Abstract: The attachment and proliferation of antibiotic resistant, biofilm-forming bacteria to oft-handled material surfaces has emerged as a growing concern, particularly in the biomedical, healthcare and food packaging industries. UV-curable phosphoniums bearing benzophenone anchors have been synthesized with a variety of alkyl, aryl, and fluoroalkyl functional groups at phosphorus to probe their efficacy as thermally stable antimicrobial additives in plastics or as surface coatings. In an embodiment, a phosphonium compound having the following formula has been synthesized: in which R is a phosphine group substituted with alkyl, aryl, substituted alkyl, substituted aryl, heteroalkyl or any combination thereof. These materials maintained the ability to kill biofilm-forming bacteria even after being subject to abrasion processes, demonstrating the potential to serve as long-term antimicrobial materials.

Abstract: In the context of additive manufacturing processes wherein objects are built by layered accumulations of discrete instantaneous deposits of feedstock material at specific locations according to a three-dimensional digital data model, methods and systems are provided for selecting an advantageous alignment between an array of fillable voxel spaces and a model layer slice. In accordance with some embodiments, variable alignment achieves an overall reduction in the amount of excess material formed by discrete depositions of material and extending beyond the contours of the object.

Abstract: In the context of additive manufacturing processes wherein objects are built by layered accumulations of discrete instantaneous deposits of feedstock material at specific locations according to a three-dimensional digital data model, methods are provided for improving at least one build quality attribute by adjusting a size of one or more voxel spaces for receiving discrete deposits. According to various embodiments, the quality attribute pertains to reducing excess material used in the build process or to thermal behavior of deposited materials. According to various embodiments, the size of a voxel space may be adjusting by scaling and by subdividing into a cluster of smaller spaces that warrant smaller deposits.

Abstract: Systems and processes for additive manufacturing are set forth for constructing an object by making successive discrete deposits of unitary masses of a feedstock materials at specific locations as determined by a digital data model for the object. In accordance with some embodiments, the deposits are non-continuous and performed in a sequence such that consecutively ordered deposit actions occur at deposit locations that are not physically adjacent, enabling control of thermal behaviors as a build progresses. In accordance with some embodiments, the sequencing of discrete depositing actions may be agilely rearranged to change temperatures and temperature gradients exhibited by deposited materials.

Abstract: In the context of additive manufacturing processes wherein objects are built by layered accumulations of discrete instantaneous deposits of feedstock material at specific locations according to a first three-dimensional digital data model, processes and systems are provided for first forming an oversized blank part that roughly conforms to the first model and is subsequently machined to final dimensions specified by the first model. Various embodiments provide for generating a second model representing the expected shape of the blank part, as formed by a discrete deposition process, and facilitating calculation of specific toolpaths by which material removal tools may render the final shape.

Abstract: In the context of additive manufacturing processes wherein an object is built by layered accumulations of discrete instantaneous deposits of feedstock material at specific locations according to a three-dimensional digital data model, systems and methods are taught for operating multiple independently-moving depositing devices in a shared build space to build the object. In some embodiments, depositing components perform discrete material depositing actions according to sequential lists of deposit location instructions which are dynamically sortable, enabling a control methodology to alleviate collision risks among depositing components and to improve thermal conditions of a workpiece during construction. Further embodiments provide for dynamic apportionment of discrete deposition actions among the available depositing devices for load balancing and fault tolerance.

Abstract: A member (10) for providing sealing, baffling, and/or reinforcement to a cavity member (30) comprising: (a) a carrier (12) with an insertion end (13) and a base end (11) having: (i) a base (16) at the base end (11) adapted for engaging with a wall (36) of the cavity member (30); (ii) a fastener (20) adapted for passing through an opening of the cavity member (32) and retaining the member (10) to the cavity member (30); (iii) a center portion (18) extending from the insertion end (13) to the base end (11); and (b) activatable material (26) disposed on the carrier (12).

