Abstract: Branched silicone (organopolysiloxane) resins and preparation method and use thereof are provided, which contain at least one group selected from phosphonate and phosphinate groups and at least one organic group containing nitrogen. Such silicone resins can be used in thermoplastic, thermosetting or rubber organic polymer compositions to reduce the flammability of the organic polymer compositions.
Abstract: A tire mix containing a cross-linkable, unsaturated-chain polymer base, curing agents, a reinforcing filler, and wax; the wax containing a paraffin wax containing a maximum of 45% by weight of normal paraffin.
Abstract: The invention relates to a rubber composition that is free of zinc or that contains less than 0.5 phr of zinc, which can be used for the manufacture of tires, based on at least: one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one blocked mercaptosilane of general formula I below: (R3O)R2R1—Si—Z—S—C(?O)-A in which: R1 and R2, which are identical or different, represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R3 represents a monovalent hydrocarbon-based group chosen from linear or branched alkyls having from 1 to 4 carbon atoms; A represents hydrogen or a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms.
Type:
Grant
Filed:
December 18, 2009
Date of Patent:
April 7, 2015
Assignees:
Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.
Inventors:
Laure Belin, Karine Longchambon, José Carlos Araujo Da Silva
Abstract: A composition for repairing voids or cracks in a cement sheath or plug comprises an aqueous epoxy resin, a hardener, an alkali-swellable material and an aqueous carrier fluid. The particle size of the alkali-swellable material is preferably smaller than 200 nanometers, thereby allowing the composition to penetrate cracks as small as 60 micrometers. A method for repairing voids or cracks in a cement sheath, thereby restoring zonal isolation, comprises preparing the composition, injecting the composition into voids or cracks in a cement sheath or plug and allowing the composition to viscosify and harden.
Abstract: The present invention is directed to crystalline organic polymer nanoparticles comprising a conductive organic polymer; wherein the crystalline organic polymer nanoparticles have a size of from 10 nm to 200 nm and exhibits two current-voltage states: (1) a high resistance current-voltage state, and (2) a low resistance current-voltage state, wherein when a first positive threshold voltage (Vth1) or higher positive voltage, or a second negative threshold voltage (Vth2) or higher negative voltage is applied to the nanoparticle, the nanoparticle exhibits the low-resistance current-voltage state, and when a voltage less positive than the first positive threshold voltage or a voltage less negative than the second negative threshold voltage is applied to the nanoparticle, the nanoparticle exhibits the high-resistance current-voltage state. The present invention is also directed methods of manufacturing the nanoparticles using novel interfacial oxidative polymerization techniques.
Type:
Grant
Filed:
October 2, 2007
Date of Patent:
March 3, 2015
Assignee:
Research Foundation of the City University of New York
Inventors:
Kai Su, Nurxat Nuraje, Lingzhi Zhang, Hiroshi Matsui, Nan Loh Yang
Abstract: Methods of forming blocked-mercapto alkoxy-modified silsesquioxanes are provided. The blocked-mercapto alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber as alcohol (a volatile organic compound (VOC)), during compounding and further processing. The blocked-mercapto alkoxy-modified silsesquioxane compounds also contain a blocked mercapto group which, when de-blocked, allows the mercapto group to interact with the polymer(s) in a rubber composition. Further described are rubber compounds containing the blocked-mercapto alkoxy-modified silsesquioxanes.
Type:
Grant
Filed:
December 29, 2008
Date of Patent:
February 24, 2015
Assignee:
Bridgestone Corporation
Inventors:
William L. Hergenrother, Chenchy Jeffrey Lin, James H. Pawlow, Terrence E. Hogan
Abstract: Disclosed herein are low volatile organic compound cleaner compositions which include a diethylene glycol monoalkyl ether, benzyl alcohol, and a fluorosurfactant. Also disclosed are low volatile organic compound cleaner compositions which include a diethylene glycol monoalkyl ether, benzyl alcohol, and an ethanolamine. Methods of using the compositions are also provided.
