Abstract: This invention discloses the production and use of a polyethylene composition comprising a metallocene-produced linear low density polyethylene and a multi modal high density polyethylene prepared from either a Ziegler-Natta or a metallocene catalyst system. The resulting polyethylene composition is suitable for preparing articles having improved environmental stress crack resistance, rigidity, contact transparency, gloss as well as good processing capabilities.

Abstract: A process for the preparation of an oligonucleotide is provided. The process comprises the assembly of an oligonucleotide attached to a solid support, wherein the solid support is prepared by a process comprising polymerisation of a monomer which comprises a protected hydroxypolyC2-4 alkyleneoxy chain attached to a polymerisable unit wherein the protected hydroxypolyC2-4 alkyleneoxy chain contains from 2 to 10 C2-4 alkyleneoxy groups and wherein the hydroxypolyC2-4 alkyleneoxy chain is protected with an acid-labile protecting group, preferably an optionally substituted trityl group.

Abstract: A polymer electrolyte fuel cell comprising a membrane-form polymer electrolyte, a cathode disposed on one side of the polymer electrolyte, and an anode disposed on the other side of the polymer electrolyte, wherein the cathode comprises a catalyst and an ion exchange resin, and the ion exchange resin is made of a polymer comprising the following segments A and segments B: Segments A: segments made of a polymer having sulfonic acid groups; and Segments B: segments made of a fluoropolymer having substantially no ion exchange groups.

Abstract: There are disclosed star shaped thermoplastic elastomers made of acrylic block copolymers obtained by transition metal catalysed radical polymerisation. The elastomers comprise core arms obtained from monomers or mixture of monomers, whose Tg is from about ?65° C. to about ?20° C., and of shell arms obtained from monomers or mixture of monomers, whose Tg is from about 70° C. to about 160° C. The core copolymer has a polydispersity of 2 or higher and the final copolymer has a polydispersity of from 3 to 10.

Abstract: A novel method of preparing carboxyl-terminated polymers. A monomer is mixed with an organolithium initiator in a hydrocarbon solvent so as to anionically polymerize linear living polymer lithium chains. A trialkyl aluminum compound is also mixed so as to form polymer lithium: aluminate complexes in equilibrium with the linear living polymer lithium chains. When a cyclic anhydride terminator is mixed, the cyclic anhydride terminator preferentially reacts with the C—Li center on a living polymer lithium chain rather than with the C—Al—Li center on a polymer lithium: aluminate complex.

Abstract: Regioregular poly(3-alkylthiophenes) and other polythiophenes can be prepared by living polymerization which have good solubility, processability and environmental stability. The polymerization method can afford regioregular poly(3-alkylthiophenes) in high yields. Kinetic study of polymerization revealed the living character of this process. The molecular weight of poly(3-alkylthiophenes) is a function of the molar ratio of the monomer to nickel initiator, and conducting polymers with relatively narrow molecular weight distribution (PDI<1.5) are now readily available. Sequential monomer addition resulted in new block copolymers containing different poly(3-alkylthiophene) segments, which further confirms the “livingness” of this system. Other synthetic methods can be used as well to conduct living polymerization. Blends and electronic devices can be prepared.

Abstract: A polyesterified block copolymer represented by the general formula (1), (2) or (3) (for example, polyolefin/polyolefin block copolymer of the following general formula (1)), obtained by an esterification reaction between a terminal maleated polymer and a terminal hydroxylated polymer. Also, a process for producing the same is provided. (1) wherein each of R1 and R2 represents hydrogen or methyl; m is an integer of 10 to 200; n is an integer 10 to 200; k is an integer 5 of to 3000.

Abstract: The present invention relates to an aminomethyl polystyrene resin wherein aminomethyl group is grafted only on the surface of polystyrene resin, and a preparation process for the same. More particularly, the present invention is directed to a process for preparing aminomethyl polystyrene resin wherein aminomethyl group is grafted only on the surface of polystyrene resin, which comprises a step for grafting amidomethyl group to surface of polystyrene resin and a step for hydrolysis of the amidomethyl group grafted on the surface of polystyrene resin.

Abstract: Disclosed is an elastomeric hydrogenated block copolymer capable of being directly extruded or molded with a minimum of additives and having both high elasticity and low permanent set. The hydrogenated block copolymers have high melt flows allowing for ease in processing the hydrogenation block copolymers in melt processes such as extrusion and molding.

Abstract: Articles made from propylene ethylene copolymers with an ethylene content between 8 and 32 mole % have been grafted with maleic anhydride and a peroxide. The functionality level is higher than what is reported with polypropylene.

