Abstract: This invention relates to poly(acrylonitrile) homo- or co-polymer having a number average molecular weight (Mn) of at least 200,000 g/mol and a dispersity () of less than 1.3.

Abstract: Disclosed in the invention is a fluorine-containing polymer microsphere. A polymerization monomer, a photoinitiator and a stable dispersant are added into a reaction kettle, carbon dioxide gas is introduced for emptying air therein, then liquid carbon dioxide is injected, an initiating light source is used for irradiating in the reaction kettle after the temperature and pressure of the reaction kettle are constant, the reaction is performed under the conditions of ?20-30° C. and 20-70 bar, wherein the concentration of the polymerization monomer accounting for the total volume of the reactants is 0.02-2 g/ml, and the weight ratio of the photoinitiator, stable dispersant and polymerization monomer is (0.3-10):(2-20):100; after the reaction is finished, the temperature returns to room temperature, and the precipitate is washed with liquid carbon dioxide, so as to obtain the polymer microspheres.

Abstract: The present invention pertains to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer. The present invention provides a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article.

Abstract: The invention relates to a process a system and a high pressure pump for the preparation of a copolymer of ethylene and a di- or higher functional (meth)acrylate in a tubular reactor, comprising the steps of: injecting ethylene at a pressure of 100 MPa to 350 MPa into the reactor from a high pressure compressor and injecting the (meth)acrylate at a pressure of 100 MPa to 350 MPa into the reactor from a high pressure pump, wherein the high pressure pump comprises—a pump suction chamber for receiving a medium to be compressed; —a cylinder for receiving the medium to be compressed from the pump suction chamber; —an outlet for discharging a compressed medium from the cylinder, —a seal fixed to the inner wall of the cylinder at an end of the cylinder distal to the outlet and—a plunger movable in the cylinder by sliding through the seal, wherein a leakage gap is present along the plunger and the leakage gap is fluidly connected to the pump suction chamber.

Abstract: A process for controlling the placement of alpha olefins within an ethylene copolymer. The process involves polymerizing ethylene and an alpha olefin in the gas phase while changing the breadth of control over the molar ratio of ethylene to comonomer and/or hydrogen which is being fed to a polymerization reactor. At tighter control breadths, the alpha olefin may be incorporated mainly in the higher molecular weight portions of the ethylene copolymer. At looser control breadths, the alpha olefin may be incorporated more evenly throughout the ethylene copolymer or mainly in the lower molecular weight portions of the ethylene copolymer.

Abstract: A hydrophilic thickener comprising a polymer obtainable by subjecting a water-soluble ethylenically unsaturated monomer to a reversed phase suspension polymerization in the presence of a polyoxyethylene polyoxypropylene alkyl ether; and a cosmetic composition containing the hydrophilic thickener. The hydrophilic thickener according to the present invention can be used in the fields of cosmetics such as powder foundations, liquid foundations, emulsions, lotions, liquid cosmetics, moisturizing gel, all-in-one gels, cleansing foams, hair setting agents, emollient creams; toiletries, sundries, and the like.

Abstract: The present invention discloses a phenanthroline derivative is represented by the following formula(I), the organic EL device employing the phenanthroline derivative as hole blocking electron transport material, electron transport material can display good performance like as lower driving voltage and power consumption, increasing efficiency and half-life time. Wherein Ar, X, m, n, p and R1 to R3 are the same definition as described in the present invention.

Abstract: The invention features a packaging material including a film having a barrier layer formed from an admixture containing a base polymer and a surface-modifying macromolecule. The invention also features containers made from the packaging materials and methods of storing a good.

Abstract: An object of the present invention is to provide a rubber composition for tire that is excellent in abrasion resistance, initial grip performance and stability of grip performance while maintaining processability. The rubber composition for tire comprises a diene rubber component, a hydrocarbon resin containing a component unit derived from a monomer component having a heteroatom or a hydrogenated product thereof (resin A) and a hydrocarbon resin that does not contain a component unit derived from a monomer component having a heteroatom or a hydrogenated product thereof (resin B), wherein a content ratio (mass ratio) of the resin B to the resin A is 0.1 to 50.

Abstract: The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene and at least one asymmetrical polyene, comprising an “alpha, beta unsaturated—carbonyl end” and a “C—C double bond end,” and wherein the polymerization takes place in the presence of at least one free-radical initiator, and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone I and reaction zone i (i>2), wherein reaction zone I is downstream from reaction zone I; and wherein at least one chain transfer agent (CTA) is added to the polymerization, and wherein the CTA is a saturated hydrocarbon or an unsaturated hydrocarbon.

