Abstract: Disclosed is a novel positive-working chemical-amplification photoresist composition capable of giving an extremely finely patterned resist layer in the manufacturing process of semiconductor devices. The photoresist composition comprises: (A) 100 parts by weight of a copolymeric resin consisting of from 50 to 85% by moles of (a) hydroxyl group-containing styrene units, from 15 to 35% by moles of (b) styrene units and from 2 to 20% by moles of (c) acrylate or methacrylate ester units each having a solubility-reducing group capable of being eliminated in the presence of an acid; and (B) from 1 to 20 parts by weight of a radiation-sensitive acid-generating agent which is an onium salt containing a fluoroalkyl sulfonate ion having 3 to 10 carbon atoms as the anion such as bis(4-tert-butylphenyl) iodonium nonafluorobutane sulfonate.
Type:
Grant
Filed:
January 31, 2002
Date of Patent:
March 22, 2005
Assignee:
Tokyo Ohka Kogyo, Co., Inc.
Inventors:
Katsumi Oomori, Hiroto Yukawa, Ryusuke Uchida, Kazufumi Sato
Abstract: The invention provides a microfabrication process which may be used to manufacture a MEMS device. The process comprises depositing one or a stack of layers on a base layer, said one layer or an uppermost layer in said stack of layers being a sacrificial layer; patterning said one or a stack of layers to provide at least one aperture therethrough through which said base layer is exposed; depositing a photosensitive layer over said one or a stack of layers; and passing light through said at least one aperture to expose said photosensitive layer.
Abstract: The invention relates to a light sensitive photographic element comprising a support, and chemically and spectrally sensitized emulsions (A) and (B), wherein:emulsion (A) comprises a tabular silver halide emulsion population comprised of at least 50 mole percent chloride, based on silver, wherein at least 50 percent of the grain population projected area is accounted for by tabular grains bounded by {111} major faces, each having an aspect ratio of at least 2 and each being comprised of a core and a surrounding band containing a higher level of bromide or iodide ion than is present in said core, said band containing up to about 30 percent of the silver in the tabular grain;wherein said emulsion (A) has been precipitated in the presence of an organic grain growth modifier or surface stabilizer and wherein said organic grain growth modifier or surface stabilizer has been substantially removed from said emulsion (A) after the formation of said band; andemulsion (B) comprises at least 50 mole percent chloride, ba