Abstract: Single crystals of a new noncentrosymmetric polar oxysulfide SrZn2S2O (s.g. Pmn21) grown in a eutectic KF-KCl flux with unusual wurtzite-like slabs consisting of close-packed corrugated double layers of ZnS3O tetrahedra vertically separated from each other by Sr atoms and methods of making same.
Type:
Grant
Filed:
July 1, 2020
Date of Patent:
July 12, 2022
Assignee:
University of South Carolina
Inventors:
Hans-Conrad Zur Loye, Yoshihiro Tsujimoto
Abstract: There is provided a nitride crystal substrate constituted by group-III nitride crystal, containing n-type impurities, with an absorption coefficient ? being approximately expressed by equation (1) by a least squares method in a wavelength range of at least 1 ?m or more and 3.3 ?m or less. ?=NeK?a??(1) (where 1.5×10?19?K?6.0×10?19, a=3), here, a wavelength is ? (?m), an absorption coefficient of the nitride crystal substrate at 27° C. is ? (cm?1), a carrier concentration in the nitride crystal substrate is Ne (cm?3), and K and a are constants, wherein an error of an actually measured absorption coefficient with respect to the absorption coefficient ? obtained from equation (1) at a wavelength of 2 ?m is within ±0.1?, and in a reflection spectrum measured by irradiating the nitride crystal substrate with infrared light, there is no peak with a peak top within a wavenumber range of 1,200 cm?1 or more and 1,500 cm?1 or less.
Type:
Grant
Filed:
June 10, 2019
Date of Patent:
July 5, 2022
Assignees:
SCIOCS COMPANY LIMITED, SUMITOMO CHEMICAL COMPANY, LIMITED
Abstract: A chalcogen-containing compound of the following Chemical Formula 1 which exhibits excellent phase stability at a low temperature, particularly at a temperature corresponding to the driving temperature of a thermoelectric element, and also exhibits an excellent thermoelectric performance index through an increase in a power factor and a decrease in thermal conductivity, a method for preparing the same, and a thermoelectric element including the same: V1-xMxSn4Bi2Se7-yTey??[Chemical Formula 1] In the above Formula 1, V is a vacancy, M is an alkali metal, x is greater than 0 and less than 1, and y is greater than 0 and less than or equal to 1.
Type:
Grant
Filed:
May 30, 2018
Date of Patent:
June 14, 2022
Assignee:
LG CHEM, LTD.
Inventors:
Min Kyoung Kim, Yu Ho Min, Cheol Hee Park, Kyung Moon Ko, Chee Sung Park, Myung Jin Jung
Abstract: Embodiments of zeolite composite catalysts and methods of producing the zeolite composite catalysts are provided, where the methods comprise dissolving in an alkaline solution a catalyst precursor comprising at least one mesoporous zeolite while heating, stirring, or both to yield a dissolved zeolite solution, where the mesoporous zeolite has a molar ratio of SiO2/Al2O3 of at least 30, where the mesoporous zeolite comprises zeolite beta, adjusting the pH of the dissolved zeolite solution, aging the pH adjusted dissolved zeolite solution to yield solid zeolite composite from the dissolved zeolite solution, and calcining the solid zeolite composite to produce the zeolite composite catalyst, where the zeolite composite catalyst has a mesostructure comprising at least one disordered mesophase and at least one ordered mesophase, and where the zeolite composite catalyst has a surface area defined by the Brunauer-Emmett-Teller (BET) analysis of at least 600 m2/g.
Type:
Grant
Filed:
April 15, 2020
Date of Patent:
June 7, 2022
Assignees:
King Fahd University of Petroleum and Minerals, Saudi Arabian Oil Company
Inventors:
Balasamy Rabindran Jermy, Syed Ahmed Ali, Raed Hasan Abudawoud, Abdullah Mohammed Aitani, Sulaiman Saleh Al-Khattaf
Abstract: An object of the present invention is to improve quality of a nitride crystal, and also improve performance and manufacturing yield of a semiconductor device manufactured using the crystal. Provided is a nitride crystal in which a composition formula is represented by InxAlyGa1-x-yN (satisfying 0?x?1, 0?y?1, 0?x+y?1), and the concentration of B in the crystal is less than 1×1015 at/cm3, and each of the concentrations of O and C in the crystal is less than 1×1015 at/cm3 in a region of 60% or more of a main surface.
Type:
Grant
Filed:
July 29, 2019
Date of Patent:
May 24, 2022
Assignees:
SCIOCS COMPANY LIMITED, SUMITOMO CHEMICAL COMPANY, LIMITED
Inventors:
Hajime Fujikura, Taichiro Konno, Takehiro Yoshida
Abstract: The invention concerns a process for preparing a copper-comprising SAPO material with AFX structure, comprising at least the steps of mixing, in an aqueous medium, at least one aluminum source, at least one silicon source, at least one copper source, at least one phosphorus source, a TETA complexing agent and a TMHD structuring agent, in order to obtain a gel, and hydrothermal treatment of said gel with a shear rate of less than 50 s?1 in order to obtain crystallization of said copper-comprising SAPO material with AFX structure.
