Abstract: Poly(propylene carbonates) are prepared from propylene oxide and CO2 with less than 10% cyclic propylene carbonate by product using cobalt based catalysts of structure preferably in combination with salt cocatalyst, very preferably cocatalyst where the cation is PPN+ and the anion is Cl? or OBzF5?. Novel products include poly(propylene carbonates) having a stereoregularity greater than 90% and/or a regioregularity of greater than 90%.
Type:
Grant
Filed:
October 6, 2005
Date of Patent:
December 4, 2007
Assignee:
Cornell Research Foundation, Inc.
Inventors:
Geoffrey W. Coates, Zengquan Qin, Claire Tova Cohen