Abstract: A solid ion conductive material can include a complex metal halide. The complex metal halide can include at least one alkali metal element. In an embodiment, the solid ion conductive material including the complex metal halide can be a single crystal. In another embodiment, the ion conductive material including the complex metal halide can be a crystalline material having a particular crystallographic orientation. A solid electrolyte can include the ion conductive material including the complex metal halide.
Type:
Grant
Filed:
April 14, 2021
Date of Patent:
May 7, 2024
Assignee:
SAINT-GOBAIN CERAMICS & PLASTICS, INC.
Inventors:
Vladimir Ouspenski, Gaurav Assat, John M. Frank
Abstract: A positive electrode active material includes positive electrode active material particles including a composite oxide with a hexagonal crystal structure. The composite oxide includes Li, Co, and at least one element M1 selected from the group consisting of Ni, Fe, Pb, Mg, Al, K, Na, Ca, Si, Ti, Sn, V, Ge, Ga, B, As, Zr, Mn and Cr, and the at least one element M1 is provided on a surface of the positive electrode active material particles. An atomic ratio of a total amount of the at least one element M1 to an amount of Co on the surface of the positive electrode active material particles is from 0.6 to 1.3.
Type:
Grant
Filed:
December 15, 2020
Date of Patent:
April 30, 2024
Assignee:
Murata Manufacturing Co., Ltd.
Inventors:
Yuki Niwata, Asuki Yanagihara, Ravi Gehlot, Yosuke Hosoya
Abstract: An electrolyte for a lithium secondary battery and a lithium secondary battery including the same are disclosed herein. In some embodiments, an electrolyte for a lithium secondary battery includes a lithium salt, a non-aqueous solvent containing a fluorine-based organic solvent, and a fluorine-based compound represented by Formula 1. In some embodiments, a lithium secondary battery includes a positive electrode, a negative electrode, a separator disposed therebetween, and the electrolyte.
Type:
Grant
Filed:
August 26, 2020
Date of Patent:
April 30, 2024
Assignee:
LG Energy Solution, Ltd.
Inventors:
Sol Ji Park, Kyoung Ho Ahn, Jun Hyeok Han, Chul Haeng Lee
Abstract: A non-aqueous electrolyte solution for a lithium secondary battery and a lithium secondary battery including the same are disclosed herein. In some embodiments, a non-aqueous electrolyte solution includes a lithium salt, an organic solvent, and a phosphoric acid-based additive-represented by Formula 1 below, which improves the high temperature stability in a lithium secondary battery: wherein R is described herein.
Abstract: This application provides a positive electrode plate and an electrochemical apparatus containing such positive electrode plate. The positive electrode plate includes a positive electrode current collector, a positive electrode active material layer disposed on at least one surface of the positive electrode current collector, and a safety layer disposed between the positive electrode active material layer and the positive electrode current collector. The safety layer includes a binding substance, a conductive substance, and a special sensitive substance. Each molecule of the special sensitive substance includes monosaccharide structural units, and carbonate groups and/or phosphate groups; and at least part of the carbonate groups and/or phosphate groups are bonded to two or more of the monosaccharide structural units. The electrochemical apparatus prepared by using the positive electrode plate of this application has significantly improved safety and electrical performance (such as cycling performance).
Abstract: A positive electrode active material precursor having a uniform particle size distribution and represented by Formula 1, wherein a percentage of fine powder with an average particle diameter (D50) of 1 ?m or less is generated when the positive electrode active material precursor is rolled at 2.5 kgf/cm2 is less than 1%, and an aspect ratio is 0.93 or more, and a method of preparing the positive electrode active material precursor [NixCoyM1zM2w](OH)2 ??[Formula 1] in Formula 1, 0.5?x<1, 0<y?0.5, 0<z?0.5, and 0?w?0.1, M1 includes at least one selected from the group consisting of Mn and Al, and M2 includes at least one selected from the group consisting of Zr, B, W, Mo, Cr, Nb, Mg, Hf, Ta, La, Ti, Sr, Ba, Ce, F, P, S, and Y. A method of preparing the positive electrode active material precursor is also provided.
Type:
Grant
Filed:
December 7, 2018
Date of Patent:
April 30, 2024
Assignee:
LG Chem, Ltd.
Inventors:
Seong Bae Kim, Yi Rang Lim, Kyoung Wan Park, Hyun Uk Kim, Hong Kyu Park, Chang Jun Moon, Eun Hee Kim
Abstract: Provided herein are compositions which are useful as electrolytes and/or catholytes in an electrochemical cell that includes a solid-state separator and a lithium-metal anode.