Type:
Grant
Filed:
May 18, 2018
Date of Patent:
May 24, 2022
Assignee:
IFP Energies Nouvelles
Inventors:
David Berthout, Bogdan Harbuzaru, Eric Llido
Abstract: The present invention discloses a method of preparing a catalyst for low-temperature synergistic catalytic purification of NOx and HCN in a flue gas, and the use thereof. Citric acid is dissolved in ethanol to obtain a citric acid/ethanol solution; tetrabutyl titanate is added, mixed uniformly to obtain a tetrabutyl titanate-citric acid/ethanol solution; glacial acetic acid is added dropwise to react for 30-40 min to obtain a solution A; the metal salt solution was added dropwise into the solution A, mixed uniformly and added with nitric acid, ammonium hydroxide is added dropwise to adjust the pH value, and the temperature is raised at a constant speed to obtain a gel B; dried and then then baked at a temperature of 300-500° C. for 3-4 h, cooled in the furnace, pulverized, tableted and sieved to obtain the catalyst for the low-temperature synergistic catalytic purification of NOx and HCN in the flue gas.
Type:
Grant
Filed:
December 20, 2019
Date of Patent:
May 17, 2022
Assignee:
Kunming University of Science and Technology
Abstract: An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.
Abstract: Method for reducing the content of nitrogen oxides NOx and nitrous oxide N2O in an input gas, comprising the steps of: treating said gas with a first amount of a NOx reducing agent in a first de-NOx catalytic bed; treating the effluent of said first de-NOx catalytic bed in at least one de-N2O catalytic bed for removal of N2O; treating the effluent of said at least one de-N2O catalytic bed with a second amount of a NOx reducing agent in a second de-NOx catalytic bed.
Abstract: This invention relates generally to a process to perform controlled alkaline and acid treatments on inorganic porous solids, yielding superior physico-chemical and catalytic properties, whereas the particle and crystal size is not negatively influenced. Accordingly, the solids obtained in this fashion can be easily recovered from the alkaline solution. The latter being problematic in the state of the art.
Type:
Grant
Filed:
July 31, 2018
Date of Patent:
May 10, 2022
Assignee:
Katholieke Universiteit Leuven
Inventors:
Danny Verboekend, Bert F. Sels, Martin A. D'Halluin
Abstract: The present invention concerns a process for the preparation of flocculated filler particles, wherein at least two aqueous suspensions of at least one filler material and at least one flocculating additive are combined.
Type:
Grant
Filed:
November 3, 2015
Date of Patent:
May 10, 2022
Assignee:
OMYA INTERNATIONAL AG
Inventors:
Michel Schenker, Matthias Buri, Lars Andersson, Daniel Gantenbein, Patrick A. C. Gane
Abstract: The present disclosure generally provides catalysts, catalytic articles and catalyst systems including such catalytic articles. In particular, the catalyst composition includes a zeolite having a chabazite (CHA) crystal structure ion-exchanged with iron and copper. Methods of making and using the catalyst composition are also provided, as well as emission treatment systems containing a catalyst article coated with the catalyst composition. The catalyst article present in such emission treatment systems is useful to catalyze the reduction of nitrogen oxides in gas exhaust in the presence of a reductant.
Abstract: The exhaust gas purification catalyst disclosed here is an exhaust gas purification catalyst disposed in the exhaust pipe of an internal combustion engine to purify nitrogen oxides contained in exhaust gas discharged from the internal combustion engine, provided with a silver alumina catalyst comprising at least alumina as a catalyst and silver supported on this alumina, wherein, in the silver alumina catalyst, the ratio of the peak intensity at a wave number of 1595 cm?1 to the peak intensity at a wave number of 1613 cm?1 by the pyridine IR method is at least 0.3, and the carried amount of the silver is 1.0 wt % to 6.0 wt % given 100 wt % as the total amount of the silver alumina catalyst.
Type:
Grant
Filed:
September 11, 2017
Date of Patent:
April 26, 2022
Assignee:
Cataler Corporation
Inventors:
Keigo Hori, Norihiko Aono, Daisuke Oki, Yuya Kawano
Abstract: Systems and methods for the use of highly reactive hydrated lime (HRH) in high temperature flue gas streams, namely those at greater than 400° F., such as are present before an air preheater (APH) to remove sulfur trioxide (SO3) from the flue gas.
