Abstract: Systems and methods are provided for conversion of methane and/or other hydrocarbons to hydrogen by pyrolysis while reducing or minimizing production of carbon oxides. The heating of the pyrolysis environment can be performed at least in part by using electrical heating within a first stage to heat the coke particles to a desired pyrolysis temperature. This electrical heating can be performed in a hydrogen-rich environment in order to reduce, minimize, or eliminate formation of coke on the surfaces of the electrical heater. The heated coke particles can then be transferred to a second stage for contact with a methane-containing feed, such as a natural gas feed. Depending on the configuration, pyrolysis of methane can potentially occur in both the first stage and second stage. In some aspects, the hydrogen-rich environment in the first stage is formed by passing the partially converted effluent from the second stage into the first stage.

Abstract: Systems and methods are provided for production of carbon nanotubes and H2 using a reaction system configuration that is suitable for large scale production. In the reaction system, a substantial portion of the heat for the reaction can be provided by using a heated gas stream. Optionally, the heated gas stream can correspond to a heated H2 gas stream. By using a heated gas stream, when the catalyst precursors for the floating catalyst-chemical vapor deposition (FC-CVD) type catalyst are added to the gas stream, the gas stream can be at a temperature of 1000° C. or more. This can reduce or minimize loss of catalyst precursor material and/or deposition of coke on sidewalls of the reactor. Additionally, a downstream portion of the reactor can include a plurality of flow channels of reduced size that are passed through a heat exchanger environment, such as a shell and tube heat exchanger.

Abstract: Systems and methods are provided for production of carbon nanotubes and H2 using a reaction system configuration that is suitable for large scale production. In the reaction system, a substantial portion of the heat for the reaction can be provided by using a heated gas stream. Optionally, the heated gas stream can correspond to a heated H2 gas stream. By using a heated gas stream, when the catalyst precursors for the floating catalyst—chemical vapor deposition (FC-CVD) type catalyst are added to the gas stream, the gas stream can be at a temperature of 1000° C. or more. This can reduce or minimize loss of catalyst precursor material and/or deposition of coke on sidewalls of the reactor. Additionally, a downstream portion of the reactor can include a plurality of flow channels of reduced size that are passed through a heat exchanger environment, such as a shell and tube heat exchanger.

Abstract: Provided herein are dual riser fluid catalytic cracking processes for producing light olefins from an oxygenate feed, such as a methanol feed, in a conventional FCC unit. In certain aspects the processes comprise cracking a hydrocarbon feed in a first riser comprising a first catalyst under first riser conditions to form a first effluent enriched in olefins, light gasoil, gasoline, or a combination thereof; cracking a hydrocarbon oxygenate feed in a second riser comprising a second catalyst under second riser conditions to form a second effluent enriched in olefins; recovering the first and second catalyst from the first and second effluents in a common reactor; regenerating the recovered first and second catalyst in a regenerator using heat from the exothermic cracking of the hydrocarbon oxygenate feed; and recirculating the regenerated first and second catalyst to the first and second riser.

Abstract: A reformer-liquid fuel manufacturing system that utilizes an engine to generate hydrogen-rich gas is disclosed. The engine operates at very rich conditions, such as 2.5<?<4.0. In doing so, it creates an exothermic reaction, which results in the production of syngas. In addition, the system utilizes the energy from the exothermic reaction to rotate a shaft and also utilizes the heat in the syngas to heat the reactants. A mechanical power plant is in communication with the rotating shaft and can be used to produce oxygen, provide electricity or operate a compressor, as require. The hydrogen-rich gas is supplied to a chemical reactor, which converts the gas into a liquid fuel, such as methanol.

Abstract: A reformer-liquid fuel manufacturing system that utilizes an engine to generate hydrogen-rich gas is disclosed. The engine operates at very rich conditions, such as 2.5<?<4.0. In doing so, it creates an exothermic reaction, which results in the production of syngas. In addition, the system utilizes the energy from the exothermic reaction to rotate a shaft and also utilizes the heat in the syngas to heat the reactants. A mechanical power plant is in communication with the rotating shaft and can be used to produce oxygen, provide electricity or operate a compressor, as require. The hydrogen-rich gas is supplied to a chemical reactor, which converts the gas into a liquid fuel, such as methanol.

Abstract: A reformer-liquid fuel manufacturing system that utilizes an engine to generate hydrogen-rich gas is disclosed. The engine operates at very rich conditions, such as 2.5<?<4.0. In doing so, it creates an exothermic reaction, which results in the production of syngas. In addition, the system utilizes the energy from the exothermic reaction to rotate a shaft and also utilizes the heat in the syngas to heat the reactants. A mechanical power plant is in communication with the rotating shaft and can be used to produce oxygen, provide electricity or operate a compressor, as require. The hydrogen-rich gas is supplied to a chemical reactor, which converts the gas into a liquid fuel, such as methanol.