Abstract: Provided are a negative electrode active material which includes negative electrode active material particles which includes a silicon oxide (SiOx, 0<x?2); and at least one lithium silicate selected from Li2SiO3, Li2Si2O5, and Li4SiO4 in at least a part of the silicon oxide. The negative electrode active material particles have a maximum peak position by a Raman spectrum of more than 460 cm?1 and less than 500 cm?1. Also provided are a method of preparing the same, and a negative electrode and a lithium secondary battery including the negative electrode active material.
Type:
Grant
Filed:
May 20, 2021
Date of Patent:
April 16, 2024
Assignee:
SK On Co., Ltd.
Inventors:
Eunjun Park, Joon-Sup Kim, Gwi Ok Park, Jeongbae Yoon, Suk Chin Lee, Hansu Kim, Donghan Youn, Dong Jae Chung
Abstract: Stainless steel for a fuel cell separator plate and a manufacturing method therefor are disclosed. The stainless steel for a fuel cell separator plate, according to one embodiment of the present invention, comprises: a stainless base material; and a passive film formed on the stainless base material, wherein a Cr/Fe atomic weight ratio in a 1 nm or less thickness region of the stainless base material, which is adjacent to an interface between the stainless and the passive film, is 0.45 or more. Therefore, by modifying the surface of the stainless steel for a fuel cell separator plate, a low interface contact resistance and a good corrosion resistance can be obtained, and a separate additional process such as precious metal coating can be removed, such that manufacturing costs are reduced and productivity can be improved.
Type:
Grant
Filed:
July 29, 2016
Date of Patent:
March 5, 2024
Assignee:
POSCO CO., LTD
Inventors:
Kwang Min Kim, Jong Hee Kim, Ki Hoon Jo, Bo Sung Seo
Abstract: The present invention relates to a lithium secondary battery which includes a positive electrode, a negative electrode, a separator disposed between the positive electrode and the negative electrode, and an electrolyte solution, wherein a patterned gel polymer electrolyte layer is included on one surface or both surfaces of at least one structure of the positive electrode, the negative electrode, or the separator.
Abstract: A positive electrode active material includes a core and a coating layer disposed on the core, wherein the core includes Li1+xMO2+y, wherein M is at least one element selected from the group consisting of nickel (Ni), cobalt (Co), and copper (Cu), and 1?x?5 and 0?y?2, and the coating layer includes carbon-based particles, wherein the carbon-based particle includes a structure in which a plurality of graphene sheets are connected, the carbon-based particle has an oxygen content of 1 wt % or more in the carbon-based particle, and the carbon-based particle has a D/G peak ratio of 1.55 or less during Raman spectrum measurement. A method of preparing the positive electrode active material, a positive electrode including the positive electrode active material, and a secondary battery including the positive electrode are also provided.
Type:
Grant
Filed:
April 5, 2019
Date of Patent:
February 6, 2024
Inventors:
Seul Ki Kim, Hye Lim Jeon, Tae Gon Kim, Wang Mo Jung, Sang Wook Lee
Abstract: A battery pack for powering an electrical device, comprising: a housing for a plurality of electrochemical cells, each having an elongate body with terminals at either end thereof; and electrical circuitry for coupling in series or parallel the plurality of electrochemical cells in the housing to electrical contacts of the electrical device; wherein the housing comprises: a first part having a body defining a chamber with an opening, the body being configured to retain the plurality of electrochemical cells side by side in the chamber, with one terminal of each cell facing towards the opening; and a second part comprising a filter and at least one vent, with the second part being configured to cover the opening of the chamber when coupled to the first part such that any combustion gases generated in the chamber by electrochemical cell malfunction pass through the opening and the filter before being vented externally of the housing through the at least one vent.
Abstract: A positive electrode active material precursor for a non-aqueous electrolyte secondary battery, including a nickel composite hydroxide particle, is provided, wherein a cross section of the nickel composite hydroxide particle includes a void, a ratio of an area of the void to the cross section of the nickel composite hydroxide particle is less than or equal to 5.0%, a circular region having a radius of 1.78 ?m is set at a position where a ratio of an area of the void to the circular region is maximum, on the cross section of the nickel composite hydroxide particle, and the ratio of the area of the void to the circular region is less than or equal to 20%.
Abstract: An electrolyte and a lithium secondary battery including the same are disclosed herein. In some embodiments, an electrolyte includes a lithium salt, an organic solvent, and an additive, wherein the additive includes a compound represented by Formula 1. In some embodiments, a lithium secondary battery includes a positive electrode, a negative electrode, and the electrolyte.
Type:
Grant
Filed:
April 1, 2020
Date of Patent:
January 16, 2024
Assignee:
LG Energy Solution, Ltd.
