Abstract: The present invention is method comprising the steps of a) contacting 4-hydroxyphenone and a salt thereof with propylene oxide in a reactor heated to a temperature in the range of from 100° C. to 200° C. to form a poly(propylene oxide)-benzophenone intermediate; then b) contacting the intermediate with ethylene oxide in the heated reactor to form an alkoxylated benzophenone substituted with propylene oxide groups and ethylene oxide groups. The method of the present invention is useful for preparing a non-volatile alkoxylated benzophenone photoinitiator that gives long lasting gloss retention in an exterior architectural coating.

Abstract: The present invention relates to a compound which is a benzophenone substituted with a hydroxyl-terminated alkylene oxide group (R) of formula 1: where R is a combination of from 1 to 13 propylene oxide groups and from 5 to 20 ethylene oxide groups, with the proviso that the sum of the propylene oxide groups and the ethylene oxide groups is not greater than 25. The compound of the present invention provides a non-volatile, non-toxic photoinitiator that provides excellent gloss retention in exterior architectural coatings.

Abstract: An aqueous dispersion of multistage polymer particles comprising at least three polymers with low minimum film formation temperature and also providing aqueous coating compositions with balanced properties.

Abstract: The present invention relates to a benzophenone derivative and an aqueous copolymer dispersion comprising the benzophenone derivative. This invention also relates to an aqueous coating composition comprising the aqueous copolymer dispersion. The benzophenone derivative provides better crosslinking efficiency and improvement to dirt pick up resistance performance.

Abstract: The present invention is method comprising the steps of a) contacting 4-hydroxyphenone and a salt thereof with propylene oxide in a reactor heated to a temperature in the range of from 100° C. to 200° C. to form a poly(propylene oxide)-benzophenone intermediate; then b) contacting the intermediate with ethylene oxide in the heated reactor to form an alkoxylated benzophenone substituted with propylene oxide groups and ethylene oxide groups. The method of the present invention is useful for preparing a non-volatile alkoxylated benzophenone photoinitiator that gives long lasting gloss retention in an exterior architectural coating.

Abstract: The present invention relates to a compound which is a benzophenone substituted with a hydroxyl-terminated alkylene oxide group (R) of formula 1: where R is a combination of from 1 to 13 propylene oxide groups and from 5 to 20 ethylene oxide groups, with the proviso that the sum of the propylene oxide groups and the ethylene oxide groups is not greater than 25. The compound of the present invention provides a non-volatile, non-toxic photoinitiator that provides excellent gloss retention in exterior architectural coatings.

Abstract: An aqueous polymer dispersion is composed of (i) an emulsion polymer having a weight average molecular weight of from 2,000 to 30,000 daltons, wherein the emulsion polymer comprises as polymerized units, based on the dry weight of the emulsion polymer, (a) from 10% to 90% by weight of an ethylenically unsaturated ionic monomer, (b) from 5% to 90% by weight of a photosensitive monomer, and (c) from 0 to 85% by weight of an ethylenically unsaturated nonionic monomer; and (ii) from 3.5% to 50% by weight of TEMPO and/or a derivative thereof, based on the total dry weight of the aqueous polymer dispersion. An aqueous coating composition comprising the aqueous polymer dispersion and a binder provides coatings with improved durability.

Abstract: The present invention relates to a benzophenone derivative and an aqueous copolymer dispersion comprising the benzophenone derivative. This invention also relates to an aqueous coating composition comprising the aqueous copolymer dispersion. The benzophenone derivative provides better crosslinking efficiency and improvement to dirt pick up resistance performance.

Abstract: A method of producing an aqueous polymer composition and a method of reducing yellowing of an aqueous polymer composition and a coating made therefrom.

Abstract: A process of stripping a dispersion of organic extender particles with volatile organic compounds and a method of reducing volatile organic compounds.

Abstract: A method of producing an aqueous polymer composition and a method of reducing yellowing of an aqueous polymer composition and a coating made therefrom.

Abstract: A new binder composition comprising, by dry weight based on the total dry weight of the binder composition, i) from 93% to 99.96% of polymer particles comprising, as polymerized units, by dry weight based on the total weight of the polymer particles, from 25% to 95% of a vinyl acetate; and from 5% to 75% of a vinyl ester of versatic acid and/or a vinyl ester of 2-ethyl hexanoic acid; and ii) from 0.04% to 7% of a low water soluble cyclodextrin.

