Abstract: An object of the invention is to provide a process for urethane resin production in which the molecular weight of the urethane resin can be easily controlled regardless of the kind of polyisocyanate compound and which can yield a urethane resin for use as a removable pressure-sensitive adhesive usable in extensive applications ranging from a strong-tack region to a slight-tack region.

Abstract: Disclosed are oriented films comprising toughened poly(hydroxy-alkanoic acid) resin compositions comprising poly(hydroxyalkanoic acid) and an impact modifier comprising an ethylene copolymer made from monomers (a) ethylene; (b) one or more olefins of the formula CH2?C(R3)CO2R4, where R3 is hydrogen or an alkyl group with 1-6 carbon atoms, such as methyl, and R4 is glycidyl; and optionally (c) one or more olefins of the formula CH2?C(R1)CO2R2, where R1 is hydrogen or an alkyl group with 2-8 carbon atoms and R2 is an alkyl group with 1-8 carbon atoms, such as methyl, ethyl, or butyl. The ethylene copolymer may further be made from carbon monoxide monomers. The compositions may further comprise one or more ethylene/acrylate and/or ethylene/vinyl ester polymers, ionomers, and cationic grafting agents. Also disclosed are packaging materials and containers comprising the oriented films.

Abstract: A process for adhesively bonding a substrate, using an adhesive comprising a polymer binder and a crosslinker compound I comprising carbodiimide groups, wherein the compound comprising carbodiimide groups is obtainable by reacting a) carbodiimides of 1,3-bis(1-methyl-1-isocyanatoethyl)benzene, 1,4-bis(1-methyl-1-isocyanatoethyl)benzene or a mixture thereof with b) polyalkylene oxides having at least two isocyanate-reactive groups, preferably at least two hydroxyl groups, and c) if appropriate, further compounds reactive with a) or b).

Abstract: Aspects of the invention include a method of curing a rubber composition comprising providing a rubber; intimately contacting a curative agent with the rubber; wherein the curative agent consists essentially of a phenol formaldehyde resin, a metal oxide and a carboxylic acid metal salt. Another aspect of the present invention is to a method of curing a rubber composition comprising providing a rubber; intimately contacting a curative agent with the rubber; wherein the curative agent comprises a phenol formaldehyde resin and carboxylic acid metal salt; and wherein halogen-donating species are absent from the rubber and curative agent.

Abstract: The present invention relates to a series of crosslinked silicone polymers that by virtue of the nature of the dimol alcohol undecylenic acid ester based crosslinker, have unique solubility and properties. These include improved tolerance for oily materials and improved skin feel. These polymers find use in personal care applications like pigmented products. In the personal care arena, solid products that do not experience syneresis are important. Syneresis is a condition that exists in a solid product that causes a liquid that is incompatible to ooze out, which is cosmetically unacceptable.

Abstract: A curable composition, which comprises: (A) an organic polymer having a reactive silicon-containing group, (B) a carboxylic acid and/or a metal salt of a carboxylic acid, (C) an amine compound having no reactive silicon group, (D) a silane compound substituted with an amino group and (E) a silane compound substituted with an epoxy group, wherein the ratio of the molar number (d) of all amino groups of the silane compound substituted with an amino group (D) contained in the composition to the molar number (e) of all epoxy groups of a silane compound substituted with an amino group (E) contained in the composition (i.e., the ratio of (d)/(e))) is 1 or more, and further the total amount of the component (D) and the component (E) with respect to 100 g of the component (A) is 30 mmol or more.

Abstract: An object is to provide a curable composition having a good curability by use of an organotin-free catalyst, and the object is solved by a curable composition, comprising: (A) a polymer having a silicon group which can be crosslinked through formation of a siloxane bond, (B) fluorosilanes represented by general formula (1): R14-aSiFa (1) (wherein R1's, the number of which is 4-a, are each independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, or at least one selected from the group consisting of siloxy groups represented by R23SiO— (wherein R2's are each independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms or a fluorine atom), and a is any of 1, 2 or 3), and (C) an amine based compound.

Abstract: The present invention relates to polyester polyols with low functionality and a process for their production, to prepolymers prepared from these polyester polyols and a process for their production, and to polyurethanes prepared from these polyester polyols and/or from these prepolymers, and to processes for their production. These polyester polyols are produced in a two-step process. In the second step of this two-step process, one or more cyclic ester monomers is reacted with one or more polyester polyols at low temperatures.

Abstract: The invention relates to novel phosphorus-containing dendrimers having a core, at least one generation and an external layer consisting, completely or partly, of identical or different units, the said units satisfying the following formula (I): in which R1 and R2, which may be identical or different, are alkyl, alkoxy or aryl groups. These dendrimers are used for extracting actinides and lanthanides from aqueous solutions containing them.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The coating is a high adhesive strength acrylate-based coating that contains a small quantity of a polycarbonate-based TPU. The coating is applied to produce an intermediate imbibable bifocal surface. A photochromic solution is subsequently imbibed by contact with the bifocal surface.

