Abstract: A composite of metal and an organic film having a high adhesiveness without deterioration of film quality is provided by exposing the surface of organic film to at least one of chemically reactive gas phase molecules and gas phase ions thereby forming functional groups on the surface of organic film, and forming a metallic film thereon through the functional groups.
Type:
Grant
Filed:
March 19, 1990
Date of Patent:
January 12, 1993
Assignees:
Hitachi, Ltd., Hitachi Chemical Company Ltd.
Abstract: A composite article is prepared as a polymeric support having a coating of noble metal deposited on at least one surface thereof, the coating exhibiting suitable peel force for high performance applications such as the preparation of an electrode, such as a biocompatible, flexible, thin-film microelectrode where in the composite article can be prepared by pretreating at least one surface of the support by sputter etching, followed by sputter-depositing a noble metal on the pretreated surface in order to form the coating of noble metal.
Type:
Grant
Filed:
July 2, 1991
Date of Patent:
January 12, 1993
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: An undercoat composition for a powder coating of a heat-resistant resin on a metal substrate at a high coating temperature wherein the composition includes a specific imide prepolymer.
Type:
Grant
Filed:
October 11, 1990
Date of Patent:
January 12, 1993
Assignee:
Sekisui Kagaku Kogyo Kabushiki Kaisha
Inventors:
Toshimi Inai, Naofumi Imahigashi, Koichi Karukaya, Koji Motoi
Abstract: A metallized film combination of an oriented polymeric substrate layer having on at least one surface thereof a coating of a blend of (a) a vinyl alcohol homopolymer or copolymer and (b) an ionic copolymer of ethylene and an ethylenically unsaturated monocarboxylic acid wherein at least 10% of the carboxylic acid groups are neutralized with an alkali metal ion; and the surface of said layer blend having a metal layer thereon and the method of coating the blend of (a) and (b) on the substrate after it is machine direction oriented, followed by transverse direction orientation and depositing a metal layer on the coating surface.
Abstract: The present invention discloses a surface treated material of excellent adhesion for painting layer, corrosion resistance after painting and press formability, containing, in a Zn or Fe series plating layer, a (meth)acrylic polymer having repeating units of a (meth)acrylic acid derivative in which a compound having an epoxy group is added to a chemical formula represented by: ##STR1## where X represents --NH-- or --O--, A represents C.sub.n H.sub.2n, n is 0 or a positive integer, R represents --H or --CH.sub.3, and R.sub.1, R.sub.2 which may be identical or different with each other represents H or alkyl group.
Type:
Grant
Filed:
August 21, 1991
Date of Patent:
December 8, 1992
Assignee:
Kabushiki Kaisha Kobe Seiko Sho
Inventors:
Hiroshi Sato, Kouki Ikeda, Jun Hisamoto, Nagisa Takee
Abstract: An anti-copying composite film comprising a substratum of paper or synthetic resin film, a metallic foil formed on the surface of said substratum and a colored transparent synthetic resin coating layer applied to the surface of said metallic foil, said anti-copying composite film being characterized in that the color of the coating layer is selected in Munsell color system so that the value may be 9 or less than 9 regardless of the hue, while the chroma is selected so that an index calculated in a formula on the base of the difference of the value and the difference of chroma with respect to those of black may be 20 or more than 20.
Abstract: A dry film lubricant is selectively applied to the plated, anodized, or conversion coated aluminum base material of an electrical connector part so as to maximize the corrosion protection on exposed surfaces while maintaining electrical conductivity on mating surfaces.
Abstract: Electro-deposition-coated steel is top coated with a flexible coating formed of a polyester having -OH functionality, a polyacrylate having -OH functionality and melamine-formaldehyde resin to provide substantially a stoichiometric amount of reactive sites relative to the total amount of -OH functionality of the polyester and the polyacrylate. The flexible coatings exhibit superior chip and scratch resistance relative to rigid coatings of the type conventionally used in the automotive industry.
Type:
Grant
Filed:
August 29, 1991
Date of Patent:
December 8, 1992
Assignee:
Morton International, Inc.
Inventors:
William A. Rasmussen, Michael L. Jackson
Abstract: Improved non-stick coating systems can be applied to untreated smooth substrate with a primer of a first polytetrafluoroethylene having a melt viscosity over 10.sup.10 poises plus a second polytetrafluoroethylene having a melt viscosity in the range of 10.sup.3 to 10.sup.8 poises to give a concentration gradient.
Abstract: A plated article comprising a molded article having a metal coating deposited thereon, the molded article being formed of a resin composition consisting essentially of 10 to 90% by weight of a polybutylene terephthalate resin and 90 to 10% by weight of an ABS resin containing 5 to 70% by weight of a rubber component composed mainly of polybutadiene, which plated article has excellent thermal resistance, mechanical strength and solvent resistance.
Abstract: Sheet materials and packages capable of holding hard-to-hold products such as methyl salicylate. The preferred embodiments include a foil layer 12 and a layer 14 of EVOH between foil layer 12 and the enclosed product. An anhydride modified adhesive layer 18 is disposed between the EVOH layer 14 and the product 52. Additional layers are used in the sheet material for purposes of adhesion, appearance, protection, body, and the like. One embodiment of the invention is a coextruded film comprising the EVOH layer 514, a surface layer 516 of LLDPE, an intervening adhesive layer 518, and a fourth covering layer 519 for covering and protecting the EVOH layer 514, especially from physical abuse. The sheet materials of the invention may be made into packages by means of fin seals 54 or lap seals 50.