Abstract: An aqueous polymer dispersion and an aqueous coating composition comprising the aqueous polymer dispersion that provides coatings with improved durability.

Abstract: A process of stripping a dispersion of organic extender particles with volatile organic compounds and a method of reducing volatile organic compounds.

Abstract: A composition comprising: (a) from 20 to 60 wt % of a saccharide component comprising from two to five sugar ring units having polymerized units of at least one alkylene oxide selected from the group consisting of ethylene oxide, propylene oxide and butylene oxide bonded to oxygen atoms on said sugar rings and at least three acetoacetyl groups bonded to terminal oxygen atoms of said polymerized units of at least one alkylene oxide; and (b) from 40 to 80 wt % of a non-saccharide component comprising a polyol unit not containing a sugar ring and having a hydroxyl functionality from two to five; said polyol unit having polymerized units of at least one alkylene oxide selected from the group consisting of ethylene oxide, propylene oxide and butylene oxide bonded to hydroxyl oxygen atoms of the polyol and at least two acetoacetyl groups bonded to terminal oxygen atoms of said polymerized units of at least one alkylene oxide; wherein total polymerized units of at least one alkylene oxide comprise from 20 to 80 w

Abstract: The present invention provides compositions useful as a replacement for cellulose ether in cement, plaster or mortar compositions comprising i) nonionic or substantially nonionic vinyl or acrylic brush polymers having pendant or side chain polyether groups, and having a relative weight average molecular weight of from 140,000 to 50,000,000 g/mole, and ii) aromatic cofactors containing one or more phenolic groups, such as catechol tannins, phenolic resins, polyphenolics, and napthhols or, in combination, one or more aromatic groups with at least one sulfur acid group, such as naphthalene sulfonate aldehyde condensate polymers, poly(styrene-co-styrene sulfonate) copolymers, and lignin sulfonates, preferably branched cofactors, including phenolic resins, aldehyde condensate polymers and lignin sulfonates. The compositions may comprise a dry powder blend of i) and ii), one dry powder of both i) and ii), or an aqueous mixture.

Abstract: A coalescent consisting essentially of a residue from a process for forming propyleneglycol phenyl ether, the coalescent consisting essentially of 65%-75% by weight, based on the weight of the residue, dipropyleneglycol phenyl ether, 8%-10% by weight, based on the weight of the coalescent, monopropyleneglycol phenyl ether, 4%-6% by weight, based on the weight of the coalescent, tripropyleneglycol phenyl ether, and 0.1%-10% by weight, based on the weight of the coalescent, alkalinity (reported as NaOH) is provided. Also provided is a method for forming certain low-VOC, low cost, coalesced aqueous polymeric dispersions including, as copolymerized units, from 70% to 100% by weight, based on the solids weight of the aqueous polymeric dispersion, vinyl acetate monomer and an aqueous coating composition including the coalesced aqueous polymeric dispersion.

Abstract: The present invention relates to a composition, an aqueous dispersion of polymer particles functionalized with acetoacetoxyethyl groups and a CO2 abating additive, an ion exchange resin functionalized with amine groups or quaternary ammonium salt groups or a combination thereof. The composition is useful for CO2 abatement in acetoacetoxy functionalized latexes compositions.

Abstract: The present invention relates to a composition comprising an aqueous solution of an acid suppressible hydrophobically modified alkylene oxide polymer and a phosphoric acid ester surfactant. The composition of the present invention provides a pourable thickener with high solids content and good phase stability.

Abstract: The present invention provides compositions useful as a replacement for cellulose ether in cement, plaster or mortar compositions comprising i) nonionic or substantially nonionic vinyl or acrylic brush polymers having pendant or side chain polyether groups, and having a relative weight average molecular weight of from 140,000 to 50,000,000 g/mole, and ii) aromatic cofactors containing one or more phenolic groups, such as catechol tannins, phenolic resins, polyphenolics, and napthhols or, in combination, one or more aromatic groups with at least one sulfur acid group, such as naphthalene sulfonate aldehyde condensate polymers, poly(styrene-co-styrene sulfonate) copolymers, and lignin sulfonates, preferably branched cofactors, including phenolic resins, aldehyde condensate polymers and lignin sulfonates. The compositions may comprise a dry powder blend of i) and ii), one dry powder of both i) and ii), or an aqueous mixture.