Abstract: An article of manufacture and method of forming a borided material. An electrochemical cell is used to process a substrate to deposit a plurality of borided layers on the substrate. The plurality of layers are co-deposited such that a refractory metal boride layer is disposed on a substrate and a rare earth metal boride conforming layer is disposed on the refractory metal boride layer.

Abstract: A system and method for forming at least one of graphene and graphene oxide on a substrate and an opposed wear member. The system includes graphene and graphene oxide formed by an exfoliation process or solution processing method to dispose graphene and/or graphene oxide onto a substrate. The system further includes an opposing wear member disposed on another substrate and a gas atmosphere of an inert gas like N2, ambient, a humid atmosphere and a water solution.

Abstract: Nickel-containing carbon nanofiber (NiCNF) materials and lubricants comprising the nanofiber materials are described herein. The NiCNF materials comprise a plurality of elongate nickel-containing carbon nanofibers. Each NiCNF comprises a carbon nanofiber shaft that is capped at one end by a nickel nanoparticle encapsulated in multiple layers of graphitic carbon. The nanofibers typically have a generally circular cross-section (i.e., in the direction perpendicular to the length-axis of the fibers). The NiCNF materials as useful, e.g., in lubricant compositions, which also are described herein.

Abstract: A method of ultra-fast boriding of a metal surface. The method includes the step of providing a metal component, providing a molten electrolyte having boron components therein, providing an electrochemical boriding system including an induction furnace, operating the induction furnace to establish a high temperature for the molten electrolyte, and boriding the metal surface to achieve a boride layer on the metal surface.

Abstract: A hard, wear resistant coating and a method of forming the coating on a substrate to be exposed to hydrocarbons is provided. A substrate is provided in a chamber. A film is deposited onto the substrate by physical vapor deposition (PVD), where the film includes a bulk layer and an outer termination layer. The deposition of the termination layer is mitigated. The termination layer is removed from the film, leaving the remaining bulk layer disposed over the substrate. And when the substrate is exposed to hydrocarbons in an environment having wear additives, friction modifiers, or naturally occurring compounds, a durable tribological layer is formed on an outer surface of the bulk layer to create a coating having low friction and anti-wear properties.

Abstract: This invention relates to carbon-based materials as anti-friction and anti-wear additives for advanced lubrication purposes. The materials comprise carbon nanotubes suspended in a liquid hydrocarbon carrier. Optionally, the compositions further comprise a surfactant (e.g., to aid in dispersion of the carbon particles). Specifically, the novel lubricants have the ability to significantly lower friction and wear, which translates into improved fuel economies and longer durability of mechanical devices and engines.

Abstract: This invention relates to carbon-based materials as anti-friction and anti-wear additives for advanced lubrication purposes. The materials have various shapes, sizes, and structures and are synthesized by autogenic reactions under extreme conditions of high temperature and pressure. The lubricant compositions comprise carbon-based particles suspended in a liquid hydrocarbon carrier. Optionally, the compositions further comprise a surfactant (e.g., to aid in dispersion of the carbon particles). Specifically, the novel lubricants have the ability to significantly lower friction and wear, which translates into improved fuel economies and longer durability of mechanical devices and engines.

Abstract: A system and method for forming graphene on a substrate and an opposed wear member having a DLC coating. The system includes graphene formed by an exfoliation process to dispose solution processed graphene onto a substrate. The system further includes an opposing wear member of DLC disposed on another substrate and a gas atmosphere of an inert gas like N2.

Abstract: A nanocomposite coating and method of making and using the coating. The nanocomposite coating is disposed on a base material, such as a metal or ceramic; and the nanocomposite consists essentially of a matrix of an alloy selected from the group of Cu, Ni, Pd, Pt and Re which are catalytically active for cracking of carbon bonds in oils and greases and a grain structure selected from the group of borides, carbides and nitrides.

Abstract: This invention relates to carbon-based materials as anti-friction and anti-wear additives for advanced lubrication purposes. The materials have various shapes, sizes, and structures and are synthesized by autogenic reactions under extreme conditions of high temperature and pressure. The lubricant compositions comprise carbon-based particles suspended in a liquid hydrocarbon carrier. Optionally, the compositions further comprise a surfactant (e.g., to aid in dispersion of the carbon particles). Specifically, the novel lubricants have the ability to significantly lower friction and wear, which translates into improved fuel economies and longer durability of mechanical devices and engines.