Abstract: This invention relates to preparation of rubber compositions comprised of EPDM and conjugated diene-based elastomer, particularly including cis 1,4-polyisoprene rubber, and particularly natural cis 1,4-polyisoprene rubber, blends and pneumatic rubber tire with an outer, visible sidewall layer of a rubber composition comprised of such rubber composition. For such preparation, a combination of at least two diverse EPDM elastomers is used together with a phase mixing process comprised of sequential phase mixing or parallel phase mixing in the sense of reinforcement filler and sulfur curatives.

Abstract: A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.

Abstract: Graft copolymers with segmented (or block) arms and a process for preparing the same. Such polymers are particularly useful in formulating air-dry clear coat and color coat lacquers used in automotive refinishing.

Abstract: An object of the present invention is to provide a novel solid reagent capable of solving the problems of conventional solid reagents based on resin beads. The present invention relates to a solid reagent comprising an organic polymer base in which a polymer side chain is introduced onto the backbone of the organic polymer base via graft polymerization and a reactive functional group is introduced onto the polymer side chain. The organic polymer base is preferably in the form of a fiber, a woven or nonwoven fabric consisting of an assembly of fibers, a porous membrane or a hollow fiber membrane. The graft polymerization is preferably a radiation-induced graft polymerization. Solid reagents according to the present invention can be used in various organic synthetic reactions.

Abstract: To provide a block copolymer composition having a good balance in transparency and impact resistance, and particularly having an excellent impact resistance, by making a molded product of injection molding under high sear condition in such a manner as to hardly generate anisotropy. A block copolymer composed of a hard segment block comprising a block made mainly of a vinyl aromatic hydrocarbon and a soft segment block comprising a block made mainly of a conjugated diene, characterized by having a remarkably improved impact resistance without degrading transparency in respect of not only an extrusion-molded product and a blow-molded product but also an injection-molded product, by blending two kinds of block copolymers having a hard segment block of a specific structure.

Abstract: A rubber composition for a base tread which achieves improved steering stability and rolling resistance properties and a tire containing the same wherein the rubber composition includes a rubber component containing (a) 20 to 60% by weight of a polybutadiene rubber containing 2.5 to 20% by weight of a 1,2-syndiotactic polybutadiene crystal, (b) 5 to 80% by weight of a tin-modified polybutadiene rubber polymerized by a lithium initiator, in which the amount of a tin atom is 50 to 3000 ppm, the amount of a vinyl bond is 5 to 50% by weight and molecular weight distribution (Mw/Mn) is at most 2, and (c) 10 to 75% by weight of a rubber other than (a) and (b).

Abstract: The method for manufacturing a thermoplastic elastomer composition of the present invention comprises continuously feeding a mixture comprising pelletized olefinic resin (A), a pulverized product (B) obtained by pulverizing bulk olefinic rubber, and a crosslinking agent (C) into a continuous kneading machine, and performing a dynamic heat treatment to yield the thermoplastic elastomer composition. An olefinic thermoplastic elastomer composition having excellent tensile characteristics and molded appearance can be manufactured with high productivity by the method of the present invention.

Abstract: A pressure sensitive adhesive is described comprising an acrylate copolymer, silica nanoparticles and crosslinked by a polyfunctional aziridine crosslinking agent.

Abstract: Various embodiments of the present invention are directed to methods for manufacturing complex, anisotropic materials with desirable properties for information storage, processing, and display. Certain of these methods involve employing a magnetic field during manufacture to induce desired orientations of precursors, subunits, and/or molecular subassemblies. The applied magnetic field steers the precursors, subunits, and/or molecular subassemblies into desirable orientations while the precursors, subunits, and/or molecular subassemblies are assembled or self-assemble into a complex, anisotropic material. One embodiment of the present invention is a class of new, complex, well-ordered, network-like materials that include a ferromagnetic-material-based framework in which organic and/or organometallic compounds are organized.

Abstract: A thermoplastic elastomer composition comprises a blend of a thermoplastic component with a cured elastomer component characterised in that the elastomer component prior to curing comprises a major proportion of a main elastomer and a minor proportion of a high molecular weight reactive polymer which shows a higher crosslinking efficiency in free-radical induced vulcanisation than the main elastomer. Preferably, the high molecular weight reactive polymer comprises from (3) to (15), and more preferably (4) to (10), parts by weight per one hundred parts of the total elastomer component of the composition. The use of the high molecular weight reactive polymer in the composition improves the low temperature performance of the composition and gives improvements to the processing behaviour, the resistance to stiffening at low temperatures and recovery/relaxation properties. Preferably, the high molecular weight reactive polymer is miscible with the main elastomer in the elastomer component.