Abstract: A metallized multilayer film comprising a first substrate layer, a second substrate layer, and a layer of metal. The first substrate layer comprises from 0 to about 40 parts by weight poly(vinylidine fluoride) and, correspondingly, from 100 to about 60 parts by weight poly(methyl methacrylate). The second substrate layer comprises from about 70 to 100 parts by weight poly(vinylidine fluoride) and, correspondingly, from about 30 to 0 parts by weight poly(methyl methacrylate).
Type:
Grant
Filed:
May 15, 1991
Date of Patent:
November 17, 1992
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: Laminated composite consisting of a substrate sheet coated with a film (A) comprising at least one layer based on a polyamide resulting from the polycondensation of an aliphatic .alpha., .omega.-dicarboxylic acid with xylylenediamines.
Type:
Grant
Filed:
May 22, 1990
Date of Patent:
November 17, 1992
Assignee:
Solvay & Cie (Societe Anonyme)
Inventors:
Jacques D'Heur, Claude Michel, Roland Grobelny
Abstract: An abrasive element comprising a substrate having on a surface thereof particles of an abrasive material secured by an organic binding medium wherein at least the surface of the element between the particles of abrasive material contains a fluorochemical selected from the group consisting of compounds comprising a fluorinated aliphatic group attached to a polar group or moiety and compounds having a molecular weight of at least 750 and comprising a non-fluorinated polymeric backbone having a plurality of pendant fluorinated aliphatic groups, said aliphatic groups comprising the higher of(a) a minimum of three C--F bonds, or(b) in which 25% of the C--H bonds have been replaced by C--F bonds such that the compound comprises at least 15% by weight of fluorine.The compound may be applied as a layer coated over the existing layers of an abrasive element or it may be incorporated into at least the coating formulation which will form the outermost layer of the binding medium.
Type:
Grant
Filed:
November 19, 1990
Date of Patent:
November 17, 1992
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: The wear resistance of hardface coatings formed on a metal substrate using cloth-like flexible preforms, by substituting two or more thinner preforms for the single layer preform heretofore employed.
Abstract: Improved non-stick coating systems can be applied on a primer with a topcoat containing two types of perfluorocarbon resin, one with a melt viscosity above about 10.sup.10 poises, the other with a melt viscosity in the range of 10.sup.3 to 10.sup.8 poises.
Abstract: A resin material for inserting a lead frame comprises:(A) 100 parts by weight of a polyarylene sulfide resin,(B) 0.1 to 30 parts by weight of an .alpha.-olefin copolymer graft-copolymerized with an unsaturated carboxylic acid or its anhydride, and(C) 10 to 300 parts by weight of a fibrous filler, a nonfibrous inorganic filler or a mixture thereof.The grafted unsaturated carboxylic acid such as maleic anhydride is essential, in comparison with olefin copolymers, preferably in an amount of 1 to 5 percent. The olefin copolymer includes that of ethylene and ethyl acrylate. The addition of (B) effectively works to improve adhesion between the lead frame and the polyarylene sulfide composition, because it does not decompose and give a gas during molding. Heat resistance and the molding performance does not change. An example comprises PPS, a copolymer of ethylene and ethyl acrylate, grafted with 3.0% of maleic anhydride, glass fiber and glass beads.
Abstract: A plurality of corona-treated polymeric films, and metal foils or sheets, are alternately arranged and laminated together to form a laminate suitable for e.g. insulating panels. Construction of this absolute or near-absolute barrier can be simultaneous or sequential. The metal foils may be of the same type, or may differ. Aluminum and steel are preferred metal foils. At sufficient thicknesses, the sheet can be stamped or shaped. Both outermost surfaces of the laminate can comprise polymeric film, or both surfaces can comprise metal foils. Alternatively, one outer surface can be a polymeric film and the other outer surface can be a metal foil.
Abstract: A composition capable of being applied as a film and hardening to form a protective layer on the back of a mirror comprises a fluid organic resin and a corrosion inhibitor selected from the group consisting of dicyandiamide and metal or acid salt thereof. The organic resin may be any thermoplastic or thermosetting resin suitable for coating the reflective and other metallic layers of the mirror. Exemplary resins include alkyd resins, acrylic resins, modified alkyd resins, polyesters, urethane oils, vinyl halide polymers or copolymers, oleoresinous varnishes, nitrocellulose compositions, phenol-formaldehyde resin varnishes, and epoxy resins. Preferably, the resin is an alkyd or modified alkyd resin. The dicyandiamide or metal or acid salt or dicyandiamide may be present in an amount from about 0.1 to 20 weight percent, preferably 0.5 to 10 weight percent, of the organic resin coating system. The resin system should be essentially free of lead and lead salts.
Abstract: An article consisting of a base and one or more attachments thereto. The base is made of one thermoplastic polymer and the attachment is made of a second thermoplastic polymer which is at least partially incompatible with the first polymer. Either the first or second polymer contains 5 to 75% by weight of a third polymer which is an olefinic polymer having functional groups thereon. Either of the first two polymers may contain up to 90% of the usual additives. This enables the production of such articles with high interface strength.