Abstract: Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.
Type:
Grant
Filed:
July 26, 2016
Date of Patent:
December 19, 2017
Assignee:
The United States of America, as represented by the Secretary of the Navy
Abstract: Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.
Type:
Grant
Filed:
July 26, 2016
Date of Patent:
December 12, 2017
Assignee:
The United States of America, as represented by the Secretary of the Navy
Abstract: Process for curing a thermoset resin comprising the step of contacting said resin with (i) an imine of the structure C(R2)(R3)?N—R1 wherein R1 is selected from hydrogen, hydroxyl, linear or branched alkyl having 1-22 carbon atoms, cycloalkyl having 3-22 carbon atoms, aryl having 6 to 15 carbon atoms, and aralkyl having 7 to 22 carbon atoms, which alkyl, cycloalkyl, aryl, and aralkyl groups may be optionally substituted with one or more groups containing heteroatoms selected from S, O, P, and/or Si. R2 is selected from C(R6)(R5)—C(?O)—R4, —C(R6)(R5)—C(?S)—R4, and —C(R6)(R5)—C(?N)—R4, wherein R4, R5, and R6 are selected from hydrogen, linear or branched alkyl having 1-6 carbon atoms, cycloalkyl having 3-12 carbon atoms, aryl, aralkyl, alkoxy having 1-6 carbon atoms, and aryloxy. R3 is selected from linear or branched alkyl having 1-22 carbon atoms, 1 cycloalkyl having 3-22 carbon atoms, aryl having 6 to 15 carbon atoms, and aralkyl having 7 to 22 carbon atoms, and (ii) methyl isopropyl ketone peroxide.
Type:
Grant
Filed:
August 14, 2013
Date of Patent:
December 12, 2017
Assignee:
AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
Inventors:
Frederik Willem Karel Koers, Auke Gerardus Talma
Abstract: An underfill film material and a method for manufacturing a semiconductor device using the same which enables voidless mounting and favorable solder bonding properties are provided. An underfill material is used which contains an epoxy resin, an acid anhydride, an acrylic resin and an organic peroxide, the underfill material exhibits non-Bingham fluidity at a temperature ranging from 60° C. to 100° C., a storage modulus G? measured by dynamic viscosity measurement has an inflection point in an angular frequency region below 10E+02 rad/s, and the storage modulus G? in the angular frequency below the inflection point is 10E+05 Pa or more and 10E+06 Pa or less. This enables voidless packaging and excellent solder connection properties.
Abstract: The invention relates to a method of producing monodisperse amidomethylated vinylaromatic bead polymers, to ion exchangers prepared from these monodisperse amidomethylated vinylaromatic bead polymers by alkaline hydrolysis, to the method of using said monodisperse amidomethylated vinylaromatic bead polymers in the manufacture of ion exchangers and chelating resins, and also to the method of using these ion exchangers in the removal of heavy metals and noble metals from aqueous solutions or gases.
Type:
Grant
Filed:
August 8, 2014
Date of Patent:
December 5, 2017
Assignee:
LANXESS DEUTSCHLAND GMBH
Inventors:
Reinhold Klipper, Wolfgang Zarges, Olaf Halle, Michael Schelhaas
Abstract: This invention relates to a thermoplastic resin composition having excellent impact resistance and molded appearance. The thermoplastic resin is a polycarbonate, polyester-based resin or a blend of polycarbonate and a polyester-based resin containing up to 30 percent by weight of at least one core-shell impact modifier having little or no styrene in the core.
Abstract: Provided is a cation exchange membrane having a stable ion exchange performance during usage, being excellent in basic properties such as membrane resistance and ion transportation as well as strength, and useful for electrodialysis and a method for producing the same. The cation exchange membrane is composed of a polyvinyl alcohol copolymer including an anionic group-containing anionic polymer segment and a vinyl alcohol polymer segment, and having a microphase separation structure having a domain size (X) in a range from 0 nm<X?150 nm. The method is composed of forming a membrane from a polyvinyl alcohol copolymer which is adjusted to contain salts in a proportion that the salt weight (C) relative to the polyvinyl alcohol copolymer weight (P) is [(C)/(P)] of 4.5/95.5 or lower.
