Abstract: A process for the manufacture of novel phosphorus-vanadium and phosphorus-vanadium cometal catalysts having a characteristic X-ray diffraction pattern suitable for use in the manufacture of maleic anhydride from butane and other C.sub.4 hydrocarbon feedstocks which process comprises reacting at a temperature of about 0.degree. C. to about 200.degree. C. a vanadium compound in an organic ether solvent having about 2 to about 10 carbon atoms with a phosphoryl halide in the presence of water or an aliphatic alcohol having from about 1 to about 8 carbon atoms, eliminating the solvent, and activating the catalyst by the addition of the hydrocarbon feedstock and water and a phosphorus compound at a temperature of about 300.degree. C. to about 500.degree. C. wherein the amount of water added is about 1,000 parts per million to about 40,000 parts per million by weight of the reactor feed gas stream is disclosed. The catalysts are useful for the manufacture of maleic anhydride from butane and other C.sub.

Abstract: Copper aluminum borate which is reducible under Temperature Programmed Reduction at a temperature no more than 350.degree. C. and/or has a surface area of at least 5 m.sup.2 /g and a pore volume of at least 0.04 cc per gram.

Abstract: A particulate catalyst composition suitable for purification of terephthalic acid under reducing conditions and a method of preparation of such catalyst are disclosed. The catalyst composition includes catalytically active rhodium on a porous, granular, carbonaceous support material having a surface area of at least about 600 m.sup.2 /gram. Rhodium is present in an amount of about 0.01 to about 2 weight percent, based on the total weight of dry catalyst composition and calculated as elemental metal. In the presence of hydrogen, this catalyst exhibits a reduced terephthalic acid decomposition rate that is comparable to that for a palladium-on-carbon catalyst having the same catalyst metal loading. The catalyst is prepared by contacting a carbonaceous support material having a surface area of at least 600 m.sup.2 /gm and a pH value in its aqueous suspension of 9-11 with an aqueous rhodium salt solution having a pH of 1-4.

Abstract: An organopolysulfide-impregnated catalyst composition usable to hydrotreat petroleum and other hydrocarbon feedstock is described. Also disclosed are processes for making and using the composition.

Abstract: A composition consisting essentially of surfactants, non-metal-crosslinked polymers, alkaline-reacting complexing agents, and a water-soluble organic solvent is suitable for preserving and cleaning hard surfaces, particularly floors. It is used in highly dilute form and leaves behind a hard, but readily redissolvable transparent protective film.

Abstract: A novel catalyst for recovering middle distillates comprising silica/titanium compound impregnated on an alumina and promoted with nickel and molybdenum.

Abstract: Method for cleaning vessels and in particular, steam generators, having deposits which are dissolved chemically and removed mechanically. The copper compounds present in the deposits are dissolved chemically and subsequently, loose deposits and liquids are removed mechanically. Encrustations still remaining are softened chemically and finally, the loosened deposits as well as the remaining chemicals are flushed out.

Abstract: The invention concerns a process for sulfurizing a catalyst, particularly a refining catalyst comprising a carrier and active metal oxides.In a first step, a sulfur compound mainly consisting of organic polysulfide is introduced into the catalyst mass. A second step consists of first sulfurizing, in the absence of hydrogen, the active metal oxides at a temperature lower than 275.degree. C. and then activating the catalyst at a temperature higher than 275.degree. C.The present invention concerns a process for presulfurizing a hydrocarbon treatment catalyst and/or preconditioning a catalyst in view of subsequent presulfurization.

Abstract: A starting slurry composed of raw brown coal and a solvent is heated and pressurized, subjected to gas-liquid separation and dehydration and then to hydrogenation/liquefaction. The CO.sub.2 -containing gas produced in the preheating/dehydration step and/or a CO.sub.2 -containing gas supplied from outside the system is blown into the slurry in the above-mentioned preheating/dehydration step, whereby carbonate-forming metal components in the brown coal are converted to the carbonates thereof in advance. In this manner, the hydrogenation/liquefaction efficiency is improved, and stabilized long-term continuous operation is attained.

Abstract: A method for the preparation of a high activity palladium metal based catalyst having the formulaPdTe.sub.a Zn.sub.d E.sub.ewhereE is one or more metals from the group IIA, IVA, VA, IB, VIIB or VIII; anda, d and e are from about 0 to 3, with the proviso that at least d or e.noteq.0.The method comprises the step of forming an aqueous solution of a palladium compound, adding to the solution a powder of a reducing metal more electropositive than palladium and reducing the palladium to its metallic state on the surface of the reducing metal and, separating the resulting catalyst from the solution. Catalysts prepared according to this method are useful for producing esters from aldehydes and alcohols and provide greater conversions to the ester than catalysts prepared by previous processes.