Abstract: A method of manufacturing using an additive manufacturing process includes providing a deposition system, the deposition system configured to provide a plurality of cells to form a blank of a part, depositing a first layer of the blank, the first layer comprising a first deposited cell, a second deposited cell spaced apart from the first deposited cell, and a third deposited cell spaced apart from the first deposited cell and the second deposited cell, and depositing a second layer of the part on the first layer, the second layer comprising a fourth deposited cell, a fifth deposited cell spaced apart from the fourth deposited cell, and a sixth deposited cell spaced apart from the fourth deposited cell and the fifth deposited cell. Each of the first layer and the second layer are formed using non-continuous deposition to form the blank.

Abstract: The attachment and proliferation of antibiotic resistant, biofilm-forming bacteria to oft-handled material surfaces has emerged as a growing concern, particularly in the biomedical, healthcare and food packaging industries. UV-curable phosphoniums bearing benzophenone anchors have been synthesized with a variety of alkyl, aryl, and fluoroalkyl functional groups at phosphorus to probe their efficacy as thermally stable antimicrobial additives in plastics or as surface coatings. In an embodiment, a phosphonium compound having the following formula has been synthesized: in which R is a phosphine group substituted with alkyl, aryl, substituted alkyl, substituted aryl, heteroalkyl or any combination thereof. These materials maintained the ability to kill biofilm-forming bacteria even after being subject to abrasion processes, demonstrating the potential to serve as long-term antimicrobial materials.

Abstract: The present invention is concerned with self-immolative recognition and/or responsive systems for electrophilic compounds, especially alkylating agents, which systems may comprise disclosure or detection of the alkylating agent. The present invention is especially concerned with non-protic triggered self-immolative systems, molecules, and methods, and in particular for detection of non-protic electrophilic agents, and especially alkylating agents, for example alkyl or benzylic halides, which may be found in pesticides or fumigants, or chemical warfare agents.

Abstract: A quaternary ammonium sulfonamide compound of formula (I): wherein R=(II), C1-C3 linear or branched alkyl, R1 and R2 are the same or different and selected from C1 to C18 linear or branched alkyl, R3 and R4 are the same or different and selected from C1 to C4 linear or branched alkyl, CF3, OR5 where R5 is C1 to C8 linear or branched alkyl or polyethylene oxide, l is 1, 2, 3, 4, 5, 6, 7 or 8, m is 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16 or 17, n is 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17 or 18, wherein the aryl groups of R may be substituted or unsubstituted, X=halogen, and Y=(III) wherein R6, R7, R8, R9 and R10 are the same or different and selected from C1 to C6 linear or branched alkyl and the benzophenone is selected from the group consisting of substituted benzophenone and unsubstituted benzophenone, process for preparing the compound and antimicrobial surface coating compositions of the compound.

Abstract: A method of manufacturing using an additive manufacturing process includes providing a deposition system, the deposition system configured to provide a plurality of cells to form a blank of a part, depositing a first layer of the blank, the first layer comprising a first deposited cell, a second deposited cell spaced apart from the first deposited cell, and a third deposited cell spaced apart from the first deposited cell and the second deposited cell, and depositing a second layer of the part on the first layer, the second layer comprising a fourth deposited cell, a fifth deposited cell spaced apart from the fourth deposited cell, and a sixth deposited cell spaced apart from the fourth deposited cell and the fifth deposited cell. Each of the first layer and the second layer are formed using non-continuous deposition to form the blank.

Abstract: A method comprising: (i) forming a reinforcement device by the following steps: forming a first member (1) and a second member (2), applying an adhesive (3) to the first member (1) and the second member (2), attaching at least one connecting feature to the first member (1), the second member (2), or both, bringing the first member (1) and the second member (2) together to form a clam-like structure, locking the first member (1) and the second member (2) with the at least one connecting feature, forming a first encasing member and a second encasing member, attaching the first encasing member to the second encasing member to form an encasing around the clam-like structure, (ii) exposing the reinforcement device to electrocoating, wherein the adhesive expands during the electro coating and bonds the first member (1) to the second member (2) and bonds the clam-like structure to the encasing.

