Patents Examined by W. R. H. Clark
  • Patent number: 5373054
    Abstract: A process for agglomerating a polymer powder which comprises mixing a polymer powder with an oxyalkylene group-containing polyvinyl alcohol resin in the presence of water and drying the resulting mixture. According to the process of the present invention, it is possible to easily prepare the polymer granules having little fine powder, a narrow particle size distribution and a large average particle size.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: December 13, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shinji Sanuki, Yoshinori Chosakon, Tsukasa Oishi
  • Patent number: 5359007
    Abstract: A method is disclosed for obtaining a thermoplastic rubber, from raw materials wich comprehend used rubber artifacts, like tires and other rubber products, devulcanized by means of physical, chemical, or physico-chemical process, transformed into an uniform and regular batch, wich is blended to a thermoplastic, thus obtaining a thermoplastic rubber for diversified industrial applications.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: October 25, 1994
    Assignee: Relastomer S/A
    Inventor: Luiz C. Oliveira Da Cunha Lima
  • Patent number: 5356995
    Abstract: The stabilised binder is a mixture of two copolymers and at least one curing agent. The one copolymer contains fluorine or silicon and a UV absorber in copolymerised form. The other copolymer is an acrylic resin. Suitable curing agents are melamine resins or polyisocyanates.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: October 18, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Andreas Valet, Roger Meuwly, Mario Slongo
  • Patent number: 5340877
    Abstract: It has been found that moldings produced from polyoxymethylene have reduced gloss if an acrylic (co)polymer is incorporated into the polyoxymethylene. The polyoxymethylene modified according to the invention gives moldings having a streak-free, uniformly matt surface which generally retain the physical properties and also the inherent color of the base material.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: August 23, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Oskar Schleith, Hans-Dieter Sabel
  • Patent number: 5334660
    Abstract: A vinyl chloride resin composition having an improved impact resistance with a good transparency that the vinyl chloride resin itself possesses originally; which comprises (A) a graft copolymer prepared by (i) adding a water-soluble electrolyte to a butadiene polymer (a) (ii) adding a monomer mixture (b) containing mainly an aromatic vinyl monomer to polymerize, (iii) adding a monomer mixture (c) containing mainly an alkyl methacrylate to polymerize and (iv), when desired, adding a monomer mixture (d) containing mainly an aromatic vinyl monomer.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: August 2, 1994
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Akira Takaki, Hiroto Mori, Toshihiko Hasegawa
  • Patent number: 5334657
    Abstract: A thermoformable chemical resistant polymer blend, useful in the preparation of refrigerator and freezer liners comprising:A) from 45 to 70 parts by weight impact modified monovinylidene aromatic polymer, comprising from 1 to 25 weight percent of a rubber and 75 to 99 weight percent of a monovinylidene aromatic polymer matrix having a molecular weight (Mw) from 50,000 to 400,000, said weight percents being based on the total weight of said impact modified, vinylaromatic polymer;B) from 15 to 40 parts by weight of an olefin polymer, selected from the group consisting of homopolymers of ethylene or propylene and copolymers of ethylene with one or more C.sub.4-8 .alpha.-olefins; andC) from 5 to 25 parts by weight of a compatibilizing polymer, adapted to increase interfacial adhesion between components A) and B), components A) and B) or components A), B) and C) existing in said blend as co-continuous phases, and the sum of A),B) and C) being 100 parts.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: August 2, 1994
    Assignee: The Dow Chemical Company
    Inventors: Steven B. Swartzmiller, Robert J. Donald, Jeffrey E. Bonekamp
  • Patent number: 5324779
    Abstract: Crosslinkable compositions with a polyethylene base are described which comprise a major proportion, for example 65 to 95% by weight, of at least one polymer selected from the polyethylenes grafted by a silane and ethylene-triethoxyvinylsilane copolymers; a minor proportion, for example, from 5 to 35% by weight, of at least one polymer selected from the hydrophilic polymers which are incompatible with ethylene polymers; as well as, added to the total weight of polymers (a) and (b), a small proportion, for example, from 1 to 10% by weight, of at least one polymer selected from the copolymers and the terpolymers with an ethylene base to react chemically with said incompatible hydrophilic polymer; and a catalytic proportion, for example of 0.001 to 0.3% by weight, of at least one hydrolytic catalyst. These crosslinkable compositions can be shaped by extrusion, extrusion blow-molding or injection molding and then crosslinked by heating in the presence of water.
