Patents by Inventor A. Clifton Lilly, Jr.
A. Clifton Lilly, Jr. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7413725Abstract: A method of making Cu, Zn, and/or Cu/Zn alloy nanoparticles subjects one or more targets to laser energy to form a vapor and condenses the vapor to form nanoparticles having an average particle size of less than 20 nm. The optional application of an electric field results in nanoparticles with aspect ratios greater than 1.0. The target(s) can be a single target or separate targets comprising a mixture of copper, zinc, and/or copper/zinc. When separate targets are used, the laser beam can be split to form two separate beams each of which is made incident upon one of the targets. The nanoparticles can be formed in a chamber having an inert atmosphere or a reactive atmosphere and a convection current is created in the chamber by maintaining the top plate at a lower temperature than the bottom plate.Type: GrantFiled: August 11, 2004Date of Patent: August 19, 2008Assignee: Philip Morris USA Inc.Inventors: M. Samy El-Shall, Sarojini Deevi, Yezdi B. Pithawalla, Seetharama C. Deevi, A. Clifton Lilly, Jr.
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Patent number: 6869275Abstract: A piezoelectrically driven fluid pump includes a chamber having two opposite sidewalls formed by flexible membranes, and an inlet and an outlet each regulated by a valve. Separate piezo elements are fixed to each of the membranes, to flex the membranes and increase or reduce the chamber volume and thereby draw fluid into the chamber or expel fluid from the chamber. The valves are each formed by two adjacent piezo elements that are supported or flexibly joined together at two opposite ends. When actuated, the valve piezo elements flex outward between the two opposite ends, opening the valve to form an aperture between the two piezo elements. In another embodiment, a fluid pump includes a chamber having one flexible membrane sidewall. A valve-regulated inlet or outlet aperture through the membrane communicates with the pump chamber. A ring-shaped piezo centered around the aperture, on the membrane, flexes the membrane.Type: GrantFiled: February 14, 2002Date of Patent: March 22, 2005Assignee: Philip Morris USA Inc.Inventors: Henry M. Dante, Hector Alonso, A. Clifton Lilly, Jr.
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Patent number: 6848450Abstract: A filter such as a cigarette filter having a metal reagent which selectively binds with a gaseous component of a gas stream such as tobacco smoke. The metal reagent comprises nanometer or micrometer size clusters of a transition metal or alloy containing a transition metal. The transition metal can be incorporated in an intermetallic compound such as titanium aluminide or iron aluminide. The metal clusters can be incorporated in or on a support material such as silica gel, porous carbon or a zeolite. The metal reagent can remove the gaseous component by selectively binding to unsaturated hydrocarbons such as 1,3-butadiene. The binding can occur by insertion of a metal atom of the metal reagent into a C—H bond or a C—C bond of the gaseous component.Type: GrantFiled: February 7, 2001Date of Patent: February 1, 2005Assignee: Philip Morris USA Inc.Inventors: A. Clifton Lilly, Jr., Kent B. Koller, John B. Paine, III, Purusottam Jena, Bijan K. Rao
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Patent number: 6739700Abstract: An on-demand inkjet printhead includes an ink chamber provided with a plurality of nozzles and a single piezoelectric actuator for increasing pressure of ink within the chamber. Each nozzle is equipped with a heater element. Ink is ejected from selected nozzles of the printhead by energizing the heater elements of the selected nozzles to reduce surface tension and viscosity of ink at the selected nozzles, and applying an actuation voltage to the piezoelectric actuator to generate a pressure pulse in the ink within the ink chamber that ejects ink droplets from the selected nozzles but not from the non-selected nozzles. The ink chamber can also be provided with a plurality of piezoelectric actuators, each of which can be actuated independently.Type: GrantFiled: December 4, 2002Date of Patent: May 25, 2004Assignee: Philip Morris IncorporatedInventors: Henry M. Dante, A. Clifton Lilly, Jr.