Abstract: A composition and method for removing deposits (10) from the internal components (24) of a gas turbine engine (18) utilizing a cleaning composition (15) which comprises an aqueous solution of hydroxylamine sulfate, a chelating agent, a compound selected from the group consisting of ammonium sulfamate, ammonium sulfamide, and hydroxylamine-o-sulfonic acid, and, an alkaline pH modifying substance added in an amount sufficient to achieve a pH value of between 6.5 and 14. The method involves contacting the deposits with the cleaning composition, such as in an apply and soak type pattern, chemically dislodging the deposits from the component surfaces. The engine is rinsed to remove the dislodged deposits and residual cleaning composition.

Abstract: Alkali metal aluminum silicate scale deposits are removed from surfaces of chemical processing equipment by alternating treatments with acidic and basic solutions, with optional rinsing of the equipment between treatments.

Abstract: A method for the removal of sub-micron contaminant particles from a surface, such as the surface of a semiconductor wafer. The method comprises washing the contaminated surface in a cleaning solution of a high-molecular-weight highly-fluorinated organic surfactant in a non-ionic highly-fluorinated organic carrier. The surface is then rinsed with a rinsing liquid, which is also a highly-fluorinated organic liquid, and which may be the same as the carrier liquid. In a preferred embodiment, a cascade rinsing method is provided in which the rinsing liquid for each rinsing step is the effluent of the subsequent rinsing step. In a further embodiment, the rinsing liquid has a lower boiling point than the surfactant to permit regeneration of the rinsing liquid by distillation of rinse effluent.

Abstract: A catalystic composition suitable for producing acrylonitrile from propylene, ammonia and oxygen (or oxygen-containing gas), which composition is represented by the following formula:(Mo).sub.a (W).sub.b (Bi).sub.c (Pb).sub.d (B).sub.e (Sb).sub.f (X).sub.g (O).sub.h(where: X is chromium or iron; a, b, c, d, e, f, g and h denote respectively number of atoms for molybdenum, tungsten, bismuth, lead, boron, antimony, X and oxygen, and wherein, if it is given that a+b=12, 0.ltoreq.b.ltoreq.7, 0.4.ltoreq.c.ltoreq.7, 2.ltoreq.d.ltoreq.12, 0.2/22.ltoreq.e/a.ltoreq.40/22, 0.ltoreq.f/a.ltoreq.25/22, and 0.ltoreq.g/a.ltoreq.3/22; and h denotes the number of oxygen necessary for satisfying the atomic valence for the individual constituent elements other than oxygen).

Abstract: Improved supported, mixed-metal oxide oxidation catalysts are prepared by conditioning a devolatilized catalyst precursor with an alcohol prior to calacining the precursor to a finished catalyst. For example, a promoted bismuth phosphomolybdate oxidation catalyst useful for converting propylene to acrolein demonstrates enhanced performance characteristics when the devolatilized catalyst precursor is subjected to boiling ethanol prior to calcining it to a finished catalyst.

Abstract: A liquefaction process for coal lignite or heavy oil is disclosed utilizing a hydrogen-donor solvent. The preferred hydrogen-donor solvent is recovered as a vapor from the liquefaction mixture. The preferred method for converting the vapor into active hydrogen-donor solvent form involves passage of the vapor over a catalyst bed positioned in the vapor space of the catalyst vessel. Novel apparatus for so positioning the catalyst bed is also disclosed.

Abstract: An improved olefin disproportionation catalyst produced by contacting (a) molybdenum or tungsten oxide supported on inorganic refractory oxide, and (B) a metal dithionite.

Abstract: A process for production of alkali metal polyphosphates and/or pyriphosphates from an alkali metal orthophosphate comprises acidifying said orthophosphate with sulphuric acid, and then either(a) heating the reaction mixture to produce the desired products, and recovering said products from the reaction mixture, or(b) separating an intermediate from the reaction mixture, and heating the intermediate to form a desired product.The products are suitable for incorporation into detergents and soap powders.

Abstract: Formaldehyde is made from methane and a molecular oxygen containing gas by using a silica supported catalyst having less than 350 parts per million by weight of sodium and having a catalytically effective amount of MoO.sub.3. The low sodium form of the silica support can be made by washing silica gel or precipitated silica, by using a fumed silica or by making an ultrapure form of silica having a silica purity of at least 99.99% silica. The ultrapure form can be made by the hydrolysis of silicon tetraalkoxides. In general, the lower the sodium level, the better is the catalyst.

Abstract: A colloidal hydrosilylation catalyst is provided by effecting reaction between a silicon hydride or a siloxane hydride and a Pt(O) or Pt(II) catalyst. The colloidal catalyst forms stable mixtures with olefinically unsaturated organopolysiloxanes.