Abstract: For a tire excellent in strength, low-heat buildup property, wet grip property, and driveability, and a rubber composition and a conjugated diene rubber for the tire, a conjugated diene rubber of the present invention includes 5 wt % or more of a structure that 3 or more conjugated diene polymer chains are bound via a denaturing agent, obtained by reaction of each chain and the agent, each chain being that at least one of terminals is an isoprene block having 70 wt % or more of an isoprene monomer unit, and the other is an active terminal, the agent having, per molecule, at least one of an epoxy group(s) and a hydrocarbyloxysilyl group(s), and being that a total number of the epoxy group(s) and hydrocarbyloxy groups in the hydrocarbyloxysilyl group(s) per molecule is 3 or more.
Abstract: The present invention provides a method for producing chitin nanofibers, which includes the steps of deproteinizing a material derived from a chitin-containing organism by an alkali treatment, deashing a deproteinized integument by an acid treatment, optionally treating the deashed integument under acidic conditions, and then subjecting to a fiber-loosening treatment. The present invention also provides chitin nanofibers obtained by the method, and a composite material and a coating composition each containing the same. The present invention provides a method for producing chitosan nanofibers, which includes, in addition to the above steps, a deacetylation step and chitosan nanofibers obtained by the method, and a composite material and a coating composition each containing the same.
Abstract: Disclosed is a paint removing composition including an aluminum containing salt, calcium hydroxide, and calcium sulfate. When applied to wet latex paint, the composition neutralizes the paint molecules and causes the colloid to come out of suspension by the process of flocculation. The composition is prepared as a dry powder and added to a sufficient amount of water to create an aqueous solution. Also disclosed is a method of cleaning paintbrush containing wet paint. The composition is placed in contact with a wet paint-containing paintbrush for a sufficient time to cause the paint to come out of suspension in the form of floc.
Abstract: A latent curing agent that can cure a thermosetting epoxy resin in a relatively short period of time and at a relatively low temperature has a structure in which an aluminum chelating agent is held by a porous resin carrier obtained through interfacial polymerization of a polyfunctional isocyanate compound. The aluminum chelating agent is preferably a complex compound comprising ?-ketoenolate anion ligands coordinated to aluminum. The latent curing agent can be produced by dissolving the aluminum chelating agent and the polyfunctional isocyanate compound in a volatile organic solvent, adding the resulting solution to an aqueous phase containing a dispersing agent, and stirring the resulting mixture to cause interfacial polymerization of the isocyanate compound while the mixture is being heated.
Abstract: It is an object of the present invention to provide an aqueous ethylene-vinyl alcohol-based copolymer dispersion which is excellent in long-term storage stability and in film-forming properties even when subjected to low-temperature or short-time drying or applied to give thick coats and can give coatings showing high gas barrier performance. The prevent invention is an aqueous ethylene/vinyl alcohol-based copolymer dispersion, which comprises: (A) an ethylene/vinyl alcohol-based copolymer with an ethylene content of 15-65 mole percent and a degree of saponification of not lower than 80 mole percent, (B) a base-neutralized ethylene/?,?-unsaturated carboxylic acid-based copolymer and (C) a polyvinyl alcohol with a degree of saponification of 75-100 mole percent and a degree of polymerization of 100-3500, the content of the polyvinyl alcohol (C) being 0.5-100 parts by weight per 100 parts by weight of the ethylene/vinyl alcohol-based copolymer (A).
Abstract: The present invention provides thermosetting aqueous binder compositions of (i) one or more diprimary diamine, e.g. lysine, or poly(primary amine), e.g. polyethylenimine and tris(2-aminoethyl)amine, and (ii) one or more 5-carbon reducing sugar, such as xylose. The binders are at least substantially formaldehyde free and cure rapidly at temperatures sufficiently low and with sufficiently little swelling to enable one to provide wood or woody material containing articles, such as particle board, oriented strand board and bamboo boards or articles.
Type:
Grant
Filed:
April 21, 2011
Date of Patent:
November 11, 2014
Assignee:
Rohm and Haas Company
Inventors:
Charles J. Rand, Barry Weinstein, Drew E. Williams
Abstract: A hydroxyapatite ceramic hybrid material, which includes a biodegradable polymer included in the pores in a hydroxyapatite ceramic structure, and a method thereof, and a calcium phosphate porous body, which is formed by an intertwining of fibrous calcium phosphates and includes a plurality of first pores formed where the fibrous calcium phosphates interconnect and plurality of equal diameter substantially spherical second pores with a larger inside diameter than the first pores, and a method thereof are provided.
