Abstract: A reactor for autothermal reforming of hydrocarbons that allows a reduction of excess-air factor ? during the reforming without resulting in a reduced conversion of the hydrocarbons in an end region of the reaction zone. The reactor includes at least one reaction zone in which is arranged at least one catalyst structure for the reformation so that the educts involved in the reformation are converted while flowing through the reaction zone. A heating device is included for heating the end region of the reaction zone to accelerate the conversion of the hydrocarbons.

Abstract: A fuel cell includes an electrolyte electrode assembly having a cathode disposed on a first side and an anode disposed on a second side of the electrolyte electrode assembly, a first flow module disposed adjacent the cathode, and a second flow module disposed adjacent the anode. At least one of the first and second flow modules includes a material suitable for exothermal hydride formation. In addition, a method for cold-starting a such fuel cell that includes at least one of the first and second flow modules with a hydrogen-containing gas so as to induce the exothermic hydride formation and release heat; and heating the fuel cell using the heat.

Abstract: A method for the autothermal reforming of a hydrocarbon, in particular of diesel, includes introducing a combustible mixture of the hydrocarbon to be reformed and an oxygen-containing medium into a first reaction zone of a reformer, A gas-phase reaction is ignited. After an operating temperature required for the autothermal reforming process is reached, water or a water-containing medium is introduced into the first reaction zone, and the water content is increased until the conditions for the reforming process of the hydrocarbon prevail. The reforming process then takes place predominantly in a second reaction zone.

Abstract: A reactor system for reacting a hydrocarbon or hydrocarbon derivative charging material comprises a catalyst-coated reaction chamber, to which a reaction educt stream can be fed through a reaction chamber inlet, and electric heating means. The reaction chamber inlet has a flat, electrically heatable, catalyst-coated, and reaction educt stream-permeable heater, which covers at least partially the inlet cross section of the reaction chamber inlet and through which the educts for reacting the charging material can be fed at least in a start operating phase of the reactor system. An electric heater may be provided in front of the reaction chamber inlet, for the purpose of heating at least one reaction educt in a start operating phase and there are means for point-by-point injection of at least one reaction educt, heated in the heater, into the reaction chamber.

Abstract: A fuel cell method and apparatus includes upstream reforming of hydrocarbons and/or alcohols, with water contained in the exhaust air stream of the fuel cell system being recovered. An absorption unit is connected into the exhaust air stream of the fuel cell, and water absorbed therein is released in a desorption unit, preferably by means of heated air to be supplied, and/or by heating the glycol solution. The moist air can subsequently be returned to the fuel cell system or the reforming unit. This makes it possible to recover all of the process water, and to operate the system at low pressure.

Abstract: The invention relates to an autothermic reforming reactor, comprising an endothermic reaction zone, in which the reforming reaction takes place; an exothermic reaction zone, in which the energy is released which is required for the reforming reaction; a quench zone connected downstream of the reaction zones for the rapid cooling of the reactor gas volume flow. According to the invention, the endothermic reaction zone and the quench zone are separated by a gas permeable heat shield (HS), whereby the heat shield (HS) comprises thermal insulation (IS) for thermally insulating the endothermic reaction zone and quench zone, in addition to a thermal radiator (STR) which faces the endothermic reaction zone and radiates the thermal energy which has been absorbed from the reactor gas volume flow.

Abstract: A reactor system for producing hydrogen from a hydrocarbon or hydrocarbon derivative using autothermal reformation includes a mixture formation chamber, an autothermal reactor, and a temperature-regulated start-up burner. The start-up burner combusts the hydrocarbon or the hydrocarbon derivative with air so as to heat the mixture formation chamber and/or the autothermal reactor to a respective operating temperature. An air supply is metered to the start-up burner so as to regulate the temperature of hot gas coming out of the start-up burner to a value near or below a deterioration temperature of the catalyst material, before the hot gas contacts the mixture formation chamber and/or the autothermal reactor.

Abstract: A heat exchanger system for a device for autothermal reforming of a hydrocarbon having a reaction zone fed with at least two fluids which react with one another, the reaction zone being at a higher temperature level than an environment of the device and at least one of the fluids being heated by the reaction products effluent from the reaction zone. The heat exchanger system includes tubes for transporting the effluent reaction products, at least one section of the tubes being arranged essentially parallel to a center axis of the reaction zone and led through the flow path of the fluid to be heated. At least sections of the flow path are curved helically or spirally around the center axis so that the fluid to be heated impinges on and passes around the tubes containing the effluent reaction products essentially perpendicularly.

Abstract: An exhaust gas purification device in a vehicle, wherein a reforming reactor is provided for extraction of hydrogen from fuel and the hydrogen is supplied to an exhaust gas stream of an internal combustion engine upstream of the exhaust gas catalytic converter, wherein the reforming reactor includes a supply device for oxygen and/or water, wherein the reforming reactor is connected with a side branch of the exhaust gas conduit and wherein oxygen and water for reforming are supplied in the form of an exhaust gas partial stream via the side branch.

