Abstract: A polyisocyanate compound obtained by highly converting a bis(isocyanatomethyl)cyclohexane into a uretidione compound, a process for producing the compound, a polyisocyanate polyaddition composition obtained by polyaddition of the compound, a compound having at least two hydroxyl groups and a compound having one hydroxyl group, and a powder coating material using the composition as the curing agent. The powder coating material is advantageous for safety and health due to the absence of dissociation of blocking agents and for economy due to a content of latent NCO greater than conventional uretidione-based powder coating materials.
Abstract: A curative blend for a thermosetting polyurethane material that allows for a polyurethane material with greater durability is disclosed herein. The curative blend is composed of 4,4?-methylenebis-(2,6-diethyl)-aniline and a second curing agent. A preferred polyurethane prepolymer is a polytetramethylene ether glycol terminated 4,4?-dicyclohexyl methane diisocyanate polyurethane prepolymer. The thermosetting polyurethane is preferably utilized as a cover for a golf ball. The cover is preferably formed over a core and boundary layer.
Abstract: Ytterbium(III) acetylacetonate is used as a catalyst for the preparation of aliphatic oligocarbonate polyols by transesterification of at least one organic carbonate with at least one aliphatic polyol.
Abstract: An adhesive, sealant or coating composition that includes: a) 20 to 80% by weight, based on the weight of a), b), and c) of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, b) 20 to 80% by weight, based on the weight of a), b), and c) of a polyether urethane containing one reactive silane group and one or more polyether segments, and c) 1 to 60% by weight, based on the weight of a), b), and c) of a pigment having a BET surface area of from 15 to 100 m2/g and an oil absorption of from 40 to 110 cc/100 g; where the sum of a), b), and c) does not exceed 100% by weight. The composition can be used to bond and/or coat substrates.
Type:
Grant
Filed:
April 28, 2004
Date of Patent:
June 13, 2006
Assignee:
Bayer MaterialScience LLC
Inventors:
Craig E. Jansen, Kurt C. Frisch, Richard R. Roesler, Dinesh Pethiyagoda, Kevan E. Hudson
Abstract: Black polyurethane foams that exhibit higher strength black colorations without the need for concomitant increases in black colorants therein are provided. Such a resultant jetter black foam article is possible through the unexpectedly effective introduction of small amounts of certain toner compounds or combinations that exhibit specific measurable appearance characteristics. Such toners exhibit at least one absorption peak within a specific range of wavelengths (e.g., from about 560 to 610 nm) and specific ranges of half-height bandwidths (from 40 to 130 nm). Furthermore, such a compound or combination of compounds, is preferably liquid in nature (at room temperature) or in dispersion form and may thus be easily incorporated within target polyurethane precursor compositions for admixture with either black pigments (or dispersions thereof), black polymeric (liquid) colorants, or both.
Abstract: The invention relates to novel blocked polyurethane prepolymers, to a process for their preparation, to reactive systems prepared therefrom that cure at room temperature, and to their use.
Type:
Grant
Filed:
December 17, 2003
Date of Patent:
June 6, 2006
Assignee:
Bayer Aktiengesellschaft
Inventors:
Kamelia Detig-Karlou, Joachim Simon, Michael Mager, Thomas Stingl, Christoph Gürtler, Michael Schelhaas
Abstract: A process for the production of compounds which contain at least one urea group and at least one silyl group. The process involves reacting a compound containing at least one amino group and a carbamate compound. The compounds produced by this process are useful as surface coating compositions, foams and adhesives.
Type:
Grant
Filed:
October 24, 2001
Date of Patent:
June 6, 2006
Assignee:
Henkel Kommanditgesellschaft auf Aktien (Henkel KGAA)
Inventors:
Thomas Bachon, Wilfried Huebner, Hermann Kluth, Wolfgang Klauck, Johann Klein
Abstract: Isocyanate-functional polyurethane prepolymers and aqueous dispersions therefrom which are useful for the production of flat materials having excellent resistance to alcoholic solvents are described. The prepolymers are prepared by reacting: A) an isocyanate selected from the group consisting of i) an aliphatic and/or a cycloaliphatic isocyanate, ii) a mixture of an aromatic isocyanate and an aliphatic and/or a cycloaliphatic isocyanate, B) a di- or polyhydroxy compound having a number average molecular weight of from 700 to about 16,000, and C) optionally, a dihydroxy and/or polyhydroxyl compound having a number average molecular weight of less than 700, with the provisos that a) at least one of components A), B or C) has a functionality of more than 2 and b) if both component A) and component B) are difunctional, component C) cannot be a trihydroxy component of the formula: R—(OH)3 ?where R is a saturated straight chain or branched chain aliphatic group of from 2 to 8 carbon atoms.
Type:
Grant
Filed:
October 2, 2003
Date of Patent:
May 16, 2006
Assignees:
Bayer MaterialScience LLC, Bayer MaterialScience AG
Inventors:
Eduard Mayer, Thomas Muenzmay, Yuliya Berezkin, Poli C. Yu, Richard R. Roesler, Mary A. Crisci
Abstract: The present invention provides a thermoplastic composite comprising: a polyolefin; a cellulosic filler; a carboxylic acid and/or carboxylic acid anhydride graft polyolefin having an acid number greater than 15 mgKOH/g; and, a basic reactive filler present in an amount of 5–25 wt %, based on the weight of the composite. Such composites may be used in structural and non-structural applications and exhibit improved mechanical properties, thermal properties and/or resistance to biological degradation.