Abstract: A high performance hard disk drive is disclosed in which a flying read/write head runs in contact or in near contact with a rotating platter. In this design there is no wear of the hard disk platter or flying head due to both head and platter being coated with an amorphous carbon that has an exceptionally low coefficient of friction in a sealed, inert gas environment. The overcoat contains carbon in the range between about 52 and 80 atomic percent and hydrogen in the range between about 20 to 48 atomic percent. There is no lubricant required in this design, which eliminates a significant cause of hard drive failure from oxidation of the lubricant, stiction and rippling of the lubricant. This contact method achieves a high areal density with no wear, within a robust, hermetically sealed environment.

Abstract: Methods and compositions relating to the preparation of structurally and compositionally modulated composite surfaces that can potentially reduce friction and increase resistance to wear and scuffing in rolling, rotating and sliding bearing applications. Preparation of nano-to-micro size pores, holes, or dimples on a given solid surface and filling them with soft or hard coatings at desired thickness to achieve such properties.

Abstract: Improved boron-based metal working and machining fluids. Boric acid and boron-based additives that, when mixed with certain carrier fluids, such as water, cellulose and/or cellulose derivatives, polyhydric alcohol, polyalkylene glycol, polyvinyl alcohol, starch, dextrin, in solid and/or solvated forms result in improved metalworking and machining of metallic work pieces. Fluids manufactured with boric acid or boron-based additives effectively reduce friction, prevent galling and severe wear problems on cutting and forming tools.

Abstract: A method of plasma modification of a film includes applying about ?400 V to about ?600 V to a gas in a chamber to generate a gas-discharge plasma; and subjecting the film to the gas-discharge plasma to form a plasma-modified film, where the gas comprises H2, H2S, NH3, deuterium, methane, or a mixture of any two or more. Films may be prepared. Devices coated with the films may be prepared.

Abstract: A method of ultra-fast boriding of a metal surface. The method includes the step of providing a metal component, providing a molten electrolyte having boron components therein, providing an electrochemical boriding system including an induction furnace, operating the induction furnace to establish a high temperature for the molten electrolyte, and boriding the metal surface to achieve a boride layer on the metal surface.

Abstract: A method for providing lubricity in fuels and lubricants includes adding a boron compound to a fuel or lubricant to provide a boron-containing fuel or lubricant. The fuel or lubricant may contain a boron compound at a concentration between about 30 ppm and about 3,000 ppm and a sulfur concentration of less than about 500 ppm. A method of powering an engine to minimize wear, by burning a fuel containing boron compounds. The boron compounds include compound that provide boric acid and/or BO3 ions or monomers to the fuel or lubricant.

Abstract: A high performance hard disk drive is disclosed in which a flying read/write head runs in contact or in near contact with a rotating platter. In this design there is no wear of the hard disk platter or flying head due to both head and platter being coated with an amorphous carbon that has an exceptionally low coefficient of friction in a sealed, inert gas environment. The overcoat contains carbon in the range between about 52 and 80 atomic percent and hydrogen in the range between about 20 to 48 atomic percent. There is no lubricant required in this design, which eliminates a significant cause of hard drive failure from oxidation of the lubricant, stiction and rippling of the lubricant. This contact method achieves a high areal density with no wear, within a robust, hermetically sealed environment.

Abstract: A durable, reliable high performance drive and method for digitizing, storing and retrieving data from a disk. In a first embodiment, at least one disk and components for spinning the disk, and digitizing, writing and reading data from the disk are covered with a 0.1 to 4 microns thick ultra low friction and wear, structurally amorphous carbon coating eliminating the need for a lubricant for sliding and rotating components. In a second embodiment the components for spinning the disk, and digitizing, writing and reading data from the disk are enclosed in a hermetically sealed housing and the housing is filled with a mixture of hydrogen and an inert gas.

Abstract: Methods and compositions relating to the preparation of structurally and compositionally modulated composite surfaces that can potentially reduce friction and increase resistance to wear and scuffing in rolling, rotating and sliding bearing applications. Preparation of nano-to-micro size pores, holes, or dimples on a given solid surface and filling them with soft or hard coatings at desired thickness to achieve such properties.

Abstract: An improved coating material possessing super-hard and low friction properties and a method for forming the same. The improved coating material includes the use of a noble metal or soft metal homogeneously distributed within a hard nitride material. The addition of small amounts of such metals into nitrides such as molybdenum nitride, titanium nitride, and chromium nitride results in as much as increasing of the hardness of the material as well as decreasing the friction coefficient and increasing the oxidation resistance.