Abstract: A method for preventing flashback in a reaction chamber that includes providing a mixture of educts flowing through a mixture distribution zone and into the reaction chamber. The mixture distribution zone has an inlet opening and a variable flow cross-section between the inlet opening and the reaction chamber. The method also includes combusting the mixture in the reaction chamber at a combustion rate, and varying the flow cross-section as a function of a volume of the mixture so as to affect a flow rate of the mixture into the reaction chamber such that the flow rate is greater than the combustion rate. In addition, a reactor that includes, an inlet opening for receiving a mixture of educts, a mixture distribution zone disposed downstream of the inlet opening and having a variable flow cross-section, a reaction chamber disposed downstream of the mixture distribution zone, and a regulation device disposed in the mixture distribution zone for varying the flow cross section.

Abstract: A fuel cell includes an electrolyte electrode assembly having a cathode disposed on a first side and an anode disposed on a second side of the electrolyte electrode assembly, a first flow module disposed adjacent the cathode, and a second flow module disposed adjacent the anode. At least one of the first and second flow modules includes a material suitable for exothermal hydride formation. In addition, a method for cold-starting a such fuel cell that includes flooding at least one of the first and second flow modules with a hydrogen-containing gas so as to induce the exothermic hydride formation and release heat; and heating the fuel cell using the heat.

Abstract: A reactor for autothermal reforming of hydrocarbons that allows a reduction of excess-air factor &phgr; during the reforming without resulting in a reduced conversion of the hydrocarbons in an end region of the reaction zone. The reactor includes at least one reaction zone in which is arranged at least one catalyst structure for the reformation so that the educts involved in the reformation are converted while flowing through the reaction zone. A heating device is included for heating the end region of the reaction zone to accelerate the conversion of the hydrocarbons.

Abstract: A heat exchanger system for a device for autothermal reforming of a hydrocarbon having a reaction zone fed with at least two fluids which react with one another, the reaction zone being at a higher temperature level than an environment of the device and at least one of the fluids being heated by the reaction products effluent from the reaction zone. The heat exchanger system includes tubes for transporting the effluent reaction products, at least one section of the tubes being arranged essentially parallel to a center axis of the reaction zone and led through the flow path of the fluid to be heated. At least sections of the flow path are curved helically or spirally around the center axis so that the fluid to be heated impinges on and passes around the tubes containing the effluent reaction products essentially perpendicularly.

Abstract: A method for reforming a liquid hydrocarbon mixture, in which the hydrocarbon mixture is initially completely vaporized before it is contacted with the gaseous reactants and caused to undergo reaction. Usable as a reformer system in this context is a device which has at least two reforming chambers composed of a vaporization chamber and at least one reaction chamber, and in which a metering device for liquid hydrocarbons is provided in the region of the vaporization chamber, and an introducing device for gaseous reactants is provided in the region between at least two of the reforming chambers. The present invention allows liquid hydrocarbon mixtures to be reformed without the formation of unwanted residues such as tar or soot.

Abstract: An exhaust gas purification device in a vehicle, wherein a reforming reactor is provided for extraction of hydrogen from fuel and the hydrogen is supplied to an exhaust gas stream of an internal combustion engine upstream of the exhaust gas catalytic converter, wherein the reforming reactor includes a supply device for oxygen and/or water, wherein the reforming reactor is connected with a side branch of the exhaust gas conduit and wherein oxygen and water for reforming are supplied in the form of an exhaust gas partial stream via the side branch.

Abstract: A fuel cell system has at least one fuel cell and a hydrogen generating arrangement for feeding the fuel cell anode with a hydrogen-containing product gas from a conversion reaction of a hydrocarbon starting substance or hydrocarbon derivative with of water fed supplied by way of a water feeding system. Water recovery devices are provided for condensing water out of the process gas supplied by the hydrogen generating arrangement, and/or out of the cathode waste gas carried away from the fuel cell cathode, and returning the condensed-out water into the water feeding system.

Abstract: A method and apparatus for applying pressure to at least one reactant for delivery from a storage tank to a gas generating system has at least one pump. An operating medium for applying pressure to the reactants is delivered from the pump to the storage tank via a pipe system. The operating medium itself may also be delivered to a reaction chamber as a reactant of the gas generating system.

Abstract: A fuel cell method and apparatus includes upstream reforming of hydrocarbons and/or alcohols, with water contained in the exhaust air stream of the fuel cell system being recovered. An absorption unit is connected into the exhaust air stream of the fuel cell, and water absorbed therein is released in a desorption unit, preferably by means of heated air to be supplied, and/or by heating the glycol solution. The moist air can subsequently be returned to the fuel cell system or the reforming unit. This makes it possible to recover all of the process water, and to operate the system at low pressure.