Abstract: A method for the precipitation of rare earth sulphate, the method including subjecting a crude rare earth sulphate solution to precipitation in the presence of a water soluble, volatile, organic compound to produce a rare earth sulphate precipitate and an acidic supernatant. The organic compound is preferably selected from the group consisting of methanol, ethanol, iso-propanol, tert-butanol, acetone or mixtures thereof, and is preferably methanol. Preferably, the organic compound is used in the precipitation at a weight ratio of between 0.25:1 to 1.5:1, and preferably 0.5:to 1.25:1, with the crude sulphate solution.
Abstract: Metal organic resins, composite materials composed of the metal organic resins, and anion exchange columns packed with the composite materials are provided. Also provided are methods of using the composite materials to remove metal anions from a sample, methods of using the metal organic resins as fluorescence sensors for detecting metal anions in a sample, and methods of making the metal organic resins and the composite materials. The metal organic resins are amine-functionalized metal organic frameworks and their associated counter anions. The composite materials are composed of metal organic resin particles coated with organic polymers, such as alginic acid polymers.
Type:
Grant
Filed:
May 10, 2021
Date of Patent:
January 2, 2024
Assignee:
Northwestern University
Inventors:
Mercouri G. Kanatzidis, Debajit Sarma, Emmanouil Manos
Abstract: A method for manufacturing an adsorption agent for treating compressed gas, which includes the steps of providing a monolithic supporting structure; producing a coating suspension that includes an adsorbent; applying the coating suspension on the supporting structure to form a coating; applying a thermal treatment to the coated supporting structure in order to sinter the coating.
Abstract: Continuous thermolysis of carbonaceous matter in a controlled temperature and steam environment to produce a low volatility char, with subsequent steam activation of the char under pressure producing activated carbon and pressurized syn-gas, all of which are carried out in a reactor system including one or more vessels. The syn-gas is enriched in hydrogen in a high temperature shift reactor and separated in a pressurized swing adsorber to provide a pressurized pure hydrogen stream and a low-pressure combustible tail gas. The tail gas and the volatiles from the thermolysis step are combusted to provide process steam and electric power. The electric power is used to supplement the thermal requirements of the process with the balance being exported.
Abstract: The invention relates to novel methods for preparing N-methyl-p-toluidine for the use thereof as additive for aviation fuel, and to specific catalysts for these methods.
Type:
Grant
Filed:
May 28, 2020
Date of Patent:
December 5, 2023
Assignee:
LANXESS Corporation
Inventors:
Martina Gerdinand, Rainer Dost, Ralf Krahwinkel, Hans-Jurgen Quella, Daniel Ullrich, Patrick Kurr
Abstract: The present invention relates to novel active compound combinations comprising at least one known compound of the formula (I) and at least one further active compound, which combinations are highly suitable for controlling animal and microbial pests such as unwanted insects and/or unwanted acarids and/or unwanted nematodes.
Type:
Grant
Filed:
October 12, 2018
Date of Patent:
November 21, 2023
Assignee:
Bayer Aktiengesellschaft
Inventors:
Silvia Cerezo-Galvez, Christian Marienhagen, Holger Weckwert, Wolfgang Thielert, Marita John
Abstract: An exhaust gas purification catalyst including an alkaline-earth metal carried on a porous carrier in a highly dispersed state. The catalyst layer of the exhaust gas purification catalyst has an alkaline-earth metal carrying region including a porous carrier, Pt, and a sulfuric acid salt of at least one alkaline-earth metal carried on the porous carrier, wherein a value of RAe/Pt is 0.5 or more, where RAe/Pt represents the Pearson's correlation coefficient calculated using ? and ? in each pixel obtained by, for a cross section of the region, performing the area analysis by FE-EPMA under the conditions of: pixel size 0.34 ?m×0.34 ?m; and number of measured pixels 256×256; and measuring an intensity (?: cps) of a characteristic X ray of an element (Ae) of the alkaline-earth metal and an intensity (?: cps) of a characteristic X ray of Pt for each pixel.