Inventors:
Hyun Seung Kim, Chul Haeng Lee, Jeong Woo Oh
Abstract: Disclosed are a pre-lithiated lithium ion positive electrode material, a preparation method therefor and use thereof. The lithium ion positive electrode material has a chemical formula of Li2O/[A(3-x)Mex]1/3-LiAO2, wherein A comprises M, and wherein M is at least one of Ni, Co, and Mn; and wherein Me is at least one of Ni, Mn, Al, Mg, Ti, Zr, Y, Mo, W, Na, Ce, Cr, Zn or Fe; and wherein 0<x<0.1. The material is co-doped with multiple elements, and these elements act synergistically to inhibit the irreversible phase change at a high voltage and improve the stability of the structure of a substrate. The spinel phase A(3-x)MexO4 structure contains the doping elements, which work together to improve the interfacial activity of the material and introduce more electrochemically active sites.
Abstract: A halide solid electrolyte material according to the present disclosure is represented by the chemical formula Li6?(4+a)b(Zr1?aMa)bX6, wherein M denotes at least one element selected from the group consisting of Ta and Nb, X denotes at least one halogen element, and two mathematical formulae 0<a<1 and 0<b<1.5 are satisfied.
Abstract: An amorphous composite solid electrolyte is provided that includes one or more three-dimensional branched macromolecules with a core portion and at least three arm portions connected to the core portion. Each arm portion includes a random copolymer or a block polymer comprising a first monomer and a second monomer with a molar ratio of the first monomer to the second monomer in the range from greater than 0 to less than or equal to 1. An ion conductive electrolytic solution including at least one lithium salt solution in an amount of approximately 1 mol/l to 10 mol/l is entrained within the branched macromolecule, with a weight ratio of the branched macromolecule to the ion conducive electrolytic solution equal to or lower than 1:9, such that the branched macromolecule has a swelling degree of at least 5:1 (liquid:polymer in weight) of the ion conductive electrolytic solution.
Type:
Grant
Filed:
December 20, 2020
Date of Patent:
November 28, 2023
Assignee:
Nano and Advanced Materials Institute Limited
Inventors:
Hui Pan, Jianping Han, Yong Zhu, Heng Liu, Ou Dong, Shengbo Lu, Chenmin Liu
Abstract: The present invention provides a rechargeable lithium-ion battery with an in situ thermally-curable electrolyte. The thermally-curable electrolyte is cured from the thermally-curable electrolyte precursor solution including a first crosslinking agent, a second crosslinking agent, an initiator, an electrolyte solvent, an electrolyte salt, one or more electrolyte additives, and one or more monomers or a monomer polymerization product. The viscosity of the thermally-curable electrolyte precursor solution is below 200 cps such that the thermally-curable electrolyte precursor solution is infiltrated within the separator and the pores inside the cathode and anode layers then cured to form porous separator and porous electrodes fully permeated with a solid electrolyte.
Type:
Grant
Filed:
August 29, 2021
Date of Patent:
November 21, 2023
Assignee:
Nano and Advanced Materials Institute Limited
Inventors:
Ou Dong, Sing Ho Lo, Zhengfu Qiu, Wing Lung Hon, Jianping Han, Yong Zhu, Shengbo Lu, Chenmin Liu
Abstract: Provided is carbonaceous substance-coated graphite particles that exhibit excellent battery properties when used as a negative electrode material for a lithium ion secondary battery. The carbonaceous substance-coated graphite particles includes: graphite particles; and carbonaceous coatings covering at least part of surfaces of the graphite particles, and the carbonaceous substance-coated graphite particles have a specific surface area SBET determined by BET method of 4.0 to 15.0 m2/g, and a pore volume Vs of pores with a pore size of 7.8 to 36.0 nm is 0.001 to 0.026 cm3/g, and in a pore size distribution graph with the pore size being plotted on a horizontal axis and a dV/dP value obtained by differentiating the pore volume with the pore size being plotted on a vertical axis, a pore size Pmax with which the dV/dP value is maximized is 2.5 to 5.5 nm.
Type:
Grant
Filed:
July 28, 2022
Date of Patent:
October 31, 2023
Assignees:
JFE Chemical Corporation, JFE Steel Corporation
Abstract: Provided are carbonaceous substance-coated graphite particles that include: graphite particles; and carbonaceous coatings covering at least part of surfaces of the graphite particles, the carbonaceous substance-coated graphite particles have a maximum particle diameter of 30.0 to 90.0 ?m, a pore volume Vs of pores with a pore size of 7.8 to 36.0 nm is 0.009 to 0.164 cm3/g, and in a pore size distribution graph with the pore size being plotted on a horizontal axis and a dV/dP value obtained by differentiating the pore volume with the pore size being plotted on a vertical axis, a pore size Pmax with which the dV/dP value is maximized is 2.5 to 5.5 nm.
Type:
Grant
Filed:
July 28, 2022
Date of Patent:
October 31, 2023
Assignees:
JFE Chemical Corporation, JFE Steel Corporation