes to dispersions of conducting polymers which are then exposed to alloys of aluminum or other metals. Advantageously, the performance of the coating is comparable to that of conventional chromium-based methods for a number of aluminum alloys having particular significance in the manufacture of aircraft.
Type:
Grant
Filed:
October 26, 2012
Date of Patent:
October 25, 2016
Assignee:
The Boeing Company
Inventors:
Francisco Jesus Cano-Iranzo, Uxoa Izagirre-Etxeberria, Oihana Zubillaga-Alcorta, Patricia Santa Coloma-Mozo, Nieves Lapena-Rey
Abstract: In accordance with one aspect of an exemplary embodiment, a furnace including a charge well is provided. The charge well comprises an open top chamber including side and base walls of a heat resistant material. An inlet is provided in a side wall of the chamber for receiving molten metal. A ramp is provided adjacent the side wall and an inner wall forms a central cavity. The ramp is disposed between the inner wall and the side wall. The ramp is generally inclined from an intersection with the base wall to adjacent a top surface of the inner wall. The cavity is in fluid communication with an outlet. A passage in the inner wall provides fluid communication between the inlet and the cavity. The inlet and an outlet each receives a conduit and at least one of the conduits can include an elbow joint.
Type:
Grant
Filed:
July 9, 2012
Date of Patent:
October 25, 2016
Assignee:
PYROTEK INC.
Inventors:
Roger Howitt, Jim Grayson, Mark Bolton, Paul Bosworth
Abstract: Aluminum-zirconium and aluminum-zirconium-lanthanide superalloys are described that can be used in high temperature, high stress and a variety of other applications. The lanthanide is preferably holmium, erbium, thulium or ytterbium, most preferably erbium. Also, methods of making the aforementioned alloys are disclosed. The superalloys, which have commercially-suitable hardness at temperatures above about 220° C., include nanoscale Al3Zr precipitates and optionally nanoscale Al3Er precipitates and nanoscale Al3(Zr,Er) precipitates that create a high-strength alloy capable of withstanding intense heat conditions. These nanoscale precipitates have a L12-structure in ?-Al(f.c.c.) matrix, an average diameter of less than about 20 nanometers (“nm”), preferably less than about 10 nm, and more preferably about 4-6 nm and a high number density, which for example, is larger than about 1021 m?3, of the nanoscale precipitates.
Type:
Grant
Filed:
March 12, 2015
Date of Patent:
September 27, 2016
Assignee:
NanoAl LLC
Inventors:
Nhon Q Vo, David N Seidman, David C Dunand
Abstract: A method for conversion coating a magnesium-containing surface, the method comprising contacting the magnesium-containing surface with an ionic liquid compound under conditions that result in decomposition of the ionic liquid compound to produce a conversion coated magnesium-containing surface having a substantially improved corrosion resistance relative to the magnesium-containing surface before said conversion coating. Also described are the resulting conversion-coated magnesium-containing surface, as well as mechanical components and devices containing the conversion-coated magnesium-containing surface.
Abstract: Methods and systems for oxidizing an interconnect for a fuel cell stack include introducing at least one interconnect to an oxidizing gas containing water vapor, the oxidizing gas being at least substantially free of nitrogen, and oxidizing the at least one interconnect in the presence of the oxidizing gas at an elevated temperature. The oxidation may be performed at a sub-atmospheric pressure. The oxidation of the interconnect may be a controlled oxidation that is performed prior to incorporating the interconnect into a fuel cell stack.
Type:
Grant
Filed:
August 19, 2013
Date of Patent:
September 6, 2016
Assignee:
BLOOM ENERGY CORPORATION
Inventors:
Sanjiv Kapoor, Michael Gasda, Virginia Osterman, Ken Bauhof
Abstract: A manufacturing method for steel sheets for containers produces steel sheets with excellent film adhesion qualities. In a method for manufacturing steel sheets upon which is formed a chemical conversion coating having a metal Zr content of 1-100 mg/m2 and F content of no more than 0.1 mg/m2, the chemical conversion coating is formed on the steel sheet by subjecting the steel sheet to immersion in or electrolytic treatment with a treatment solution containing Zr ions and F ions, and subsequently, the steel sheet upon which the chemical conversion coating has been formed is washed with water having a temperature of at least 80° C. and dried.
Abstract: Disclosed are methods for treating and coating a ferrous metal substrate, such as cold rolled steel, hot rolled steel, and electrogalvanized steel. These methods include contacting the ferrous metal substrate with an aqueous pretreatment composition comprising: (a) a Group IIIB and/or IVB metal compound; (b) phosphate ions; and (c) water. Also disclosed are off-shift methods of removing iron from the pretreatment bath.
Abstract: An acidic, aqueous composition contains a trivalent chromium compound, an organo-functional silane, and a compound of a group IV-B element. The composition protects metal surfaces, preferably aluminum and aluminum alloys, against corrosion and improves their paint adhesion. The trivalent chromium compound may comprise chromium fluoride and optionally others, such as chromium nitrate. The organo-functional silane is preferably an aminopropyltriethoxy silane, and the compound of a group IV-B element is preferably fluorozirconic acid. The composition can either be dried-in-place or rinsed before a further coating layer is applied. The composition may also include at least one polymer having a plurality of both carboxylic functional groups, alone or with hydroxyl groups.