Patents Examined by Thomas R. Neville
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Patent number: 5476747Abstract: A silver halide photographic light-sensitive material comprises a support and provided thereon, a photographic component layer comprising a silver halide emulsion layer and a hydrophilic colloid layer other than the emulsion layer, wherein the photographic component layer contains a hydrazine derivative, a nucleation accelerating agent and polymer latex containing as a protective colloid a hydrophilic polymer having an average number molecular weight of 1,000 to 1,000,000 and having a solubility of not less than 0.1 g in 100 g of water at 20.degree. C., provided that the hydrophilic polymer is not gelatin.Type: GrantFiled: December 29, 1994Date of Patent: December 19, 1995Assignee: Konica CorporationInventors: Kazuhiro Yoshida, Takeshi Sampei, Toshiyuki Takabayashi
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Patent number: 5476759Abstract: A silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer is disclosed, wherein said light-sensitive material contains a DIR coupler represented by formula (I): ##STR1## wherein A represents a coupler residue; R represents an alkyl group having from 1 to 4 carbon atoms or a pyridyl group; and n represents 1 when A represents a phenol type or naphthol type coupler residue, or n represents 0 when A represents other coupler residues, and said emulsion layer contains chemically sensitized silver halide grains which individually have a distinct layer comprising silver iodobromide containing from 7 to 45 mol % of silver iodide and which individually have an overall silver iodide content of more than 4 mol %.Type: GrantFiled: July 28, 1993Date of Patent: December 19, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiji Mihayashi, Seiji Ichijima, Toshio Kawagishi, Naoki Saito, Masuji Motoki
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Patent number: 5474885Abstract: A modified gelatin is disclosed wherein part of the free carboxyl groups is replaced by modifiers having more acid end-standing groups chosen from --SO.sub.3 M, --OSO.sub.3 M, --SSO.sub.3 M, --OPO(OH).sub.2, --OPO(OH)(OR.sup.2), --PO(OH).sub.2, --PO(OH)(OR.sup.2).In a preferred embodiment such a modified gelatin is incorporated in a DTR photographic material which after processing can serve as a lithographic printing plate. Thanks to the more hydrophilic character of the modified gelatin the differentiation between printing and non-printing areas is improved and toning at printing start-up is reduced.Type: GrantFiled: May 26, 1994Date of Patent: December 12, 1995Assignee: Agfa-Gevaert, N.V.Inventors: Eddy Michiels, Piet Kok, Johan Loccufier, Frank Michiels, Ludo Van Rompuy
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Patent number: 5472834Abstract: To eliminate the "pi-line" artefact after processing a silver halide industrial photographic X-ray material is disclosed comprising on at least one side of a support, at least one gelatino silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating, wherein said photographic material comprises at least one vinyl sulphone compound as a hardening agent and at least one polyoxyalkylene compound as a surfactant in at least one of its hydrophilic layers.Type: GrantFiled: April 5, 1994Date of Patent: December 5, 1995Assignee: Agfa-Gevaert, N.V.Inventors: Raymond Florens, Pieter Perdieus, Andre Roefs
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Patent number: 5472835Abstract: The present invention is a process for continuous preparation of solutions of water-immiscible or water-insoluble organic compounds in substantially non-aqueous organic solvents. Particularly, a process for the continuous preparation of colour forming coupler solutions for use in the photographic industry is described. The process uses a twin screw extruder wherein the compound to be dissolved is introduced into a first section of the extruder. The compound passes along the extruder interior to a section where organic solvent is introduced to form the required solution.Type: GrantFiled: June 21, 1994Date of Patent: December 5, 1995Assignee: Eastman Kodak CompanyInventors: David R. Bendle, David G. N. English, Jeremy S. Foster
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Patent number: 5472838Abstract: Silver halide emulsions with tabular grains showing increased aspect ratio are produced by adding to the precipitiation vessel a compound of the formula I: ##STR1## in which R.sub.1 means H or optionally substituted alkyl, aralkyl or cycloalkylR.sub.2 means H or optionally substituted alkyl, aryl or aralkyl or a polymer chainR.sub.3 means H, OH, alkyl, aryl, aralkyl, halogen, NHR.sub.4, O--CO--R.sub.4, O--CO--NHR.sub.4 or an optionally substituted oxazoline ringR.sub.4 means optionally substituted or alkyl, aralkyl or arylm means 2 or 3,n means 2 to 10,000,or a compound of the formula II ##STR2## in which R.sub.1, R.sub.3, n and m have the meaning stated above and may be identical or different andR.sub.5 means optionally substituted alkene, arylene, aralkene or a polyaddition, polycondensation or polymerisation chain.Type: GrantFiled: July 11, 1994Date of Patent: December 5, 1995Assignee: Agfa-Gevaert AGInventors: Gunter Helling, Klaus Wagner
