Abstract: There is provided a thermoelectric material including a compound which is formed of an element R belonging to alkaline earth metal and lanthanoid, and an element X belonging to any of Group 13 elements, Group 14 elements, and Group 15 elements. The composition ratio of the element R and the element X is selected to obtain the compound having an AlB2 type structure.

Abstract: Provided are a p-type thermoelectric conversion material, a thermoelectric conversion module, and a method of manufacturing a p-type thermoelectric conversion material that are capable of obtaining high thermoelectric conversion characteristics. The p-type thermoelectric conversion material has a full Heusler alloy having a composition represented by the following General Formula (1) and has a relative density of 85% or more, FexTiyMAaMBb . . . (1), wherein in Formula (1), MA is one element selected from the group consisting of Si, Sn, and Ge, MB is one element selected from the group consisting of Al, Ga, and In, and x, y, a, and b are numbers set so that x+y+a+b=100, a+b=z, 50<x?52.5, 20?y?24.5, 24.5?z?29, a>0, and b>0 in atom %, respectively.

Abstract: There is provided a thermoelectric conversion material formed of an Fe2TiSi-based full-Heusler alloy to which La is added, wherein La is solid-dissolved in the Fe2TiSi-based full-Heusler alloy.

Abstract: In order to provide an Fe2TiSi type full-Heusler thermoelectric conversion material having a high dimensionless figure-of-merit ZT, the full-Heusler thermoelectric conversion material is characterized in that: the full-Heusler thermoelectric conversion material has secondary crystal grains having an Fe2TiSi type composition and a coating layer covering the circumference of the secondary crystal grains and containing an element other than Fe, Ti, and Si as a main component; and the coating layer has a composition containing an element being dissolvable in a crystal structure of the Fe2TiSi type composition and having an electric resistivity lower than the secondary crystal grains.

Abstract: There is provided a thermoelectric conversion material formed of an Fe2TiSi-based full-Heusler alloy to which La is added, wherein La is solid-dissolved in the Fe2TiSi-based full-Heusler alloy.

Abstract: According to one embodiment, a thermoelectric conversion material includes a main phase and a grain boundary phase, the main phase is a Fe2TiSi-based full Heusler alloy, the grain boundary phase includes a metal N slightly solid-soluble in Fe2TiSi, and a volume ratio of the grain boundary phase is 2% to 10%.

Abstract: Provided is a thermoelectric conversion material formed from a full Heusler alloy represented by the composition formula: Fe2+?(Ti1??M1?)1??+?(Al1??M2?)1??. M1 represents at least one element selected from the group consisting of V, Nb and Ta, and M2 represents at least one element selected from the group consisting of Group 13 elements except for Al and Group 14 elements. ? satisfies the relation: 0<??0.42, ? satisfies the relation: 0??<0.75, and ? satisfies the relation: 0??<0.5. The valence electron concentration, VEC, satisfies the relation: 5.91?VEC<6.16.

Abstract: Provided are a p-type thermoelectric conversion material, a thermoelectric conversion module, and a method of manufacturing a p-type thermoelectric conversion material that are capable of obtaining high thermoelectric conversion characteristics. The p-type thermoelectric conversion material has a full Heusler alloy having a composition represented by the following General Formula (1) and has a relative density of 85% or more, FexTiyMAaMBb . . . (1), wherein in Formula (1), MA is one element selected from the group consisting of Si, Sn, and Ge, MB is one element selected from the group consisting of Al, Ga, and In, and x, y, a, and b are numbers set so that x+y+a+b=100, a+b=z, 50<x?52.5, 20?y?24.5, 24.5?z?29, a>0, and b>0 in atom %, respectively.

Abstract: The present invention aims at providing a thermoelectric conversion module with low toxicity, which exhibits conversion efficiency equivalent to that of BiTe. The thermoelectric conversion module of the present invention employs a full Heusler alloy as the material for forming the P-type thermoelectric conversion unit and the N-type thermoelectric conversion unit. The material for forming the N-type thermoelectric conversion unit contains at least any one of Fe, Ti, and Si and Sn.

Abstract: The present invention provides a metal-based thermoelectric conversion material having a high figure-of-merit ZT, the thermoelectric conversion material being a p-type or n-type full-Heusler alloy, having a composition of an Fe2TiA type (wherein A is Si and/or Sn), and including crystal grains having an average grain diameter of 30-500 nm. In particular, in the case where the composition of an Fe2TiA type is represented by the empirical formula Fe2+?Ti1+yA1+z, the values of ?, y, and z in an Fe—Ti-A ternary alloy phase diagram lie within the range ? surrounded by the points (50, 37, 13), (45, 30, 25), (39.5, 25, 35.5), (50, 14, 36), (54, 21, 25), and (55.5, 25, 19.5) in terms of (Fe, Ti, A) in at %.

Abstract: A thermoelectric material includes the crystal grains of a primary phase silicide and a secondary phase silicide. The average grain sizes of the primary phase silicide and the secondary phase silicide are larger than 0 nm and equal or smaller than 100 nm. The primary phase silicide includes: one kind of elements selected from Mn elements, Fe elements, and Cr elements; and Si elements, or one kind of elements selected from Mn elements, Fe elements and Cr elements; Si elements; and one or more kinds of elements selected from Al elements, Ga elements, and In elements. The secondary phase silicide includes: one kind of elements selected from Mn elements, Fe elements, and Cr elements; Si elements; and one or more kinds of metal elements selected from Al elements, Ga elements, and In elements. The crystal grains of the primary phase silicide and the secondary phase silicide are respectively oriented.