Abstract: A resin composition for encapsulation, which contains 100 parts by weight of a synthetic resin, 10 to 500 parts by weight of a carbon precursor having a volume resistivity of 102 to 1010 ?·cm, 0 to 60 parts by weight of a conductive filler having a volume resistivity lower than 102 ?·cm and 100 to 1,500 parts by weight of an other inorganic filler.
Abstract: A molded plastic body is produced from a cured reaction mixture. The reaction mixture is pourable in a non-cured state and includes 50 to 90% by weight, based on the reaction mixture, of an inorganic particulate filler, a crosslinking agent, and 10 to 50% by weight, based on the reaction mixture, of a binder solution. The binder solution includes a monomer and a polymer dissolved in it. The molded plastic body is characterized in that the percentage of the crosslinking agent admixed with the binder solution is more than 10% by weight based on the percentage of the monomer in the binder solution. The invention also relates to a method for producing the molded plastic body.
Type:
Grant
Filed:
October 31, 2005
Date of Patent:
October 7, 2014
Assignee:
Schock GmbH
Inventors:
Roland Reichenberger, Rudolf Paternoster, Klaus Hock
Abstract: The recycled crumb rubber coating is a corrosion-proof coating for piping and the like. The coating is formed from recycled crumb rubber mixed with an epoxy resin and a hardener. Crumb rubber is first mixed with a liquid epoxy resin. An agent for reducing the viscosity of the liquid epoxy resin may also be added. A hardener is then added to this mixture. Finally, powdered crumb rubber is added and mixed to form the recycled crumb rubber coating. The total crumb rubber forms about 23 wt % of the coating. If no viscosity reducing agent is added, then the liquid epoxy resin forms about 51.6 wt % of the coating. If the viscosity reducing agent is added, then the liquid epoxy resin forms about 50.1 wt % of the coating, and the viscosity reducing agent forms about 1.5 wt % of the coating. The hardener forms about 25.4 wt % of the coating.
Type:
Grant
Filed:
June 25, 2012
Date of Patent:
October 7, 2014
Assignee:
King Fahd University of Petroleum and Minerals
Inventors:
Nasser Al-Aqeeli, Hamoud M. Assehdi Al Hajri
Abstract: A product for pre-treatment and laundering of fabric having a stained portion. The product comprising a pourable aqueous detergent composition and a dispensing cap. The cap can have a pour volume sized and dimensioned to provide for a unit dose of the detergent composition. A portion of the cap can be provided with surface irregularities for scrubbing a stain.
Type:
Grant
Filed:
June 23, 2011
Date of Patent:
September 9, 2014
Assignee:
The Procter & Gamble Company
Inventors:
Nalini Chawla, Tom Patrick Collins, Michael David Sanders, Sherri Lynn Randall
Abstract: Use a centrifuge, especially a peeler centrifuge, that has a coarse salt particle layer deposited on its screen to effect recovery of an epoxy resin, especially a liquid epoxy resin, from a product slurry, which epoxy resin has a lower residual salt content than an epoxy resin recovered without use of the coarse salt particle layer.
Type:
Grant
Filed:
September 9, 2009
Date of Patent:
September 9, 2014
Assignee:
Dow Global Technologies LLC
Inventors:
Shuji Maeda, Ryosuke Tamai, Takashi Ikeda, Joseph Weber
Abstract: A system for use in forming polymer compositions, including as a replacement for phenolic based resin systems, for instance, in preparing foundry molds. In a preferred embodiment, the system includes the use of a) a polyermizable hydroxyl-containing component comprising a humic substance (as can be provided by lignite), b) an isocyanate component, and c) a catalyst, and preferably amine catalyst, component adapted to catalyze the polymerization of a) and b). The system is optionally used as binder system in the presence of a filler, such as, in combination with a foundry aggregate such as sand. A polymer system of this invention can be substantially free of formaldehyde or phenol, and preferably contains little or no aromatic solvents.
Type:
Grant
Filed:
November 14, 2008
Date of Patent:
August 26, 2014
Assignee:
University of Northern Iowa Research Foundation