Type:
Grant
Filed:
September 9, 2019
Date of Patent:
November 21, 2023
Assignees:
CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA
Abstract: A multi-function catalyst article for treating both NO and carbon monoxide emissions in a flow of a combustion exhaust gas from a stationary emission source comprises a honeycomb monolith substrate comprising one or more channels which are open at both ends and extend along an axial length thereof and through which, in use, a combustion exhaust gas flows, which catalyst article comprising a catalyst composition comprising a combination of a first, vanadium-containing SCR catalyst component and a second component which is a compound of a transition metal comprising copper, manganese, cobalt, molybdenum, nickel or cerium or a mixture of any two or more thereof and optionally a third, crystalline molecular sieve component.
Type:
Grant
Filed:
September 24, 2020
Date of Patent:
November 21, 2023
Inventors:
Paul Joseph Andersen, Ferdinand Baer, Maria Theresia Brandmair, Kevin Doura, Heike Kreuder, Desiree Duran Martin
Abstract: A catalytic reactor for industrial-scale hydrogenation processes is described. The catalytic reactor contains a catalytic fixed bed that comprises a support structure and a catalyst. During operation of the reaction in the catalytic reactor, the fixed bed is filled with reaction medium to at least 85% by volume. A very high contact area of the catalyst with the reaction medium is at the same time provided. The support structure is formed from material webs having a thickness of 5 to 25 ?m, with a crosslinking density of at least 3 mm?3 present. The support structure consists of metals selected from elements of groups 8, 6 and 11 of the periodic table of the elements and mixtures thereof.
Type:
Grant
Filed:
September 25, 2020
Date of Patent:
November 21, 2023
Assignee:
Evonik Operations GmbH
Inventors:
Meike Roos, René Poss, Monika Berweiler, Markus Göttlinger
Abstract: A method for coating a monolithic porous catalyst support having a plurality of channels formed in a longitudinal direction with a catalyst slurry, and a device therefor are proposed. A pressure dispersion coating device for a porous catalyst support includes: a slurry quantitative input means; a container being variable in volume, having an open upper part thereof into which a slurry is input by the slurry quantitative input means, and having a bottom thereof movable; a container moving means fastened to one side of the container; a moving means fastened to a lower part of the container and having a shaft connected to the bottom of the container; an overflow outlet being formed on a side part of the container and provided with a valve; and a pressurizing means disposed on the open upper part of the container.
Type:
Grant
Filed:
October 4, 2019
Date of Patent:
November 14, 2023
Assignee:
HEESUNG CATALYSTS CORPORATION
Inventors:
Hyun-sik Han, Dong-Sun Seo, Myeong-cheol Seon, Seung-bok Yu
Abstract: A heterogeneous catalyst comprising a support and gold, wherein: (i) said support comprises alumina, (ii) said catalyst comprises from 0.1 to 5 wt % of gold, (iii) at least 90 wt % of the gold is in the outer 60% of catalyst volume, and (iv) particles of the catalyst have an average diameter from 200 microns to 30 mm; wherein weight percentages are based on weight of the catalyst.
Type:
Grant
Filed:
June 20, 2019
Date of Patent:
November 14, 2023
Assignees:
Rohm and Haas Company, Dow Global Technologies LLC
Inventors:
Kirk W. Limbach, Christopher D. Frick, Dmitry A. Krapchetov, Wen -Sheng Lee, Victor J. Sussman, Jeffrey A. Herron
Abstract: A gasoline engine exhaust gas purification catalyst for purifying exhaust gas emitted from a gasoline engine includes a precious metal, alumina, and a ceria/zirconia composite oxide supported on a three-dimensional structure, and has pores having a peak 1 at a pore size of not less than 0.001 ?m and not greater than 0.05 ?m, pores having a peak 2 at a pore size of not less than 2.5 ?m and not greater than 5.0 ?m, and pores having a peak 3 at a different pore size than the above pore sizes in a pore size distribution measured by mercury intrusion method, wherein the pore volume of the pores having the peak 3 is greater than 1.4% of the total pore volume. A production method for the catalyst, and an exhaust gas purification method using the catalyst are also described.
Abstract: [Object] To provide a method for efficiently producing a water-absorbing agent having excellent physical properties. [Solution] The method for producing a water-absorbing agent includes a drying step of drying a particulate crosslinked hydrogel polymer containing a drying aid. The drying aid is (a) a compound having a betaine structure and having a long-chain alkyl group having 8 or more carbon atoms, one quaternary nitrogen, and one acid group within a molecule thereof and/or (b) a compound having a long-chain alkyl group having 8 or more carbon atoms, one tertiary nitrogen, and one or more acid groups within a molecule thereof. An addition amount of the drying aid with respect to a gel solid content of the particulate crosslinked hydrogel polymer is 0.001% by mass to 0.5% by mass. In this production method, surface-crosslinking is performed on water-absorbent resin powder obtained through the drying step.
