Patents by Inventor Adrianus Theodorus SMIT

Adrianus Theodorus SMIT has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11492753
    Abstract: Lignocellulosic biomass can be fractionated for the purpose of increasing cellulose purity in the pulp, increasing native lignin content of the isolated lignin, and improving cellulose hydrolysis, by performing the steps of: (a) extracting the biomass with an extracting liquid comprising at least 20 wt % of a first organic solvent at a temperature below 100° C.; (b) treating the extracted biomass with a treatment liquid comprising a second organic solvent selected from lower alcohols, ethers and ketones, optionally water and optionally an acid, at a temperature between 120° C. and 280° C., and, optionally: (c) subjecting a cellulose-enriched product stream resulting from step (b) to enzymatic hydrolysis. The first and second organic solvent may be different or the same; in particular they comprise ethanol or acetone.
    Type: Grant
    Filed: February 17, 2014
    Date of Patent: November 8, 2022
    Assignee: NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO
    Inventors: Adrianus Theodorus Smit, Wouter Johannes Joseph Huijgen, Rudie Johan Hendrik Grisel
  • Patent number: 11230611
    Abstract: The present invention concerns an improved process for biorefinery of brown macroalgae, which comprises: (a) contacting the brown macroalgae with a solvent system comprising at least 30 wt % organic solvent, to obtain extracted macroalgae as solid residue and a liquor; and (b) biorefining the extracted macroalgae. The inventors have found that the contacting of step (a) results in an efficient and cost-effective dewatering of the macroalgae, wherein up to 95 wt % of the internal moisture of the macroalgae could be lost without the need for energy-consuming drying techniques. As such, the downstream biorefinery of the extracted macroalgae is greatly facilitated.
    Type: Grant
    Filed: November 21, 2018
    Date of Patent: January 25, 2022
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventors: Adrianus Theodorus Smit, Wouter Johannes Joseph Huijgen
  • Publication number: 20200291138
    Abstract: The present invention concerns an improved process for biorefinery of brown macroalgae, which comprises: (a) contacting the brown macroalgae with a solvent system comprising at least 30 wt % organic solvent, to obtain extracted macroalgae as solid residue and a liquor; and (b) biorefining the extracted macroalgae. The inventors have found that the contacting of step (a) results in an efficient and cost-effective dewatering of the macroalgae, wherein up to 95 wt % of the internal moisture of the macroalgae could be lost without the need for energy-consuming drying techniques. As such, the downstream biorefinery of the extracted macroalgae is greatly facilitated.
    Type: Application
    Filed: November 21, 2018
    Publication date: September 17, 2020
    Applicant: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventors: Adrianus Theodorus Smit, Wouter Johannes Joseph Huijgen
  • Patent number: 10072099
    Abstract: The present invention is directed at a process for fractionating lignocellulosic biomass for the purpose of reducing processing costs, increasing delignification, reducing side-reactions, in particular reducing hemicelluloses degradation, improving cellulose hydrolysis and increasing the nativity of the obtained lignin, by performing organosolv fractionation of the biomass with a treatment liquid at a temperature below 170° C., wherein the treatment liquid comprises a non-hydroxylic organic solvent, in particular a ketone, water and some acid, and optionally subjecting the cellulose-enriched product stream to enzymatic hydrolysis.
    Type: Grant
    Filed: July 15, 2014
    Date of Patent: September 11, 2018
    Assignee: Stichting Energieonderzoek Centrum Nederland
    Inventors: Adrianus Theodorus Smit, Wouter Johannes Joseph Huijgen, Rudie Johan Hendrik Grisel
  • Publication number: 20160152736
    Abstract: The present invention is directed at a process for fractionating lignocellulosic biomass for the purpose of reducing processing costs, increasing delignification, reducing side-reactions, in particular reducing hemicelluloses degradation, improving cellulose hydrolysis and increasing the nativity of the obtained lignin, by performing organosolv fractionation of the biomass with a treatment liquid at a temperature below 170° C., wherein the treatment liquid comprises a non-hydroxylic organic solvent, in particular a ketone, water and some acid, and optionally subjecting the cellulose-enriched product stream to enzymatic hydrolysis.
    Type: Application
    Filed: July 15, 2014
    Publication date: June 2, 2016
    Applicant: Stichting Energieonderzoek Centrum Nederland
    Inventors: Adrianus Theodorus SMIT, Wouter Johannes Joseph HUIJGEN, Rudie Johan Hendrik GRISEL
  • Publication number: 20160024712
    Abstract: Lignocellulosic biomass can be fractionated for the purpose of increasing cellulose purity in the pulp, increasing native lignin content of the isolated lignin, and improving cellulose hydrolysis, by performing the steps of: (a) extracting the biomass with an extracting liquid comprising at least 20 wt % of a first organic solvent at a temperature below 100° C.; (b) treating the extracted biomass with a treatment liquid comprising a second organic solvent selected from lower alcohols, ethers and ketones, optionally water and optionally an acid, at a temperature between 120° C. and 280° C., and, optionally: (c) subjecting a cellulose-enriched product stream resulting from step (b) to enzymatic hydrolysis. The first and second organic solvent may be different or the same; in particular they comprise ethanol or acetone.
    Type: Application
    Filed: February 17, 2014
    Publication date: January 28, 2016
    Applicant: Stichting Energieonderzoek Centrum Nederland
    Inventors: Adrianus Theodorus SMIT, Wouter Johannes Joseph HUIJGEN, Rudie Johan Hendrik GRISEL
  • Publication number: 20150329889
    Abstract: Cellulose from lignocellulosic biomass which also contains protein, such as grasses and straws, can be enzymatically converted to valuable products such as glucose at lower enzyme consumption by: (a) extracting the biomass with water at 15-75° C. to produce an extracted biomass and a protein-containing aqueous extract; (b) mechanically, chemically and/or thermally pretreating cellulose-containing-biomass, in particular by organosolv treatment; and (c) contacting biomass pretreated in step (b) with: (i) an enzyme capable of hydrolysing cellulose; and (ii) the protein-containing aqueous extract obtained in step (a).
    Type: Application
    Filed: December 18, 2013
    Publication date: November 19, 2015
    Applicant: STICHTING ENERGIEONDERZOEK CENTRUM NEDERLAND
    Inventors: Adrianus Theodorus SMIT, Wouter Johannes Joseph HUIJGEN