Abstract: Quinacridone pigments that are surface-functionalized with glycidyl methacrylate, maleic anhydride, or 4-methacryloxyethyl trimellitic anhydride to create a functionalized pigment. The functional groups are then activated to bond hydrophobic polymers, thereby coating the pigment with the hydrophobic polymers. The quinacridone pigments can be used for a variety of applications. They are well-suited for use in electro-optic materials, such as electrophoretic media for use in electrophoretic displays.

Abstract: A flow reactor system and methods having tubing useful as polymerization chamber. The flow reactor has at least one inlet and at least one mixing chamber, and an outlet. The method includes providing two phases, an aqueous phase and a non-aqueous phase and forming an emulsion for introduction into the flow reactor.

Abstract: Provided is a method for producing water-absorbent resin particles suitable for use in absorbent article and the like, the water-absorbent resin particles having better water-absorbent performance, a suitable particle size, and a narrow particle-size distribution. A method for producing water-absorbent resin particles by reversed-phase suspension polymerization of a water-soluble ethylenic unsaturated monomer in a carrier fluid, wherein the method for producing water-absorbent resin particles comprises conducting the reversed-phase suspension polymerization reaction in the presence of an organic acid monoglyceride.

Abstract: A compound comprising a first ligand LA of Formula I: is described. In Formula I, Z is selected from O, S, and Se; at least one of X1, X2, X3, and X4 is nitrogen, while the remainder are carbon; Y1 and Y2 are independently selected from NR, O, and S; R, RA, RB, and RC are each independently selected from a variety of substituents, and adjacent substitutions in R, RA, RB, and RC are optionally joined to form a fused ring; ligand LA is at least a tridentate ligand coordinated to a metal M; M is coordinated to ring A and to ring B through metal-carbene bonds; and the ligand LA is optionally linked with other ligands to comprise a tetradentate, pentadentate or hexadentate ligand. Formulations and devices, such as an OLEDs, that include the compound with a ligand LA of Formula I are also described.

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I), and compounds of formula (III), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula and their use as IR absorber, organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes.

Abstract: A method of exchanging or transforming end groups in and/or improving the ferroelectric properties of a PVDF-TrFE co-polymer is disclosed. A bulky or chemically dissimilar end group, such as an iodine, sulfate, aldehyde or carboxylic acid end group, may be transformed to a hydrogen, fluorine or chlorine atom. A method of making a PVDF-TrFE co-polymer is disclosed, including polymerizing a mixture of VDF and TrFE using an initiator, and transforming a bulky or chemically dissimilar end group to a hydrogen, fluorine or chlorine atom. A PVDF-TrFE co-polymer or other fluorinated alkene polymer is also disclosed. The co-polymer may be used as a ferroelectric, electromechanical, piezoelectric or dielectric material in an electronic device.

Abstract: Disclosed herein are highly active dilithio initiators prepared from high molecular weight dienes (C?6) and methods for the preparation of such compounds. These dilithio initiators result in greater control over polymer microstructure and provide useful polymers and oligomers with low vinyl incorporation.

Abstract: An organometallic compound represented by Formula 1: M(L1)n1(L2)n2(L3)n3??Formula 1 wherein in Formula 1, M, L1, L2, L3, n1, n2, and n3 are the same as defined in the specification.

Abstract: A process for preparation of a polymer product comprising the steps of i) feeding an aqueous mixture comprising a monoethylenically unsaturated monomer or a mixture of monoethylenically unsaturated monomers into a first reactor device (2) through at least one inlet; ii) partially polymerizing the monomer or monomers and transferring the polymerizing monomer or mixture of monomers from the inlet to an outlet (3) of the first reactor device (2) to provide a partially polymerized product; iii) flowing the partially polymerized product out of the outlet (3), in which no more than 60% of the monomer or mixture of monomers has been polymerized in the partially polymerized product as it exits the outlet (3) of first reactor device (2), and transferring it to a further reactor device (5), in which the further reactor device (5) has an inlet and an outlet (6); iv) continuing the polymerization in the further reactor device (5) and removing the polymer product from the outlet (6) of the further reactor device (5), ch

Abstract: Compositions and methods for silver plating onto metal surfaces such as PWBs in electronics manufacture to produce a silver plating which is greater than 80 atomic % silver, tarnish resistant, and has good solderability.