    Type: Grant
    Filed: October 21, 1991
    Date of Patent: June 28, 1994
    Assignee: Institut Francais Du Petrole
    Inventors: Jacques Jarrin, Gaetan Serpe, Francois Dawans
  • Patent number: 5321077
    Abstract: A polymer polyol composition comprising a continuous phase, a disperse phase within the continuous phase, and a dispersant to enhance the stability of the polymer polyol is disclosed. The dispersant is a grafted polyol-polyacrylate dispersant comprised of a isocyanate vinyl monomer/ethylenically unsaturated monomer random copolymer and a polyoxyalkylene polyether, wherein the random copolymer and the polyoxyalkylene polyether are connected through at least one urethane graft site.Methods of preparing the polymer polyol composition and the grafted polyol-polyacrylate dispersant are provided. The polymer polyol compositions have low viscosities as well as high stability and may be prepared with high levels of dispersed vinyl polymer and high styrene:acrylonitrile ratios in the dispersed vinyl polymer. The polymer polyol compositions are useful for the preparation of polyurethanes, particularly polyurethane foams.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: June 14, 1994
    Assignee: Arco Chemical Technology, L.P.
    Inventors: John E. Hayes, Robert G. Gastinger
  • Patent number: 5319028
    Abstract: A polyvinyl chloride plastisol composition is provided, which contains as essential components (A) polyvinyl chloride resin particles prepared by microsuspension polymerization of vinyl chloride in the presence of a polymethyl methacrylate resin soluble in vinyl chloride and having polymethyl methacrylate resin localized on the surfaces of the resin particles, and (B) a plasticizer, and which has excellent thermal stability and stability with time of viscosity. The composition can be used advantageously as a material for use in processing procedures in which heat accumulates in plastisol being retained, for example, in slush processing, dip processing, etc. or for use in coating processing in which adhesiveness is required.
    Type: Grant
    Filed: December 13, 1991
    Date of Patent: June 7, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Eitaro Nakamura, Kazunori Ueki
  • Patent number: 5310828
    Abstract: Novel polymeric compositions are provided for polyamide fibers or fibers having terminal amino groups that impart stain resistance and are resistant to discoloration.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: May 10, 1994
    Assignee: Peach State Labs, Inc.
    Inventors: Michael S. Williams, Thomas H. Moss, III
  • Patent number: 5310788
    Abstract: An improved saponified ethylene-vinyl acetate copolymer composition comprising(A) 50 to 99.5 weight % of a saponified ethylene-vinyl acetate copolymer,(B) 0.4 to 50 weight % of an ethylene copolymer having a density of 0.90.about.0.94 g/cm.sup.3, and(C) a graft polymer obtainable by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide.
    Type: Grant
    Filed: April 29, 1992
    Date of Patent: May 10, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroshi Takida, Tomoyoshi Uemura
  • Patent number: 5298334
    Abstract: An improved saponified ethylene-vinyl acetate copolymer composition comprising(A) 50 to 99.5 weight % of a saponified ethylene-vinyl acetate copolymer,(B) 0.4 to 50 weight % of an ethylene copolymer having a density of 0.90.about.0.94 g/cm.sup.3, and(C) a graft polymer obtainable by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide.
    Type: Grant
    Filed: August 21, 1991
    Date of Patent: March 29, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroshi Takida, Tomoyoshi Uemura
  • Patent number: 5294672
    Abstract: The present invention relates to thermoplastic reinforced elastomeric blend compositions which exhibit improved tensile strengths, wherein the elastomeric blend compositions comprises a blend of a metal neutralized sulfonated polymer with about 1 to about 40 weight percent of a metal neutralized copolymer of ethylene and methacrylate.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: March 15, 1994
    Assignee: Exxon Research & Engineering Co.
    Inventor: Dennis G. Peiffer
  • Patent number: 5292814
    Abstract: The invention concerns a process for the preparation of monodispersed polymer beads, wherein in a first stage a seed polymer is prepared in an organic solvent and in the presence of an R--X compound, separated and in a second stage an emulsion polymerization is carried out in an aqueous medium in the presence of the seed polymer. The polymer beads obtained in this manner have diameters in the range of 0.5 to 50 .mu.m, and may be used in the immobilization of proteins and cells, as carriers of catalysts and in peptide synthesis and in chromatography.