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Patent number: 5468598Abstract: A process for preparing a stable, solid particle dispersion of a substantially water-insoluble compound useful in imaging, comprises the steps of:(a) forming a coarse aqueous slurry of solid particles of said compound and a hydrophobic, water-soluble or water-dispersible polymer in an amount of 0.1 to 100% by weight based on the weight of said compound; and(b) milling said slurry for time sufficient to provide particles of the desired average particle size;wherein the polymer is an uncharged or weakly anionically charged water-soluble or water-dispersible homopolymer or copolymer in which at least 10 mole % of the repeat units contain an uncharged pendant group that terminates in (a) a CH.sub.3 unit, (b) a ring containing at least two contiguous CH.sub.2 units, or (c) an aromatic group.The resulting dispersion has dispersed solid particles of said compound having the desired small particle size and is stable toward particle agglomeration, particle growth and needle growth.Type: GrantFiled: April 18, 1994Date of Patent: November 21, 1995Assignee: Eastman Kodak CompanyInventors: David D. Miller, Mary C. Brick, Mridula Nair
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Patent number: 5468592Abstract: An ultra-hard silver halide photographic material having high processing stability, which contains a hydrazine derivative represented by the following general formula (1) or (2): ##STR1## wherein X.sup.1 and X.sup.2 are each a group containing 1 to 6 carbon atoms, Y.sup.1 is a hydrogen atom or a group, R.sup.1 is a group, Y.sup.1 and R.sup.1 jointly provide 4 to 30 carbon atoms, Y.sup.2 is an electron withdrawing group, R.sup.2 is a hydrogen atom or a monovalent group, and n is an integer of from 1 to 5.Type: GrantFiled: March 31, 1994Date of Patent: November 21, 1995Assignee: Fuji Photo Film Co. Ltd.Inventors: Kazumi Nii, Takashi Hoshimiya, Kazunobu Katoh, Toshihide Ezoe
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Patent number: 5466567Abstract: Imaging elements, such as photographic, electrostatographic and thermal imaging elements, are comprised of a support, an image-forming layer and an electrically-conductive layer comprising a film-forming hydrophilic colloid having dispersed therein both electrically-conductive fine particles and pre-crosslinked gelatin particles. The combination of hydrophilic colloid, electrically-conductive fine particles and pre-crosslinked gelatin particles provides a controlled degree of electrical conductivity and beneficial chemical, physical and optical properties which adapt the electrically-conductive layer for such purposes as providing protection against static or serving as an electrode which takes part in an image-forming process.Type: GrantFiled: October 28, 1994Date of Patent: November 14, 1995Assignee: Eastman Kodak CompanyInventors: Charles C. Anderson, Yongcai Wang, James L. Bello, Ibrahim M. Shalhoub, Douglas D. Corbin
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Patent number: 5462841Abstract: A method for producing a reproduction in reduced or enlarged size of a halftone original with improved tone rendition by the use of a continuous tone correction mask in conjunction with the halftone original applied in projection exposure.It is a particular characteristic of the present invention that said improved tone rendition is obtained by using in said projection exposure a mask image, the maximum density (i.e. density at 3% dot value areas of the halftone original used in the projection exposure) is linearly directly proportional to the screen ruling of the halftone original used in the projection exposure (see FIG. 2 and 3).Type: GrantFiled: April 15, 1994Date of Patent: October 31, 1995Assignee: AGFA-Gevaert N.V.Inventor: Lode Carleer
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Patent number: 5462846Abstract: Disclosed is a silver halide color photographic material having at least one non-coloring layer. The layer contains (i) at least one water-insoluble polymer having a number average molecular weight of less than 2000, which is obtained obtained by polymerizing at least one monomer having an aromatic group, and optionally contains (ii) at least one UV absorbent selected from 2-(2'-hydroxyphenyl)benzotriazoles, benzophenones and triazines and (iii) at least one high boiling point organic solvent having a refractive index of 1.50 or less. The photographic material has high light fastness.Type: GrantFiled: November 22, 1994Date of Patent: October 31, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Yoneyama
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Patent number: 5462832Abstract: A novel method of forming radiation images, especially X-ray images of bones and gastric areas for medical examination, is disclosed.Type: GrantFiled: July 12, 1994Date of Patent: October 31, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Nobuyuki Iwasaki
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Patent number: 5462831Abstract: To eliminate the "pi-line" artifact after processing a method of image formation is disclosed in a silver halide industrial X-ray photographic material, comprising on at least one side of a support, at least one gelatin silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating, wherein said material further comprises a hardening agent different from a vinyl sulphone compound, preferably formaldehyde, and at least one polyoxyalkylene compound as a surfactant in at least one of its hydrophilic layers, and wherein after exposure to direct X-rays said material is subjected in an automatic processing machine to the steps of developing in a developer comprising at least one anionic alkylphenoxy polyalkyleneoxy phosphate ester surfactant, fixing in a fixer which may comprise at least one alpha-ketocarboxylic acid, rinsing and drying.Type: GrantFiled: April 5, 1994Date of Patent: October 31, 1995Assignee: Agfa-Gevaert, N.V.Inventors: Benedictus Jansen, Andre Roefs, Francis Sels, Pieter Perdieus, Raymond Florens
