Abstract: Described herein is an absorbent article. The absorbent article includes an assembly of components and an adhesive composition joining at least two of the assembly of components together. The adhesive composition includes from about 50 wt. % to about 80 wt. % of one or more copolymers and a blend of one or more heterophase copolymers. The one or more copolymers include from about 30 mole % to about 70 mole % of monomer units selected from ethylene. 1-butene, and mixtures thereof. The one or more copolymers also include from about 30 mole % to about 70 mole % of propene monomer units. The adhesive composition is free of polyisobutylene and has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C.

Abstract: Described herein is an adhesive composition including a copolymer. The adhesive composition has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C. The adhesive composition has a Storage Modulus at 37° C. of from about 3 MPa to 9.5 MPa. The adhesive composition has a Yield Stress at 37° C. of from about 0.8 MPa to about 1.45 MPa.

Abstract: A packaging material including a polymeric film surrounding a plastic mass form material. In embodiments, methods include packaging sticky plastic mass form polymers within a polymeric film to prevent agglomeration. Processes include the use of a polymeric film composition that is compatible with the core plastic mass form. The polymeric film can be applied to the plastic mass form through continuous coextrusion, as a film through a hot melt form, fill, and seal process, or as a sealed film bag for inclusion of cooled and coated or uncoated solid sticky plastic material shapes.

Abstract: Described herein is an adhesive composition including (a) from about 70 wt. % to about 90 wt. % of one or more copolymers, and (b) from about 10 wt. % to about 30 wt. % of one or more heterophase copolymers. The one or more copolymers include (i) from about 30 mole % to about 70 mole % of monomer units selected from the group consisting of ethylene, 1-butene, and mixtures thereof; and (ii) from about 30 mole % to about 70 mole % of propene monomer units. The adhesive composition is free of polyisobutylene. The adhesive composition has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C. The one or more heterophase copolymers includes a first heterophase copolymer and a second heterophase copolymer.

Abstract: A continuous process for pre-contacting coordination polymerization catalyst components with each other before they are introduced into a polymerization reactor at 130 degrees Fahrenheit to 200 degrees Fahrenheit, where the activated coordination catalyst is contacted with at least one monomer to produce amorphous poly alpha olefin (APAO), the process involving blending a Ziegler-Natta pro-catalyst with a liquid carrier forming a Ziegler-Natta pro-catalyst slurry and flowing a co-catalyst mixture into the Ziegler-Natta pro-catalyst slurry continuously in a pre-contacting device, forming an activated Ziegler-Natta catalyst; continuously injecting the activated Ziegler-Natta catalyst into the heated polymerization reactor while simultaneously, and continuously, injecting propylene monomer and any other alpha-olefin monomers, and hydrogen gas for molecular weight control, initiating an exothermic reaction forming a monomer-polymer-catalyst slurry then continuously stirring the monomer-polymer-catalyst slurry for

Abstract: A continuous process for pre-contacting coordination polymerization catalyst components with each other before they are introduced into a polymerization reactor at 130 degrees Fahrenheit to 200 degrees Fahrenheit, where the activated coordination catalyst is contacted with at least one monomer to produce amorphous poly alpha olefin (APAO), the process involving blending a Ziegler-Natta pro-catalyst with a liquid carrier forming a Ziegler-Natta pro-catalyst slurry and flowing a co-catalyst mixture into the Ziegler-Natta pro-catalyst slurry continuously in a pre-contacting device, forming an activated Ziegler-Natta catalyst; continuously injecting the activated Ziegler-Natta catalyst into the heated polymerization reactor while simultaneously, and continuously, injecting propylene monomer and any other alpha-olefin monomers, and hydrogen gas for molecular weight control, initiating an exothermic reaction forming a monomer-polymer-catalyst slurry then continuously stirring the monomer-polymer-catalyst slurry for

Abstract: A continuous process for pre-contacting coordination polymerization catalyst components with each other before they are introduced into a polymerization reactor at 130 degrees Fahrenheit to 200 degrees Fahrenheit, where the activated coordination catalyst is contacted with at least one monomer to produce amorphous poly alpha olefin (APAO). Embodiments of the process involves blending a metallocene pre-catalyst with an organic solvent forming a metallocene pre-catalyst solution and flowing a co-catalyst mixture into the metallocene pre-catalyst solution continuously in a pre-contacting device, forming an activated metallocene catalyst. Embodiments further involve continuously injecting the activated metallocene catalyst into the heated polymerization reactor while simultaneously and continuously injecting propylene monomer and/or other alpha-olefin monomers, and hydrogen gas for molecular weight control, initiating an exothermic reaction forming a monomer-polymer-catalyst slurry.