    Type: Grant
    Filed: March 14, 1991
    Date of Patent: March 8, 1994
    Inventors: Ernst Bayer, Wolfgang Rapp
  • Patent number: 5292819
    Abstract: Radial block copolymers characterized by the formulas: (1) (pS-pI).sub.n X and (2) (pS-pI-pB).sub.n X where pS is polystyrene, pI is polyisoprene, pB is butadiene, X is a residue of a multifunctional coupling agent used in the production of the radial block copolymer, and n is a number greater than 2 representative of the number of branches appended to X; hot-melt adhesive compositions constituted of said radial block copolymers, and articles of manufacture produced therefrom. These copolymers possess blocks of high average molecular weight polystyrene (10,000 to 25,000) and an overall average molecular weight (90,000 to 380,000) such that when blended in requisite proportions with a compatible tackifier resin, preferably also a secondary tackifying resin or plasticizing oil, and stabilizer, superior hot-melt adhesive compositions can be formed.
    Type: Grant
    Filed: May 24, 1991
    Date of Patent: March 8, 1994
    Assignees: The Dow Chemical Company, Exxon Chemical Patents, Inc.
    Inventors: Charles F. Diehl, Gary R. Marchand, Michael O. Myers, Jean M. Tancrede
  • Patent number: 5292806
    Abstract: Blends of low styrene content polystyrene-polyisoprene-polystyrene block copolymer and high styrene content polystyrene-polyisoprene-polystyrene block copolymer can be used with tackifier resins, plasticizer oil and antioxidants to formulate pressure sensitive adhesives of improved cohesive strength vis-a-vis adhesives formed from the low styrene content polystyrene-polyisoprene-polystyrene block copolymer while maintaining good balance between tack, bonding characteristics and heat resistance.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: March 8, 1994
    Assignees: The Dow Chemical Company, Exxon Chemical Patents, Inc.
    Inventors: Charles F. Diehl, Jean M. Tancrede
  • Patent number: 5286575
    Abstract: The present invention is directed to a blend comprising about 5 to about 95 percent by weight of an ethylene vinyl alcohol copolymer and about 95 to about 5 percent by weight of an amorphous nylon polyamide copolymer having a glass transition temperature in the range of about 30 to 100.degree. C. The polyamide forms separate domains when blended with the ethylene vinyl alcohol copolymer. Such a structure has been found to surprisingly provide a composition capable of stretching at temperatures less than about 110.degree. C. without incurring problems known in the art.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: February 15, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Richard T.-H. Chou
  • Patent number: 5286808
    Abstract: Crosslinked elastomeric acetal polymers are made by the copolymerization of 1,3-dioxolane with a smaller amount of one or more bifunctional monomers. The two functional groups of the bifunctional monomer react under the same cationic polymerization conditions as the 1,3-dioxolane. The elastomeric acetal polymer does not crystallize even when the temperature is as low as -50.degree. C. The elastomeric acetal polymer is particularly useful for blending with crystalline acetal polymers to yield a composition with improved impact resistance.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: February 15, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: George L. Collins, William M. Pleban, Paul Zema
  • Patent number: 5281665
    Abstract: A thermoplastic resin composition is here provided which comprising99 to 50% by weight of at least one of engineering plastics (A) and1 to 50% by weight of an ethylene copolymer (B) having at least one of carbon-carbon unsaturated double bonds, and1 to 200 parts by weight, based on 100 parts by weight of the resin (A)+(B), of at least one selected from the group consisting of a rubber-like elastomer (C) and/or an olefin polymer or copolymer (D).
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: January 25, 1994
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Hirofumi Fukui, Katsufumi Suga
  • Patent number: RE34640
    Abstract: Block copolymers compose a polyisobutylene rubbery soft segment of M.sub.n of about 5,000 to above 500,000 and glassy hard segments of M.sub.n of about 5,000 or higher and usually about 10,000 to 35,000 or more, are made by preparing a living polymer block of the polyisobutylene and then polymerizing on said living polyisobutylene block the glassy hard segments by adding thereto an electron donor having a donor number of 15 to 50 and then adding and polymerizing the monomers for the glassy hard segments. The monomers for the glassy hard segments are styrene and its derivatives and indene and its derivatives and mixtures thereof.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: June 14, 1994
    Assignee: University of Akron
    Inventors: Joseph P. Kennedy, Judit E. Puskas, Gabor Kaszas, William G. Hager