Type:
Grant
Filed:
September 4, 2015
Date of Patent:
April 26, 2022
Assignee:
Mississippi Lime Company
Inventors:
Curt Biehn, Randy Griffard, Mark DeGenova, Eric Van Rens, Pat Mongoven
Abstract: A chalcogen-containing compound of the following Chemical Formula 1 which exhibits excellent phase stability at a temperature corresponding to the driving temperature of a thermoelectric element, and also exhibits an excellent thermoelectric performance index (ZT) through an increase in a power factor and a decrease in thermal conductivity, a method for preparing the same, and a thermoelectric element including the same: V1-xMxSn4-yPbyBi2Se7-zTez??[Chemical Formula 1] In the above Formula 1, V is a vacancy, M is an alkali metal, x is greater than 0 and less than 1, y is greater than 0 and less than 4, and z is greater than 0 and less than or equal to 1.
Type:
Grant
Filed:
May 11, 2018
Date of Patent:
April 19, 2022
Assignee:
LG CHEM, LTD.
Inventors:
Min Kyoung Kim, Yu Ho Min, Cheol Hee Park, Kyung Moon Ko, Chee Sung Park, Jae Hyun Kim, Myung Jin Jung
Abstract: The present invention provides a polycrystalline silicon rod whose rod surface portion has a phosphorus concentration of 0.015 ppba or less, in which the ratio (P2/P1) of the phosphorus concentration (P2) of the rod center portion to the phosphorus concentration (P1) of the rod surface portion is within the range of 2 or lower. The present invention also provides a method for producing a polycrystalline silicon rod by the Siemens method that assembles a polycrystalline silicon seed rod in a reactor, then heats the seed rod up to a temperature of 1000° C. or more and less than the melting point of silicon by energization heating, and supplies a raw material gas including trichlorosilane gas and hydrogen gas as the main components to the reactor at the heating temperature to deposit and grow silicon on the seed rod surface.
Abstract: An object of the present disclosure is to provide an NOx storage material having sufficient NOx storage capacity even in a low temperature region and a production method thereof. An NOx storage material including a composite oxide of silver and gallium. The composite oxide of silver and gallium is preferably a delafossite-type composite oxide. The composite oxide is produced by dissolving a silver salt and a gallium salt in a solvent and baking the solution, wherein the molar ratio of silver:gallium is preferably from 2:8 to 7:3.
Abstract: The invention relates to a catalyst device for purifying exhaust gases containing nitrogen oxide by using selective catalytic reduction (SCR), the catalyst device comprising at least two catalytic layers, the first layer containing vanadium oxide and a mixed oxide comprising titanium oxide and silicon oxide and the second layer containing a molecular sieve containing iron, wherein the first layer is applied onto the second layer. The invention also relates to uses of the catalyst device and a method for purifying exhaust gases.
Abstract: A combined remediation method of petroleum-contaminated soil includes: impurity removal pretreatment, photocatalytic pre-oxidation, stepwise thermal desorption of petroleum from soil, and high-temperature oxidation; with iron-titanium composite metal oxide (ITCMO) as a catalyst, conducting oxidation pretreatment under light conditions so that some cross-linked structures in macromolecular petroleum contaminants are broken and degraded; and conducting stepwise pyrolysis to achieve a removal rate of more than 98.00%. The new method adopts a combined remediation technology of photocatalytic pre-oxidation-stepwise pyrolysis, which realizes a relatively-high removal rate of petroleum hydrocarbons and the efficient and harmless remediation of high-concentration petroleum-contaminated soil, and remedied soil can be reused.
Type:
Grant
Filed:
October 19, 2020
Date of Patent:
April 5, 2022
Assignee:
CHINA UNIVERSITY OF PETROLEUM
Inventors:
Dong Liu, Shuhai Guo, Wei Zhu, Fushan Wen, Nan Shi, Yu Qiu, Xiaoning Feng, Bo Wu, Gang Li, Changlong Yin, Xiujie Yang, Dehui Kong, Hongbo Dai, Mengfei Li, Sa Wang
Abstract: A method for the reduction and prevention of mercury emissions into the environment from combusted fossil fuels or other off-gases with the use of peracetic acid is disclosed. The peracetic acid is used for the capture of mercury from the resulting flue gases using a flue gas desulfurization system or scrubber. The method uses peracetic acid in conjunction with a scrubber to capture mercury and lower its emission and/or re-emission with stack gases. The method allows the use of coal as a cleaner and environmentally friendlier fuel source as well as capturing mercury from other processing systems.
Type:
Grant
Filed:
October 10, 2018
Date of Patent:
March 29, 2022
Assignee:
ECOLAB USA INC.
Inventors:
Nicholas R. Denny, Bruce A. Keiser, David M. Dotzauer, Wayne M. Carlson