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Patent number: 6690016Abstract: A method and apparatus for detecting, locating, isolating and controlling variations in the manufacturing process by transient thermography. A heat source (200) imparts heat to a surface which is radiated in the infrared region. Infrared sensors (204, 206, 208, 210) are coupled to a processor which tracks the physical characteristics of the sample, and provides feedback to a central process controller to make adjustments to the manufacturing process. The sample can be a continuous product such as a green powder metal sheet or tobacco product.Type: GrantFiled: December 6, 2000Date of Patent: February 10, 2004Assignee: Philip Morris IncorporatedInventors: Michael L. Watkins, Grier S. Fleischhauer, A. Clifton Lilly, Jr.
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Patent number: 6688313Abstract: An electrical smoking system comprising a cigarette and an electric lighter, wherein the cigarette comprises a tubular tobacco mat partially filled with material tobacco so as to define a filled tobacco rod portion and an unfilled tobacco rod portion. The cigarette and the lighter are mutually arranged so that when the cigarette is received in the lighter, the electrical heater element of the lighter at least partially superposes at least a portion of the filled tobacco rod portion. The cigarette and the lighter are also mutually arranged so that when the cigarette is received in the lighter, the free end of the cigarette is occluded. The cigarette includes a zone of perforations at a location along the filled tobacco rod portion, with the cigarette being free of perforations along the unfilled tobacco rod portion. An apparatus for perforating a cigarette which can be smoked in an electrical smoking device includes a drum link-up assembly and a laser perforating apparatus.Type: GrantFiled: March 23, 2001Date of Patent: February 10, 2004Assignee: Philip Morris IncorporatedInventors: Susan E. Wrenn, A. Clifton Lilly, Jr., Traci L. Franklin, Patrick H. Hayes, Mary Ellen Counts, William James Crowe
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Patent number: 6660109Abstract: A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as ≦1% Cr, ≧0.05% Zr ≦2% Ti, ≦2% Mo, ≦1% Ni, ≦0.75% C, ≦0.1% B, ≦1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, ≦1% rare earth metal, and/or ≦3% Cu.Type: GrantFiled: October 31, 2001Date of Patent: December 9, 2003Assignee: Chrysalis Technologies IncorporatedInventors: Mohammad R. Hajaligol, Clive Scorey, Vinod K. Sikka, Seetharama C. Deevi, Grier Fleishhauer, A. Clifton Lilly, Jr., Randall M. German
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Patent number: 6637439Abstract: A tobacco smoking mixture is provided that includes tobacco and at least one inorganic particulate material. The at least one inorganic particulate material is effective to reduce the temperature of a burning portion of the tobacco smoking mixture upon combustion/pyrolysis thereof. The at least one inorganic particulate material can be an inorganic carbonate, an inorganic hydrate, an inorganic oxide, an inorganic phosphate, a carbon material or combinations thereof.Type: GrantFiled: August 31, 2001Date of Patent: October 28, 2003Assignee: Philip Morris IncorporatedInventors: Mohammad R. Hajaligol, A. Clifton Lilly, Jr.
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Patent number: 6607576Abstract: The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, ≦1% Cr and either ≧0.05% Zr or Zro2 stringers extending perpendicular to an exposed surface of the heating element or ≧0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, ≦2% Ti, ≦2% Mo, ≦1% Zr, ≦1% C, ≦0.1% B. ≦30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, ≦1% rare earth metal, ≦1% oxygen, ≦3% Cu, balance Fe.Type: GrantFiled: October 14, 1998Date of Patent: August 19, 2003Assignee: Chrysalis Technologies IncorporatedInventors: Vinod K. Sikka, Seetharama C. Deevi, Grier S. Fleischhauer, Mohammad R. Hajaligol, A. Clifton Lilly, Jr.