Abstract: A polymeric insert formed by extruding a material including polyamide and a plurality of long fibers to form a column structure having a first profile. A method for making such an insert comprising passing a polymeric material in a substantially flowable state through a die, and substantially simultaneously passing a fiber through the die, wherein during the passing step the polymeric material has a relative viscosity of less than about 60 according to ASTM D789.

Abstract: A member (10) for providing sealing, baffling, and/or reinforcement to a cavity member (30) comprising: (a) a carrier (12) with an insertion end (13) and a base end (11) having: (i) a base (16) at the base end (11) adapted for engaging with a wall (36) of the cavity member (30); (ii) a fastener (20) adapted for passing through an opening of the cavity member (32) and retaining the member (10) to the cavity member (30); (iii) a center portion (18) extending from the insertion end (13) to the base end (11); and (b) activatable material (26) disposed on the carrier (12).

Abstract: A quaternary ammonium sulfonamide compound of formula (I): wherein R=(II), C1-C3 linear or branched alkyl, R1 and R2 are the same or different and selected from C1 to C18 linear or branched alkyl, R3 and R4 are the same or different and selected from C1 to C4 linear or branched alkyl, CF3, OR5 where R5 is C1 to C8 linear or branched alkyl or polyethylene oxide, l is 1, 2, 3, 4, 5, 6, 7 or 8, m is 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16 or 17, n is 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17 or 18, wherein the aryl groups of R may be substituted or unsubstituted, X=halogen, and Y=(III) wherein R6, R7, R8, R9 and R10 are the same or different and selected from C1 to C6 linear or branched alkyl and the benzophenone is selected from the group consisting of substituted benzophenone and unsubstituted benzophenone, process for preparing the compound and antimicrobial surface coating compositions of the compound.

Abstract: A method of servicing, or repairing a crack in, a dovetail portion of a dynamoelectric machine's rotor coil slot wall. The coil slot wall includes a radial entry surface connected to an inwardly tapered surface. The inwardly tapered surface is connected to an intermediate radial surface. A machining step machines a first groove in the radial entry surface and inwardly tapered surface. The first groove extends linearly to the intermediate radial surface. The first groove is configured so that a smooth and linear surface is created along a length of the first groove. A second machining step machines a second groove in the intermediate radial surface in an orientation substantially perpendicular to the first groove. A portion of the second groove contacts a portion of the first groove. At least one of the first groove and the second groove are configured to remove damaged material from the coil slot wall.

Abstract: A method for filtering internet traffic between one or more users and the internet is described herein, the method iterated in a computer system having a processor and an operating system software implemented by the processor and representative of executable code. In the method, website requests are received from one or more client devices of the one or more users, and the requests are compared against one of an internal whitelist of websites built and maintained by one or more external servers on behalf of a consumer organization, and a master whitelist approved and managed by the organization. If the website is on the whitelist, the one or more external servers grant access to the internet traffic so that the client device receives the website URL and content thereof, otherwise access to the requested website is blocked.

Abstract: A method comprising: (i) forming a reinforcement device by the following steps: forming a first member (1) and a second member (2), applying an adhesive (3) to the first member (1) and the second member (2), attaching at least one connecting feature to the first member (1), the second member (2), or both, bringing the first member (1) and the second member (2) together to form a clam-like structure, locking the first member (1) and the second member (2) with the at least one connecting feature, forming a first encasing member and a second encasing member, attaching the first encasing member to the second encasing member to form an encasing around the clam-like structure, (ii) exposing the reinforcement device to electrocoating, wherein the adhesive expands during the electro coating and bonds the first member (1) to the second member (2) and bonds the clam-like structure to the encasing.

Abstract: A polymeric insert formed by extruding a material including polyamide and a plurality of long fibers to form a column structure having a first profile. A method for making such an insert comprising passing a polymeric material in a substantially flowable state through a die, and substantially simultaneously passing a fiber through the die, wherein during the passing step the polymeric material has a relative viscosity of less than about 60 according to ASTM D789.