Abstract: The present invention relates to novel one-component polyurethane systems including one or more organic and/or inorganic compounds of vanadium in which the vanadium has an oxidation state of at least +4, to their preparation and use for preparing paints, inks and adhesives.
Type:
Grant
Filed:
February 20, 2004
Date of Patent:
May 9, 2006
Assignee:
Bayer Materialscience AG
Inventors:
Christoph Gürtler, Jan Mazanek, Joachim Petzoldt, Heinz Schmidt, Stephan Nowak
Abstract: Polyurethane elastomers are formed from first and second graft curatives, each graft curative having a molecular weight of at least about 800, wherein the first and second graft curatives are substantially immiscible with one another, and wherein the polyurethane elastomer exhibits a hardness of less than about 40 Shore A according to ASTM D2240-86 and a compression set of less than about 8% according to ASTM D395-89, method B, at a temperature of about 70° C. for about 22 hours. Rolls are manufactured using such polyurethane elastomers, particularly rolls that are suitable for use in image forming devices, such as electrophotographic print applications.
Type:
Grant
Filed:
January 13, 2004
Date of Patent:
April 25, 2006
Assignee:
Lexmark International, Inc.
Inventors:
Bradley L. Beach, Bhaskar Gopalanarayanan, Kelly A. Killeen, Johnny D. Massie, II, Ronald L. Roe
Abstract: The present invention relates to an improved process for the production of carbodiimide modified organic isocyanate, preferably a polymethylene polyphenylisocyanate, and most preferably diphenylmethane diisocyanate. This process includes (1) neutralizing acidic impurities in an organic isocyanate, (2) partially carbodiimidizing isocyanate groups of the neutralized organic isocyanate, and (3) terminating the carbodiimidization reaction.
Type:
Grant
Filed:
June 17, 2004
Date of Patent:
April 18, 2006
Assignee:
Bayer MaterialScience LLC
Inventors:
James William Rosthauser, James Thomas Garrett, Jeffrey S. Bolton
Abstract: Disclosed herein is a method of making a golf ball by mixing a polyisocyanate copolymer and at least one other reactant, such as a polyol, to form a reaction product and reaction injection molding the reaction product to form at least one of a core and cover component. Preferably, the polyisocyanate copolymer includes an aromatic polyisocyanate and an aliphatic polyisocyanate. Most preferably, the polyisocyanate copolymer includes a copolymer of toluene diisocyanate and hexamethylene diisocyanate.
Type:
Grant
Filed:
April 2, 2004
Date of Patent:
April 11, 2006
Assignee:
Callaway Golf Company
Inventors:
Viktor Keller, Thomas J. Kennedy, III, William M. Risen, Jr., Michael J. Tzivanis
Abstract: Viscoelastic foams and elastomers based on a reaction system comprising a monomeric polyisocyanate composition, a specified mixture of polyols, and a specified package of additives. The viscoelastic materials offer superior combinations of physical properties, including surprisingly low compression sets. Very soft viscoelastic foams and microcellular elastomers can be conveniently prepared from the reaction system without the necessity of using plasticizers. The reaction system can be processed into useful polymeric articles using a wide range of conventional polyurethane processing methods.
Abstract: A printing paste containing: a) 5 to 30% by weight of a polyurethane, b) 1 to 20% by weight of an organic fixing agent, c) 0 to 50% by weight of one or more further ingredient(s) and d) water as the remainder, the sum of the amounts of components (a)+(b)+(c)+(d) being 100%, is suitable for printing textile materials.
Abstract: The present invention provides a composition of matter having the structure: where Q is a multi-valent organic moiety containing isocyanurate functionality; X is H, —CH2OH, or —CH2OR?; R? is an alkyl or aryl group having from 1 to 12 carbon atoms; and y is at least 2. Also provided is a curable composition containing the composition of matter.
Type:
Grant
Filed:
February 5, 2004
Date of Patent:
April 4, 2006
Assignee:
PPG Industries Ohio, Inc.
Inventors:
Michael A. Mayo, Steven V. Barancyk, Jane N. Valenta, Sherry M. Gaggini, William A. Humphrey
Abstract: The invention relates to a moisture-crosslinkable hot-melt adhesive which is composed of a polyurethane prepolymer obtained by polyaddition of at least one polyol to at least one isocyanate chosen from the group of diisocyanates trimerized as isocyanurates and reaction products of diisocyanates with water, the prepolymer having a content of free NCO group of between 1 and 25% by weight. The adhesive according to the invention may be used for the adhesive bonding of fixing components of the Velcro® type to articles intended for hygiene.
Type:
Grant
Filed:
June 4, 2003
Date of Patent:
April 4, 2006
Assignee:
Bostik SA
Inventors:
Michel Miskovic, François Bauduin, Patrick Bouttefort, Jean-François Chartrel
Abstract: A novel thixotropic agent comprising urea crystals which comprises at least one compound containing at least one functional group having at least one bond which can be activated with actinic radiation; a novel process for preparing a thixotropic agent comprising urea crystals by reacting at least one primary and/or secondary amine and/or water with at least one polyisocyanate in a liquid organic medium consisting of or comprising at least one compound containing at least one functional group having at least one bond which can be activated with actinic radiation; and the use of the thixotropic agents to prepare coating materials, adhesives and sealing compounds curable thermally and with actinic radiation.
Type:
Grant
Filed:
August 22, 2001
Date of Patent:
March 28, 2006
Assignee:
BASF Coatings AG
Inventors:
Ulrike Röckrath, Uwe Conring, Hurbert Baumgart, Ingrid Heid