Abstract: There is provided a thermoelectric material including a compound which is formed of an element R belonging to alkaline earth metal and lanthanoid, and an element X belonging to any of Group 13 elements, Group 14 elements, and Group 15 elements. The composition ratio of the element R and the element X is selected to obtain the compound having an AlB2 type structure.

Abstract: In order to provide an Fe2TiSi type full-Heusler thermoelectric conversion material having a high dimensionless figure-of-merit ZT, the full-Heusler thermoelectric conversion material is characterized in that: the full-Heusler thermoelectric conversion material has secondary crystal grains having an Fe2TiSi type composition and a coating layer covering the circumference of the secondary crystal grains and containing an element other than Fe, Ti, and Si as a main component; and the coating layer has a composition containing an element being dissolvable in a crystal structure of the Fe2TiSi type composition and having an electric resistivity lower than the secondary crystal grains.

Abstract: There is provided a thermoelectric conversion material made of a full-Heusler alloy and capable of enhancing figure of merit. In order to solve the above problem, the thermoelectric conversion material is made of the full-Heusler alloy represented by the following composition formula: (Fe1-xM1x)2+?(Ti1-yM2y)1+?(A1-zM3z)1+?. A composition in a ternary phase diagram of Fe—Ti-A is inside a hexagon having points (50, 37, 13), (45, 30, 25), (39.5, 25, 35.5), (50, 14, 36), (54, 21, 25), and (55.5, 25, 19.5) as apexes. Further, an amount of change ?VEC of an average valence electron number per atom VEC in the case of x=y=z=0 satisfies a relation 0<|?VEC|?0.2 or 0.2<|?VEC|?0.3.

Abstract: In order to provide a thermoelectric conversion element which has a high Seebeck coefficient, a low thermal conductivity, and a high performance, even if the material system that has a low environmental load and can reduce the cost is used, the thermoelectric conversion element in which lattice points are classified into two or more kinds (A site and B site), lattices of which the kinds are different are connected to each other, the numbers of lattices of which the kinds are different are different (A site: 2, and B site: 1), and a lattice structure is configured by arranging nanoparticles or semiconductor quantum dots, includes areas of which conductivity types are different.

Abstract: The present invention provides a metal-based thermoelectric conversion material having a high figure-of-merit ZT, the thermoelectric conversion material being a p-type or n-type full-Heusler alloy, having a composition of an Fe2TiA type (wherein A is Si and/or Sn), and including crystal grains having an average grain diameter of 30-500 nm. In particular, in the case where the composition of an Fe2TiA type is represented by the empirical formula Fe2+?Ti1+yA1+z, the values of ?, y, and z in an Fe—Ti-A ternary alloy phase diagram lie within the range ? surrounded by the points (50, 37, 13), (45, 30, 25), (39.5, 25, 35.5), (50, 14, 36), (54, 21, 25), and (55.5, 25, 19.5) in terms of (Fe, Ti, A) in at %.

Abstract: Provided is a thermoelectric conversion material formed from a full Heusler alloy represented by the composition formula: Fe2+?(Ti1??M1?)1??+?(Al1??M2?)1??. M1 represents at least one element selected from the group consisting of V, Nb and Ta, and M2 represents at least one element selected from the group consisting of Group 13 elements except for Al and Group 14 elements, ? satisfies the relation: 0<??0.42, ? satisfies the relation: 0??<0.75, and ? satisfies the relation: 0??< 0.5. The valence electron concentration, VEC, satisfies the relation: 5.91?VEC<6.16.

Abstract: To provide a stress relaxation structure that can achieve both high thermal conductivity and high thermal stress relaxation ability and has excellent vibration durability, and a thermoelectric conversion module having such a stress relaxation structure. The stress relaxation structure includes a rolled-up body having a first thermal conductor and a second thermal conductor that are alternately rolled up. The first thermal conductor is metal foil, and the second thermal conductor is porous metal foil.

Abstract: A thermoelectric conversion device includes a Heusler alloy film having a structure of B2 or L21 in notation of A2BC and a pair of electrodes on the Heusler alloy film to output an electromotive force generated by a thermal gradient in the Heusler alloy film. The thermoelectric conversion device further includes an electrode for applying an electric field or a voltage to the Heusler alloy film to increase and control an electric conductivity and a Seebeck coefficient S of the Heusler metal film. The device can control to increase an electric conductivity and Seebeck coefficient S by applying an electric field or a voltage through an insulation film to the Heusler alloy film. The device may have a shared connection to select one of outputs of a plurality of thermoelectric conversion devices arranged in a matrix or increase an electromotive force as an output.

Abstract: In order to provide a thermoelectric conversion unit capable of generating power with high thermoelectric conversion efficiency, in the thermoelectric conversion unit including: a plurality of thermoelectric conversion modules (1 to 3) including a plurality of pairs of n-type thermoelectric conversion material portions and p-type thermoelectric conversion material portions connected by electrodes; and a hot water pipe 201 and a cold water pipe 202 for generating a temperature difference in the thermoelectric conversion modules and generating power by using a Seebeck effect, at least one of the plurality of thermoelectric conversion modules is different from another thermoelectric conversion module in at least one of a thickness of the thermoelectric conversion material portions, the kind of thermoelectric conversion material, and a thickness of the electrodes.