Abstract: A hot-melt formulation includes a butene-1-co-hexene-1 copolymer formed from butene-1 and hexene-1 monomers synthesized using a supported Ziegler-Natta catalyst reacted with an organometallic cocatalyst, a styrenic block copolymer with less than 15 percent bound styrene, a high melt viscosity metallocene catalyzed polyolefin, a high melt viscosity polypropylene with a melt viscosity above 18,000 cps, and a low molecular weight polyethylene wax, wherein the melt viscosity of the wax is less than 1,000 centipoise at a temperature of 350 degrees Fahrenheit.

Abstract: A method to make a hot-melt polymer formulation with from 50 wt % to 100 wt % of a propylene-co-butene-1-co-hexene-1 terpolymer or a propylene-co-hexene-1 copolymer, each polymer made using a metal chloride supported Ziegler-Natta catalyst, at a process temperature between about 130 degrees Fahrenheit and about 200 degrees Fahrenheit and at a reactor pressure sufficient to maintain the propylene in a liquid phase without solvent; using 1 wt % to 20 wt % of at least one of: a metallocene-catalyst made polymer; a homopolymer of propylene with 0.1%-5% functionality; and a styrene block copolymer; and wherein the melt viscosity of the terpolymer or copolymer formulation is controlled by addition of hydrogen gas as a chain transfer agent.

Abstract: A method to make a high melt strength amorphous poly alpha olefin (APAO) includes blending APAO with a free radical initiator using a residence time from 0.1 minutes to 10 minutes at a temperature range from 300 degrees Fahrenheit to 400 degrees Fahrenheit, thereby forming an intermediate. A graftable monomer may then be added to the intermediate in a ratio from 0.1:100 to 2:100 at a temperature range from 225 degrees Fahrenheit to 400 degrees Fahrenheit using a residence time from 0.1 to 20 minutes, thereby forming a functionalized APAO. A multifunctional monomer in an amount ranging from 0.1% to 5% by weight of the functionalized APAO can be added to the functionalized APAO for 0.1 to 20 minutes at 200 to 400 degrees Fahrenheit, thereby forming a cross-linkable APAO. An acid neutralizer may be added to initiate crosslinking, making a crosslinked APAO with various degrees of crosslinking as observed by the changes in the melt viscosity.

Abstract: A hot-melt formulation includes a butene-1-co-hexene-1 copolymer formed from butene-1 and hexene-1 monomers synthesized using a supported Ziegler-Natta catalyst reacted with an organometallic cocatalyst, a styrenic block copolymer with less than 15 percent bound styrene, a high melt viscosity metallocene catalyzed polyolefin, a high melt viscosity polypropylene with a melt viscosity above 18,000 cps, and a low molecular weight polyethylene wax, wherein the melt viscosity of the wax is less than 1,000 centipoise at a temperature of 350 degrees Fahrenheit.

Abstract: Described herein is an absorbent article having a longitudinal centerline and a lateral centerline, a front waist region with a front waist edge, a rear waist region with a rear waist edge, a crotch region disposed between the front waist region and the rear waist region, and two spaced apart longitudinal side edges joining the front waist edge to the rear waist edge, wherein the absorbent article comprises an assembly of components, and wherein the absorbent article comprises an adhesive composition. The adhesive composition comprises a copolymer; the adhesive composition has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C., the adhesive composition has a Storage Modulus at 37° C. of from about 3 MPa to 9.5 MPa, and the adhesive composition has a Yield Stress at 37° C. of from about 0.8 MPa to about 1.45 MPa.

Abstract: Described herein is an adhesive composition including (a) from about 70 wt. % to about 90 wt. % of one or more copolymers, and (b) from about 10 wt. % to about 30 wt. % of one or more heterophase copolymers. The one or more copolymers include (i) from about 30 mole % to about 70 mole % of monomer units selected from the group consisting of ethylene, 1-butene, and mixtures thereof; and (ii) from about 30 mole % to about 70 mole % of propene monomer units. The adhesive composition is free of polyisobutylene. The adhesive composition has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C. The one or more heterophase copolymers includes a first heterophase copolymer and a second heterophase copolymer.