Type:
Grant
Filed:
June 20, 2017
Date of Patent:
November 7, 2023
Assignee:
NIPPON SHOKUBAI CO., LTD.
Inventors:
Ryota Wakabayashi, Mai Sato, Motohiro Imura, Tokio Shuto, Yoshihiro Shobo
Abstract: Methods for producing porous graphic carbon microspheres having improved separation properties over conventional porous graphitic carbons. The methods include dispersing a monovinyl aromatic monomer, a polyvinyl aromatic monomer, and an initiator in a solvent, contacting porous silica microspheres with the monomer dispersion for a time sufficient for the monomers to coat the porous silica microspheres, polymerizing the monomers to form copolymer coated microspheres, sulfonating the copolymer, pyrolyzing the sulfonated copolymer, digesting the carbon microspheres to dissolve the silica leaving porous carbon microspheres, pyrolyzing the porous carbon microspheres, and graphitizing the porous carbon microspheres to form porous graphitic carbon microspheres. Further provided are improved porous graphitic carbon microspheres and chromatography columns including the improved porous graphitic carbon microspheres described herein.
Type:
Grant
Filed:
June 16, 2021
Date of Patent:
November 7, 2023
Assignee:
Sigma-Aldrich Co. LLC
Inventors:
William R. Betz, Michael J. Keeler, Curtis W. Frantz, Jay M. Jones, William Maule, Kenneth G. Espenschied, Cory E. Muraco, Clinton Corman, Maochun Ye
Abstract: A method of controlling aphid pests includes exposing the aphid pests on a host plant to an effective pest-controlling amount of a triketone compound having the following formula:
Abstract: Provided is an exhaust gas purification catalyst capable of reducing a noble metal amount while maintaining a catalyst performance, which comprises a substrate and at least three catalyst coating layers formed on the substrate, the first and third catalyst coating layers contain Pd as a catalyst metal and are formed in a range of a predetermined length from an upstream end surface in an exhaust gas flow direction, and the second catalyst coating layer contains Rh as a catalyst metal and is formed in a range of a predetermined length from a downstream end surface in the exhaust gas flow direction.
Type:
Grant
Filed:
March 24, 2021
Date of Patent:
October 24, 2023
Assignees:
TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
Abstract: The invention relates to ester compounds of the general formula (I) to a process for preparation thereof and to the use thereof. These ester compounds may contain a mixture of at least two compounds of the general formula (I).
Type:
Grant
Filed:
October 29, 2020
Date of Patent:
October 24, 2023
Assignees:
Klüber Lubrication München SE & Co. KG, Universität Bielefeld
Inventors:
Tobias Betke, Carmen Plass, Harald Gröger, Dirk Loderer, Stefan Seemeyer, Thomas Kilthau, Ling Ma
Abstract: A methane production apparatus (200) includes: a holding unit (110) configured to hold any one or both of: a metal organic framework containing any one or a plurality of chromium, copper, and magnesium, and storing carbon dioxide; and potassium bicarbonate; and a hydrogen supply unit (140) configured to supply hydrogen to the holding unit (110).
Type:
Grant
Filed:
July 14, 2020
Date of Patent:
October 17, 2023
Assignees:
TOKYO GAS CO., LTD., THE UNIVERSITY OF TOKYO
Abstract: Disclosed are a low-temperature de-NOx catalyst using a ceria-alumina complex support, and a method of manufacturing the same. According to the present invention, provided is a low-temperature de-NOx catalyst using a ceria-alumina complex support, manufactured by impregnating noble metal and metal oxides into a ceria-alumina complex support synthesized by treating a ceria precursor and an alumina precursor in a predetermined mass ratio by a co-precipitation method.
Type:
Grant
Filed:
August 26, 2020
Date of Patent:
October 3, 2023
Assignee:
KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION
Inventors:
Kwan Young Lee, Ki Bong Lee, Hyun Wook Kim