Abstract: A flame retardant polyester fiber for artificial hair, which is obtained by melt spinning a composition as a mixture of 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate and a copolymer polyester comprising polyalkylene terephthalate as a main component with 5 to 30 parts by weight of (B) a brominated epoxy flame retardant. The present invention also relates to the polyester fiber for artificial hair which has at least one modified cross-section, is a mixture with a fiber having a modified cross-section, and has a mixing ratio of the fiber having a round cross-section to the fiber having a modified cross-section is 8:2 to 1:9, and to the flame retardant polyester fiber for artificial hair which further comprises a hydrophilic fiber treating agent attached thereto, and thus has excellent smooth feeling, combing properties, and flame retardance.

Abstract: A flame retardant polyester fiber for artificial hair, which is obtained by melt spinning a composition as a mixture of 100 parts by weight of (A) a polyester made of one or more of polyalkylene terephthalate and a copolymer polyester comprising polyalkylene terephthalate as a main component with 5 to 30 parts by weight of (B) a brominated epoxy flame retardant. The present invention also relates to the polyester fiber for artificial hair which has at least one modified cross-section, is a mixture with a fiber having a modified cross-section, and has a mixing ratio of the fiber having a round cross-section to the fiber having a modified cross-section is 8:2 to 1:9, and to the flame retardant polyester fiber for artificial hair which further comprises a hydrophilic fiber treating agent attached thereto, and thus has excellent smooth feeling, combing properties, and flame retardance.

Abstract: A solventless silicone pressure-sensitive adhesive composition is provided. The composition includes (A) a polyorganosiloxane with a polymerization degree of 300 to 2,000 and having at least two alkenyl group-containing organic groups, (B) a polyorganohydrosiloxane having at least three silicon-bonded hydrogen atoms, (C) a polydiorganosiloxane having alkenyl groups at both terminals, (D) a polydiorganosiloxane having SiH groups at both terminals, (E) a polyorganosiloxane composed of R23SiO1/2 units and SiO2 units (R2 is a monovalent hydrocarbon group), and (F) a platinum-based catalyst. The composition enables the prevention of problems caused by residual or volatilized organic substances, such as the absorption of ultraviolet radiation or the like, and also enables ready removal of the composition without deforming or damaging the adherend.

Abstract: The present invention relates to novel coating compositions comprising polyisocyanates, aliphatic oligocarbonate polyols, oligoester polyols and polyacrylate polyols, to a process for their production and to their use in the production of coatings.

Abstract: The present invention relates to a series of crosslinked silicone polymers that by virtue of the nature of the crosslinking undecylenic acid ester based crosslinker, have unique solubility and properties. These include improved tolerance for oily materials and improved skin feel. These polymers find use in personal care applications like pigmented products. In the personal care arena, solid products that do not experience syneresis are important. Syneresis is a condition that exists in a solid product that causes a liquid that is incompatible to ooze out, which is cosmetically unacceptable.

Abstract: A novel class of proton exchange membrane materials, sulfonated poly(phthalazinones), were prepared by modification of poly(phthalazinone). Sulfonation reactions were conducted at room temperature using mixtures of 95-98% concentrated sulfuric acid and 27-33% fuming sulfuric acid with different acid ratios in order to get SPPEK with degree of sulfonation (DS) in the range of 0.6 to 1.0. The presence of sulfonic acid groups was confirmed by FT-IR analysis, and the DS and structures were characterized by NMR. The introduction of sulfonic groups into the polymer chains led to an increase in the glass transition temperature and a decrease in the decomposition temperature. Membrane films were cast from solution in N,N-dimethylformamide or N,N-dimethylacetamide. Water uptakes and swelling ratios of the membrane films increased with DS and sulfonated polymers with DS>1.2 were water soluble at 80° C. Proton conductivity increased with DS and temperature up to 95° C., reaching 10?2 S/Cm.

Abstract: A two package type clear coating composition which can form cured coating film excelling in all aspects of scratch resistance, acid resistance, stain resistance and finished appearance such as coated surface smoothness, comprising a hydroxyl-containing acrylic resin (A) having a hydroxyl value of 100-200 mgKOH/g and a number-average molecular weight of 5,000-10,000, which is obtained by copolymerization of a monomeric mixture comprising an aromatic vinyl monomer and a monomer having cyclohexyl ring; a trifunctional HMDI isocyanurate compound (B); and a polyester polyol (C) having a hydroxyl value of 250-350 mgKOH/g and a number-average molecular weight of 350-550, which is obtained by esterification reaction of C3-6 diol with dicarboxylic acid having cyclohexyl ring.

Abstract: Capped poly(arylene ether)s are prepared by a method that includes reacting a poly(arylene ether) with a capping agent to form a capping reaction mixture, washing the capping reaction mixture with a concentrated basic aqueous solution, and isolating the capped poly(arylene ether) by a total isolation method. The washing method is effective for removal of capping-related impurities, and surprisingly does not result in decomposition of the capped poly(arylene ether).