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Patent number: 5460931Abstract: A light-sensitive silver halide photographic material is disclosed, comprising a reflective support comprising a resin layer-coated base paper and having thereon a silver halide emulsion layer , wherein a hydrophilic colloid layer containing a white pigment is provided between the resin layer and the silver halide emulsion layer; the resin layer having an uneven surface; and a Wiener spectrum of the silver halide photographic material satisfying the following relation,1.1<(WS2) / (WS1)<2.0wherein WS1 and WS2 are average intensities of the spectrum within a spatial frequency range of 2 to 3 mm.sup.-1 and 10 to 20 mm.sup.-1, respectively.Type: GrantFiled: November 14, 1994Date of Patent: October 24, 1995Assignee: Konica CorporationInventors: Shigeo Tanaka, Tsuyoshi Ikeda
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Patent number: 5460919Abstract: A process of forming a super high-contrast negative image is disclosed, which comprises the steps of imagewise exposing a negative-working silver halide photographic material comprising a support having thereon one or more hydrophilic colloidal layers, at least one of the one or more hydrophilic colloidal layers being a negative-working silver halide emulsion layer, and then developing the photographic material with a developer containing an aminophenol derivative developing agent and a reductone compound in the existence of an organic compound having a negative reduction potential. A negative-working silver halide photographic material and a photographic developer being used for the image-forming process are also disclosed.Type: GrantFiled: July 22, 1994Date of Patent: October 24, 1995Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu, Jun Takeuchi, Kiyoshi Suematsu
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Patent number: 5460916Abstract: Disclosed is a silver halide photographic material for X-ray photography which has at least one light-sensitive silver halide emulsion layer on each side of a transparent support and constitutes a radiation image-forming system in combination with two radiation-intensifying screens respectively arranged on the front and the back sides of the photographic material. The photographic material is characterized by having a crossover rate of at most 15% with respect to the light emitted from said intensifying screens, and by producing an image having a characteristic curve such that when drawn using crossed coordinates equal to each other in unit length, with diffusion density as ordinate (Y-axis) and common logarithm of exposure amount as abscissa (X-axis), the characteristic curve provides a point gamma value ranging from 2.7 to 4.2 at every point within the optical density (diffusion density) range of 1.6 to 2.0 and a point gamma value of at least 0.Type: GrantFiled: May 24, 1994Date of Patent: October 24, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Nobuyuki Iwasaki
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Patent number: 5457014Abstract: Melt crystallization of a photographic composition containing dispersed particles of a filter dye and dispersed particles of oxidized developer scavenger, in particular a hydrazide or a disulfonamidophenol oxidized developer scavenger, is inhibited by dispersing the oxidized developer scavenger in the composition in the form of particles comprising the oxidized developer scavenger dispersed or dissolved in an organic solvent selected such that the following relationship is satisfied:6.65+10.0 A-1.53 B+0.11 B.sup.2 -0.99 AB.ltoreq.4.0wherein A is the weight ratio of organic solvent to oxidized developer scavenger; and B is the log P of the organic solvent.Type: GrantFiled: May 18, 1994Date of Patent: October 10, 1995Assignee: Eastman Kodak CompanyInventors: Paul L. Zengerle, Glenn M. Brown, John B. Rieger
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Patent number: 5457016Abstract: A photographic support material has a back coating comprising a blend of a polypropylene and low density polyethylene.Type: GrantFiled: August 30, 1993Date of Patent: October 10, 1995Assignee: Felix Schoeller Jr. Papierfabriken GmbH & Co. KGInventor: Ralf-Burkhard Dethlefs
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Patent number: 5457006Abstract: A photo-mask and a method of manufacturing a photo-mask, which includes the steps of applying a resist film onto a substrate of quartz, glass and the like, subjecting the resist film to light exposure and development to form a fine resist pattern, etching the mask substrate covered by the fine resist pattern, causing a non-light transmitting thin film of Cr, Ta, etc. to adhere thereon by vapor deposition, sputtering and the like, and removing the thin film on the resist pattern together with the resist film, thereby to form the photo-mask.Type: GrantFiled: March 29, 1991Date of Patent: October 10, 1995Assignee: Sharp Kabushiki KaishaInventors: Junji Hirokane, Hiroyuki Katayama, Akira Takahashi, Tetsuya Inui, Kenji Ohta, Junichi Washo, Tomoyuki Miyake, Kazuo Van, Michinobu Mieda
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Patent number: 5457018Abstract: A shaped article, in particular a support for image information layers prepared from a biaxially stretched film prepared from a polymer blend of 50 to 97 wt.% of a linear polyester and 3 to 50 wt.% of a polymer containing styrene, wherein the percentages relate to the sum of polyester and polymer containing styrene, is characterised by particularly-elevated covering power.Type: GrantFiled: November 14, 1994Date of Patent: October 10, 1995Assignee: Agfa Gevaert AGInventors: Klaus Sommer, Leo Morbitzer, Louis Bollens, Marc Stevens, Rudiger Plaetschke, Alfred Pischtschan