Abstract: This invention describes methods of compacting and densifying high purity silicon powder to defined geometric forms and shapes. High purity silicon powder is first mixed with binder from a select group of binders and pressed into desired shapes in a mechanical equipment. The binder is removed either in a separate step or combined with a subsequent sintering operation. The binders and process conditions are chosen to make negligible change to the purity of the silicon in the end product. When high purity silicon powder is utilized in the process, the end use for the densified silicon compacts is primarily as feedstock for silicon-based photovoltaic manufacturing industries.