Abstract: Described herein is an adhesive composition including at least 90 wt. % of a copolymer including from about 30 wt. % to about 70 wt. % of propene monomer units and from about 30 wt. % to about 70 wt. % of 1-butene monomer units. The adhesive composition can have a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C. The adhesive composition can have an Enthalpy of Fusion of less than 17 J/g. The adhesive composition can have a Tensile Strength at Yield of from about 0.5 MPa to about 1.5 MPa. The copolymer can have a Static Peel Time of at least 220 seconds.

Abstract: Described herein is an absorbent article. The absorbent article includes an assembly of components and an adhesive composition joining at least two of the assembly of components together. The adhesive composition includes from about 70 wt. % to about 90 wt. % of one or more copolymers and from about 10 wt. % to about 30 wt. % of one or more heterophase copolymers. The one or more copolymers include from about 30 mole % to about 70 mole % of monomer units selected from ethylene, 1-butene, and mixtures thereof. The one or more copolymers also include from about 30 mole % to about 70 mole % of propene monomer units. The adhesive composition is free of polyisobutylene and has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C.

Abstract: Described herein is an adhesive composition including a copolymer. The adhesive composition has a viscosity of from about 2,000 mPa·s to about 11,500 mPa·s at 150° C. The adhesive composition has a Storage Modulus at 37° C. of from about 3 MPa to 9.5 MPa. The adhesive composition has a Yield Stress at 37° C. of from about 0.8 MPa to about 1.45 MPa.

Abstract: A hot-melt adjuvant-free formulation includes a butene-1-co-hexene-1 copolymer formed from butene-1 and hexene-1 monomers with a supported Ziegler-Natta catalyst, a styrenic block copolymer with less than 15 percent styrene, a high melt flow index metallocene, a high melt flow rate polypropylene with a melt flow above 18000 cps, and a low molecular weight polyethylene wax, wherein the molecular weight is less than 1000 centipoise at a temperature of 350 degrees Fahrenheit.

Abstract: A method to make a hot-melt polymer formulation with from 50 wt % to 100 wt % of a propylene-co-butene-1-co-hexene-1 terpolymer or a propylene-co-hexene-1 copolymer, each polymer made using a metal chloride supported Ziegler-Natta catalyst, at a process temperature between about 130 degrees Fahrenheit and about 200 degrees Fahrenheit and at a reactor pressure sufficient to maintain the propylene in a liquid phase without solvent; using 1 wt % to 20 wt % of at least one of: a metallocene-catalyst made polymer; a homopolymer of propylene with 0.1%-5% functionality; and a styrene block copolymer; and wherein the melt viscosity of the terpolymer or copolymer formulation is controlled by addition of hydrogen gas as a chain transfer agent.

Abstract: A method to make a hot-melt polymer formulation with from 50 wt % to 100 wt % of a propylene-co-butene-1-co-hexene-1 terpolymer or a propylene-co-hexene-1 copolymer, each polymer made using a metal chloride supported Ziegler-Natta catalyst, at a process temperature between about 130 degrees Fahrenheit and about 175 degrees Fahrenheit and at a reactor pressure sufficient to maintain the propylene in a liquid phase without solvent; using 1 wt % to 20 wt % of at least one of: a metallocene polymer; a homopolymer of propylene with 0.1%-5% functionality; and a styrene block copolymer; and wherein the terpolymer or copolymer formulation is controlled by addition of a hydrogen gas as a chain transfer agent.

Abstract: A hot melt adhesive formulation includes 60 to 99 wt. % of an amorphous propylene-co-hexene-1 polymer component based on the total weight of the hot melt adhesive without the use of flammable solvents, 20 to 80 wt % of hexene-1 co-monomer based on the total weight of the amorphous propylene-co-hexene-1 copolymer component, 20 to 80 wt. % of a propylene co-monomer based on the total weight of the amorphous propylene-co-hexene-1 copolymer component, and from 1 to 40 wt. % of a co-adjuvant based on the total weight of the hot melt adhesive. The hot melt adhesive formulation has rolling ball tack from 2 to 50 centimeters at ambient temperature after conditioning at ambient temperatures for 24 hours. The hexene-1 monomer to propylene monomer ratios are from 4:1 to 1:4.