Type:
Grant
Filed:
April 8, 2015
Date of Patent:
December 5, 2017
Assignees:
KURARAY CO., LTD., YAMAGUCHI UNIVERSITY
Abstract: A coupling agent having at least two alkenylbenzene groups each covalently bonded with a nitrogen of an amine compound. The coupling agent can have the structure I: wherein Z is an amine; R1-R10 are each, independent of one another, H, an organic functional group or a terminal alkene, wherein at least one terminal alkene is on each benzene ring; m is an integer from 1 to 8.
Type:
Grant
Filed:
August 14, 2015
Date of Patent:
December 5, 2017
Assignee:
KRATON POLYMERS U.S. LLC
Inventors:
Adrie A. Van Der Huizen, Carl L. Willis
Abstract: Provided is a fluorine-containing resin particle dispersion including: fluorine-containing resin particles, a resin which is not dissolved in at least one solvent in a group of hydroxyl group-containing solvents including an alcohol-based solvent having 1 to 10 carbon atoms, containing no aromatic ring in the molecule structure, and a water-based medium, and which is adhered on the surface of the fluorine-containing resin particles, and at least one solvent, in which the resin is not dissolved, in the group of hydroxyl group-containing solvents, in which the fluorine-containing resin particles having the resin adhered on the surface thereof are dispersed.
Abstract: A process for the reactivation of an acidic ion exchange resin is described. The invention relates to the treatment of an at least partially deactivated resin which has been deactivated by contact with an impure ethylenically unsaturated acid or ester containing target impurities. The reactivation includes the step of contacting the at least partially deactivated resin with an alcohol to thereby increase the activity thereof. The invention extends to reactivating a resin deactivated by contact with an impure ethylenically unsaturated acid, ester or nitrile containing target impurities by contacting the at least partially deactivated resin with an alcohol and a carboxylic acid to thereby increase the activity thereof. A reactivated resin and a process for preparing and purifying an ethylenically unsaturated acid or ester of the following formula: R1—C(?(CH2)m)—COOR2 are also described.
Abstract: Disclosed herein is a composition having a plurality of particles of a filler material and crosslinking units having the formula —(SiR—CH2—CH2—CH2)—. The silicon atom in the crosslinking unit is directly or indirectly bound to the filler material. Each R is alkyl, alkenyl, phenyl, methyl, ethyl, allyl, halogen, chloro, or bromo. Also disclosed herein is a filler material having the silicon atom of a silacyclobutane group is directly or indirectly bound thereto. Also disclosed herein is a method of crosslinking silacyclobutane groups bound to a plurality of particles of a filler material. The silicon atom of the silacyclobutane group is directly or indirectly bound to the filler material. Also disclosed herein is a composition including a plurality of fibers of a polymer having reactive oxygen atoms and siloxane groups. Coordination bonds are formed between the oxygen atoms and the silicon atoms of the siloxane groups of separate fibers.
Type:
Grant
Filed:
October 27, 2015
Date of Patent:
November 14, 2017
Assignee:
The United States of America, as represented by the Secretary of the Navy
Inventors:
Duane L. Simonson, R. Andrew McGill, Bernadette A. Higgins, Michael Papantonakis
Abstract: In a first aspect, a composition of matter includes a substantially symmetrical 3-arm star block copolymer having a central core and diblock copolymer arms having inner blocks and outer blocks. In a second aspect, an article includes a substrate, a block copolymer composition on the substrate, and a neutral layer between the substrate and the block copolymer composition.
