Abstract: A heat transfer apparatus for processing a liquid continuously has a positive mechanical drive for a set of vertical whip rods each disposed in a vertical heat transfer tube. Each whip rod is free-standing on its lower end and is sufficiently flexible to conform closely to the inner surface of the tube as it orbits. The orbital drive propels the whip rod directly through a pair of horizontal, vertically spaced plates that engage the rods in loose openings that serve as fluid inlets from the drive plate. A motor rotates a drive shaft coupled to at least one of the drive plates through at least one eccentric crank. Each plate can be an opposed pair of plates with a separate eccentric drives 180.degree. out of phase with one another for a self balancing. Another form of drive plate uses a rigid circular ring that mounts rod-engaging sleeves via a network of wires supported by the ring.

Abstract: An apparatus and method for treating chemical production plant process condensate such that a contaminant-rich stream and a relatively pure aqueous stream is separately recoverable from the condensate, wherein the contaminants are substantially removed from the condensate by steam stripping and subsequent rectification in a relatively low pressure stripping/rectification tower. The tower overhead is then condensed with a portion of the condensed overhead being returned to the top of the rectification section of the tower as reflux and the balance being withdrawn as a concentrated stream for reuse in the plant. In a second embodiment, separate stripping and rectification towers operate in series whereby the overhead of the stripping tower is delivered to the lower section of the rectification tower and the rectification bottoms are returned to the top of the stripping tower.

Abstract: 1-Hexene is difficult to separate from hexane by conventional distillation or rectification because of the proximity of their boiling points. 1-Hexene can be readily separated from hexane by azeotropic distillation. Effective agents are 2-ethyl-1-butanol and diacetone alcohol.

Abstract: A water-treatment process which simultaneously performs degritting, degreasing, coagulation, flocculation and settling. The steps include breaking down into two elementary steps, at least least one of the degritting and degreasing functions and, simultaneously performing at least one of the following associated steps:coarse degritting and coagulation of untreated water;fine degritting and a first step for coalescence of grease particles, and high-energy flocculation;a second step for coalescence of the grease particles and low-energy flocculation, andseparating the greast particles and commencing a settling operation.

Abstract: 1-Decene is difficult to separate from decane by conventional distillation or rectification because of the proximity of their boiling points. 1-Decene can be readily separated from decane by azeotropic distillation. Effective agents are methyl propionate, ethyl butyrate and methyl t-butyl ether.

Abstract: 1-Octene is difficult to separate from octane by conventional distillation or rectification because of the proximity of their boiling points. 1-Octene can be readily separated from octane by azeotropic distillation. Effective agents are ethyl formate, ethyl acetate and t-amyl methyl ether.

Abstract: alpha-Phellandrene is difficult to separate from 3-carene by conventional distillation or rectification because of the proximity of their boiling points. alpha-phellandrene can be readily separated from 3-carene by azeotropic distillation. Effective agents are methyl formate, nitroethane and acetal.

Abstract: The process of this invention is directed to recovering diluted aqueous latex paint collected during cleaning of latex paint manufacturing equipment. The collected aqueous diluted latex paint is subjected to vacuum evaporation at temperatures between about 120.degree. F. and 170.degree. F. at reduced pressures of at least about 25 inches of mercury vacuum to produce a distillate containing above 99% by weight water and concentrated latex paint reusable as latex paint or as blend in latex paint products.

Abstract: The invention provides a method of producing ultra-fine particles and an apparatus therefor. A particle carrier is moved in a chamber which is decompresed and charged with inert gas. An evaporable material is heated so as to deposit evaporated ultra-fine particles onto a part of the moving particle carrier. The deposited ultra-fine particles are collected from the part of the moving particle carrier while evaporated ultra-fine particles deposit onto another part of the moving particle carrier.

Abstract: A long sand trap for separating and removing sand from inflow channels, particularly of sewage treatment plants is provided with a settling channel (1) having in particular a trapezoidal cross-section and extending along a straight path. A transporting conveyor device (8) which is acting opposite to the direction of flow is provided in the bottom area (6). A classifying conveyor device (10) discharges the sand delivered from the transporting conveyor device (8) in an upwardly inclined manner. The classifying conveyor device (10) is arranged in the central longitudinal plane (3) of the settling channel (1). It has a discharge chute (17) which can be used selectively left-hand or right-hand.

Abstract: The invention relates to a process for isolating pure diketene with recovery of materials of value by continuous, two-stage distillation of crude diketene at reduced pressure and with continuous reaction of the resulting distillation residue with acetic acid, pure diketene and acetic anhydride being separated off by means of the two-stage distillation. In the stabilization of the distillation residue with acetic acid, reutilizable acetic acid, which contains acetone with or without acetic anhydride, is recovered.