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Patent number: 6533395Abstract: An on-demand inkjet printhead includes an ink chamber provided with a plurality of nozzles and a single piezoelectric actuator for increasing pressure of ink within the chamber. Each nozzle is equipped with a heater element. Ink is ejected from selected nozzles of the printhead by energizing the heater elements of the selected nozzles to reduce surface tension and viscosity of ink at the selected nozzles, and applying an actuation voltage to the piezoelectric actuator to generate a pressure pulse in the ink within the ink chamber that ejects ink droplets from the selected nozzles but not from the non-selected nozzles. The ink chamber can also be provided with a plurality of piezoelectric actuators, each of which can be actuated independently.Type: GrantFiled: January 18, 2001Date of Patent: March 18, 2003Assignee: Philip Morris IncorporatedInventors: Henry M. Dante, A. Clifton Lilly, Jr.
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Patent number: 6446426Abstract: A miniature heat source capable of being used in a hand-held device for delivering a metered pulse of fuel to a combustion chamber where it is converted into a pulsed amount of heat. For example, the heat source apparatus can be used in a hand-held cigarette smoking system or within a portable device wherein a microturbine generates electricity, as well as any type of environment where a high energy pulse of heat is desired. The heat source includes a valve such as a sliding, rotatable or timed valve which delivers a metered volume of fuel to the combustion chamber. The valve can deliver the fuel, in an expanded gaseous form, to a venturi conduit which increases the velocity of the gas flow, and delivers the fuel to a combustion chamber where the gas is mixed with air. The combustible mixture is then combusted within the combustion chamber by ignition and/or by catalyzed oxidation.Type: GrantFiled: May 3, 2000Date of Patent: September 10, 2002Assignee: Philip Morris IncorporatedInventors: William R. Sweeney, A. Clifton Lilly, Jr.
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Patent number: 6332936Abstract: A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as ≦1% Cr, ≧0.05% Zr ≦2% Ti, ≦2% Mo, ≦1% Ni, ≦0.75% C, ≦0.1% B, ≦1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, ≦1% rare earth metal, and/or ≦3% Cu.Type: GrantFiled: September 20, 1999Date of Patent: December 25, 2001Assignee: Chrysalis Technologies IncorporatedInventors: Mohammad R. Hajaligol, Clive Scorey, Vinod K. Sikka, Seetharama C. Deevi, Grier Fleischhauer, A. Clifton Lilly, Jr., Randall M. German
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Patent number: 6284191Abstract: A powder metallurgical process of preparing iron aluminide useful as electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 20 to 32% Al, and optional additions such as ≦1% Cr, ≧0.05% Zr or ZrO2 stringers extending perpendicular to an exposed surface of the heating element, ≦2% Ti, ≦2% Mo, ≦1% Zr, ≦1% C, ≦0.1% B, ≦30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, ≦1% rare earth metal, ≦1% oxygen, and/or ≦3% Cu.Type: GrantFiled: September 20, 1999Date of Patent: September 4, 2001Assignee: Chrysalis Technologies IncorporatedInventors: Seetharama C. Deevi, A. Clifton Lilly, Jr., Vinod K. Sikka, Mohammed R. Hajaligol
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Patent number: 6280682Abstract: The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, ≦1% Cr and either ≧0.05% Zr or ZrO2 stringers extending perpendicular to an exposed surface of the heating element or ≧0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, ≦2% Ti, ≦2% Mo, ≦1% Zr, ≦1% C, ≦0.1% B, ≦30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, ≦1% rare earth metal, ≦1% oxygen, ≦3% Cu, balance Fe.Type: GrantFiled: September 20, 1999Date of Patent: August 28, 2001Assignee: Chrysalis Technologies IncorporatedInventors: Vinod K. Sikka, Seetharama C. Deevi, Grier S. Fleischhauer, Mohammad R. Hajaligol, A. Clifton Lilly, Jr.