Type:
Grant
Filed:
October 27, 2016
Date of Patent:
November 14, 2017
Assignee:
E I DU PONT DE NEMOURS AND COMPANY
Inventors:
William Brown Farnham, Michael Thomas Sheehan, Hoang Vi Tran, Daqing Zhang
Abstract: The present disclosure relates to a method for regeneration of spent ion exchange resins to obtain regenerated ion-exchange resins. The regenerated ion exchange resins can efficiently reduce the total acid number (TAN) of highly acidic crude oils. The present disclosure particularly relates to a method of treatment of spent ion exchange resins using at least one non-acidic crude oil condensate and at least one polar organic solvent.
Abstract: A water repellent composition comprising a fluorinated copolymer having structural units based on a monomer (a) having a C1-6 polyfluoroalkyl group, structural units based on a monomer (b) having a C1-6 alkyl group and structural units based on a monomer (c) (halogenated olefin), and a medium, wherein the proportion of the structural units based on the monomer (a) is from 50 to 90 mass % of the structural units (100 mass %) based on all the monomers.
Abstract: The present invention provides a chromatography medium comprising one or more electrospun polymer nanofibers which form a stationary phase comprising a plurality of pores through which a mobile phase can permeate and use of the same in chromatography, such as the isolation of recombinant proteins, monoclonal antibodies, viral vaccines and plasmid DNA. The invention further provides for the use of the chromatographic medium in a simulated moving bed system.
Type:
Grant
Filed:
November 7, 2012
Date of Patent:
October 31, 2017
Assignee:
Puridify Ltd.
Inventors:
Daniel Gilbert Bracewell, Robert Stevens, Oliver Hardick
Abstract: Tetrafluoroethene-based fluoropolymers of low gel content, methods of making the fluoropolymers, methods of extruding the fluoropolymers into articles, and extruded articles comprising the fluoropolymers.
Type:
Grant
Filed:
July 16, 2013
Date of Patent:
October 31, 2017
Assignee:
3M INNOVATIVE PROPERTIES COMPANY
Inventors:
Harald Kaspar, Klaus Hintzer, Tilman C. Zipplies, Thomas J. Blong
Abstract: A process for removing metallic impurities from a product mass flow comprising water-absorbing polymer particles by means of bar magnets, wherein the water-absorbing polymer particles comprise a surfactant and have direct contact with the bar magnets.
Type:
Grant
Filed:
April 19, 2010
Date of Patent:
October 31, 2017
Assignee:
BASF SE
Inventors:
Rüdiger Funk, Jürgen Schröder, Thomas Pfeiffer, Emil Bitzer
Abstract: Disclosed is a nylon-based resin composite that has a sufficiently low moisture absorption rate to substantially prevent the occurrence of deformation and can attain both low warpage and improved impact resistance. The nylon-based resin composite comprises about 100 parts by weight of a base resin and about 1 to about 30 parts by weight of an impact modifier wherein the base resin comprises about 20 to about 80% by weight of a modified nylon-based thermoplastic resin containing benzene rings in the main chain and about 20 to about 80% by weight of a flat reinforcing fiber having a cross-sectional aspect ratio of about 1.5 or more.
Type:
Grant
Filed:
June 18, 2009
Date of Patent:
October 24, 2017
Assignee:
Lotte Advanced Materials Co., Ltd.
Inventors:
Jung Hoon Park, Young Jun Lee, Tae Uk Kim, Bum Seok Youn
Abstract: The present invention relates to ionomers comprising a reaction product of the reaction between a) a halogenated isoolefin copolymer and b) a nucleophile having no pendant vinyl group and a nucleophile comprising at least one pendant vinyl group. The present invention also relates to a method of preparing and curing these ionomers.
Type:
Grant
Filed:
December 18, 2013
Date of Patent:
October 24, 2017
Assignee:
LANXSS, Inc.
Inventors:
Dana K. Adkinson, Jacob Rawski, Sean Malmberg, Gregory J. E. Davidson