Abstract: Acetic acid and/or acetic anhydride containing methyl crotonate, vinyl acetate, or both as impurities, is contacted with ozone in an amount of excess molar to the carbon-carbon double bond in said methyl crotonate and/or vinyl acetate and the impurities produced by ozone-treatment are removed off by distillation. A large quantity of impurities such as aldehydes are produced after treatment by treating acetic acid and/or acetic anhydride containing much amount of unsaturated compounds as impurities with ozone. Distilling the ozone-treated acetic acid and/or acetic anhydride make it possible to remove methyl crotonate and vinyl acetate, which are unsaturated compounds difficult to remove by the conventional separation methods, to give high-quality acetic acid and/or acetic anhydride excellent in the residence time in the potassium permanganate test.

Abstract: 2-Butanol is difficult to separate from t-amyl alcohol by conventional distillation or rectification because of the proximity of their boiling points. 2-Butanol can be readily separated from t-amyl alcohol by extractive distillation. Effective agents are methyl caproate, adiponitrile and cyclopentanone.

Abstract: 1-Propanol is difficult to separate from 2-butanol by conventional distillation or rectification because of the proximity of their boiling points. 1-Propanol can be readily separated from 2-butanol by extractive distillation. Effective agents are isobutyl acetate, isobornyl methyl acetate and ethyl butyrate.

Abstract: Method and apparatus for the distillation of liquids which is particularly suited for the removal of soluble impurities and insoluble and non-volatile particles of 10 microns to 0.2 micron or less in size. A substantially elongated distillation chamber having walls equipped with axially disposed concentric boiling rings spaced from the walls near the bottom, and a packing stop, packing redirector rings for condensed vapor, and a reflux condenser in the upper part of the distillation chamber provide, during distillation, a smooth convective upward flow of distilling liquid and vapor proximate the walls and boiling rings and a smooth convective downward flow of distilling liquid and vapor substantially centrally of the distillation chamber.

Abstract: Contaminants are removed from impure propylene oxide by fractionating in a first column to remove overhead essentially all of the pentenes and pentanes and most of the oxygen-containing impurities to provide a partially purified first propylene oxide bottoms fraction, extractively distilling the first bottoms fraction in a second extractive column using a C.sub.2 to C.sub.6 alkylene glycol extractive distillation agent to form a second overhead fraction comprising propylene oxide, hexenes, hexanes, water, residual quantities of pentenes and pentanes and oxygen-containing impurities, extractively distilling the second overhead fraction in a third column using a C.sub.6 to C.sub.10 alkane hydrocarbon extractive distillation agent to form a third bottoms fraction comprising the extractive distillation agent, propylene oxide, hexenes, hexanes, residual quantities of pentenes and pentanes and water, and extractively distilling said third bottoms fraction in a fourth column using a C.sub.6 to C.sub.

Abstract: Crude propylene oxide is purified by a distillation process wherein it is (a) extractively distilled in a first column using a C.sub.2 to C.sub.6 alkylene glycol extractive distillation agent to form a first overhead fraction comprising propylene oxide, C.sub.5 -C.sub.7 hydrocarbons, methanol, water and oxygen-containing impurities, (b) wherein the first overhead fraction is separated in a plurality of intermediate distillation columns to provide an intermediate propylene oxide overhead fraction consisting essentially of propylene oxide and water, and (c) the intermediate propylene oxide overhead fraction is charged to a final distillation column using a C.sub.2 to C.sub.6 alkylene glycol extractive distillation agent to form a final overhead fraction consisting essentially of propylene oxide.

Abstract: Ethanol is difficult to separate from isopropanol by conventional distillation or rectification because of the proximity of their boiling points. Ethanol can be readily separated from isopropanol by extractive distillation. Effective agents are methyl caproate, cyclopentane and isobutyl acetate.

Abstract: This disclosure relates to an improved solar water purification system and process wherein the evaporating, condensing and distillate collecting chambers are located underground to assist in the evaporation and condensation process. The system includes three computer controlled preheaters which are constantly monitored to determine the temperature of the load therein. The cycling and recycling of the load relative to the load tank and the three preheaters is controlled by the computer for optimum system efficiency. One of the three preheaters is located underground, while a second preheater is located externally as a solar preheater and the third preheater is an outside gas, oil or waste heat fired preheater. In addition to producing pure water through the evaporation process, there is disclosed a system and process whereby various contaminants may be captured for further processing, storage and exploitation.

Abstract: The invention generally relates to a process for the purification of a component of a binary azeotrope in which the composition of the azeotrope changes by about 10 mole percent with pressure comprising:(a) subjecting a binary azeotrope to a distillation step in which most of one of the binary components is removed as distillate (distillate 1) with the bottoms (bottoms 1) enriched in the other component;(b) subjecting distillate 1 to at least one additional distillation step conducted at a different pressure in which most of the component recovered as bottoms 1 is removed as distillate 2 with the bottoms 2 enriched in the component enriched in distillate 1;(c) optionally repeating step (b) as many times as desired; and(d) recovering the desired purified component.The invention is particularly useful in the purification of pentafluoroethane in a pentafluoroethane/chloropentafluoroethane azeotrope.