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Patent number: 6033623Abstract: A powder metallurgical process of preparing iron aluminide useful as electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 20 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1 % rare earth metal, .ltoreq.1% oxygen, and/or .ltoreq.3% Cu.Type: GrantFiled: July 11, 1996Date of Patent: March 7, 2000Assignee: Philip Morris IncorporatedInventors: Seetharama C. Deevi, A. Clifton Lilly, Jr., Vinod K. Sikka, Mohammed R. Hajaligol
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Patent number: 6030472Abstract: A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr.ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3% Cu.Type: GrantFiled: December 4, 1997Date of Patent: February 29, 2000Assignee: Philip Morris IncorporatedInventors: Mohammad R. Hajaligol, Clive Scorey, Vinod K. Sikka, Seetharama C. Deevi, Grier Fleischhauer, A. Clifton Lilly, Jr., Randall M. German
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Patent number: 5976458Abstract: The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.Type: GrantFiled: January 3, 1996Date of Patent: November 2, 1999Assignee: Philip Morris IncorporatedInventors: Vinod K. Sikka, Seetharama C. Deevi, Grier S. Fleischhauer, Mohammad R. Hajaligol, A. Clifton Lilly, Jr.
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Patent number: 5880439Abstract: An electrically powered functionally graded ceramic composite heater and a functionally stepped ceramic composite heater useful for cigarette lighters. The electrical resistance heater includes discrete heating zones wherein each zone of the heater can be activated using an electric control module, and is capable of heating to a temperature in the range of 600.degree. C. to 900.degree. C. using portable energy devices. The ceramic heater can be made by pressing together layers of differing amounts of constituents of the ceramic precursor material followed by secondary processing steps to obtain discrete heating elements. The heater design can include a hub on one end to provide structural integrity, and function as a common for the heating zones.Type: GrantFiled: March 12, 1996Date of Patent: March 9, 1999Assignee: Philip Morris IncorporatedInventors: Seetharama C. Deevi, A. Clifton Lilly, Jr.
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Patent number: 5865185Abstract: A smoking article is provided in which a replaceable tobacco flavor unit containing tobacco flavor material is electrically heated by a set of permanent reusable heaters to evolve flavors or other components in vapor or aerosol form for delivery to a smoker. Each heater heats only a portion of the available tobacco flavor material so that a plurality of individual puffs of tobacco flavor substance can be delivered sequentially to the smoker. The replaceable tobacco flavor unit can also include a filter to reduce the effect of residual aerosol which settles or condenses on the permanent portions of the article and which can result in undesirable flavor generation when reheated. A method and apparatus for manufacturing the replaceable tobacco flavor unit is also provided.Type: GrantFiled: May 24, 1995Date of Patent: February 2, 1999Assignee: Philip Morris IncorporatedInventors: Alfred L. Collins, Mary Ellen Counts, Amitabh Das, Seetharama C. Deevi, Grier S. Fleischhauer, Charles T. Higgins, Willie G. Houck, Jr., Billy J. Keen, Jr., Robert E. Lee, III, A. Clifton Lilly, Jr., D. Bruce Losee, Jr., Hugh J. McCafferty, Constance H. Nichols, Wynn R. Raymond, Robert L. Ripley, Renzer R. Ritt, Sr., G. Robert Scott, F. Murphy Sprinkel, Michael L. Watkins, Susan E. Wrenn, Francis V. Utsch
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Patent number: 5730158Abstract: A smoking article is provided in which a replaceable tobacco flavor unit containing tobacco flavor material is electrically heated by a set of permanent reusable heaters to evolve flavors or other components in vapor or aerosol form for delivery to a smoker. Each heater heats only a portion of the available tobacco flavor material so that a plurality of individual puffs of tobacco flavor substance can be delivered sequentially to the smoker. The replaceable tobacco flavor unit can also include a filter to reduce the effect of residual aerosol which settles or condenses on the permanent portions of the article and which can result in off-tastes when reheated. A method and apparatus for manufacturing the replaceable tobacco flavor unit is also provided.Type: GrantFiled: May 24, 1995Date of Patent: March 24, 1998Assignee: Philip Morris IncorporatedInventors: Alfred L. Collins, Mary E. Counts, Amitabh Das, Seetharama C. Deevi, A. Clifton Lilly, Jr., D. Bruce Losee, Jr., Michael L. Watkins, Francis V. Utsch