Abstract: Provided are water-resistant and/or photoprotective compositions including: (a) an aqueous phase including from 0% to 99.9% by weight of the composition, based on the total weight of the composition; (b) an oil phase including from 0% to 99.9% by weight of the composition, based on the total weight of the composition; (c) an active sun block agent; and (d) a micronized, non-solubilized wax including 0.1% to 10% by weight of the composition, based on the total weight of the composition; wherein the wax has a D50 particle size of 1 to 100 ?m, and a melting point of at least 70° C.; and wherein the composition includes at least 50% by weight of at least one of the aqueous phase or the oil phase. Uses of the compositions, and methods utilizing the compositions, are also provided.

Abstract: Provided are antifog hydrophilic polyurethane compositions including: (a) from 20% to 70% by weight side-chain ethylene oxide monomeric units, based on the total weight of the polyurethane; (b) from 10% to 100% by weight of at least one main-chain polyol having a number-average molecular weight of from 200 to 900 g/mol, based on the total weight of main-chain polyols present in the polyurethane; and (c) an amount of acid-functional units effective to provide an acid number of from 1 to 100 mg KOH/g to the polyurethane. Methods of making and using such compositions are also provided.

Abstract: The present technology relates to antimicrobial cleaning compositions comprising a polyurethane having at least one acid group salted with a biguanide (e.g., bis-biguanide) free base compound. More specifically, the present technology relates to an antimicrobial cleaning composition comprising a) a polyurethane with at least one free acid group salted with a biguanide free base; b) at least one surfactant; and c) a diluent. Surfaces treated with the antimicrobial compositions of the disclosed technology are provided with residual inhibition against the proliferation of microbe growth.

Abstract: The present subject matter relates to a polyurethane composition comprising a polyurethane with at least one free acid group salted with a biguanide free base.

Abstract: The present invention provides a blend of a soft water reducible polyurethane with a high percentage of tethered ethylene oxide rich chains and a harder acrylic copolymer with specified percentages of repeat units from C1-C12 esters of acrylic and/or methacrylic acid and an acid component from combined acrylic and methacrylic acid. The blend forms the binder in a coating that exhibits the possibilities of having high gloss, transparency, and facilitating the conversion of inks applied to the coating to a smudge resistant image in a short period of time after application of the ink.

Abstract: The present invention provides a blend of a soft water reducible polyurethane with a high percentage of tethered ethylene oxide rich chains and a harder acrylic copolymer with specified percentages of repeat units from C1-C12 esters of acrylic and/or methacrylic acid and an acid component from combined acrylic and methacrylic acid. The blend forms the binder in a coating that exhibits the possibilities of having high gloss, transparency, and facilitating the conversion of inks applied to the coating to a smudge resistant image in a short period of time after application of the ink.

Abstract: An aqueous cationic polyurethane dispersion for waterborne digital print and other applications comprising an aqueous dispersion of polyurethane having properly positioned tertiary amino groups, e.g., tethered tertiary amino group separated from backbone by at least two intervening atoms or terminal tertiary amino groups with multiple tertiary amino groups per terminus, where said amino groups are optionally partially quaternized and/or neutralized.

Abstract: An aqueous cationic polyurethane dispersion for waterborne digital print and other applications comprising an aqueous dispersion of polyurethane having properly positioned tertiary amino groups, e.g., tethered tertiary amino group separated from backbone by at least two intervening atoms or terminal tertiary amino groups with multiple tertiary amino groups per terminus, where said amino groups are optionally partially quaternized and/or neutralized.

Abstract: An aqueous cationic polyurethane dispersion for waterborne digital print and other applications comprising an aqueous dispersion of polyurethane having properly positioned tertiary amino groups, e.g., tethered tertiary amino group separated from backbone by at least two intervening atoms or terminal tertiary amino groups with multiple tertiary amino groups per terminus, where said amino groups are optionally partially quaternized and/or neutralized.

Abstract: The flame-retarding properties of polymeric compositions are selectively enhanced, without adversely affecting other properties of these materials to any significant degree, by including in the compositions oligomeric urethanes with high bromine content.

Abstract: An aqueous cationic polyurethane dispersion, coagulating acids, and a reactive crosslinking moiety are disclosed for use as pretreatment for digital printing on substrates such as textiles and garments. The pretreatment comprises a polyurethane having properly positioned tertiary amino groups, generally protonated or quaternized, in combination with a reactive crosslinker, coagulating acid, and some di- or polyvalent metal ions.

Abstract: Vinyl polymers formed by bulk or solution polymerization techniques are combined with nanoparticles to produce aqueous dispersions of nanoparticle/vinyl polymer composites.

Abstract: An aqueous cationic polyurethane dispersion for waterborne digital print and other applications comprising an aqueous dispersion of polyurethane having properly positioned tertiary amino groups, e.g., tethered tertiary amino group separated from backbone by at least two intervening atoms or terminal tertiary amino groups with multiple tertiary amino groups per terminus, where said amino groups are optionally partially quaternized and/or neutralized.

Abstract: The flame-retarding properties of polymeric compositions are selectively enhanced, without adversely affecting other properties of these materials to any significant degree, by including in the compositions oligomeric urethanes with high bromine content.

Abstract: The water-resistance properties of polyester-based polyurethanes are remarkably enhanced, without adversely affecting the transparency properties of these materials to any significant degree, by including in the polymer a substantially dispersed nano-particle proton scavenger. The hydrolytic stability and water-resistance properties of polyester-based polyurethanes are remarkably enhanced and match those of polycarbonate-based polyurethanes, without adversely affecting the transparency of these materials to any significant degree, by including in the polymer a substantially dispersed nano-particle proton scavenger such as calcium carbonate.

Abstract: A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers, and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.

Abstract: A water activated adhesive system is described that is particularly suited for applying non-paper polymeric labels to surfaces which have low moisture permeability. The adhesive system is characterized by a dry non-tacky surface that becomes tacky in less than one second when contacted with a water-based activator. While it is a water activated adhesive, it is also characterized after aging bonded to a substrate by resistance to adhesive failure during 72 hours of immersion in ice/water mixture. The adhesive is beneficial to allow use of existing paper labeling equipment with polymeric labels.

Abstract: The water-resistance properties of polyester-based polyurethanes are remarkably enhanced, without adversely affecting the transparency properties of these materials to any significant degree, by including in the polymer a substantially dispersed nano-particle proton scavenger. The hydrolytic stability and water-resistance properties of polyester-based polyurethanes are remarkably enhanced and match those of polycarbonate-based polyurethanes, without adversely affecting the transparency of these materials to any significant degree, by including in the polymer a substantially dispersed nano-particle proton scavenger such as calcium carbonate.

Abstract: Vinyl chloride polymer compositions, optionally plasticized, containing a hydrophilic polymer (e.g., a hydrophilic polyurethane or hydrophilic vinyl polymer) are described for use as coatings and films with increased moisture vapor transmission and/or static dissipative properties. Films from this material are useful as fluid barriers that allow diffusion of moisture vapors. Similar modifications can be made to acrylate and urethane polymers.

Abstract: A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers, and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.