Patents by Inventor Andrew J. Sivak

Andrew J. Sivak has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5373061
    Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: December 13, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo
  • Patent number: 5367090
    Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: November 22, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo
  • Patent number: 5329037
    Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: July 12, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo
  • Patent number: 5296562
    Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
    Type: Grant
    Filed: March 18, 1993
    Date of Patent: March 22, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo
  • Patent number: 5296626
    Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: March 22, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo
  • Patent number: 5294679
    Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
    Type: Grant
    Filed: March 18, 1993
    Date of Patent: March 15, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo
  • Patent number: 5266663
    Abstract: Silyl derivatives of eugenol include compositions of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from linear, branched, and cyclic hydrocarbon groups having a total of from one to about eight carbon atoms, except that where one of R.sup.1, R.sup.2 or R.sup.3 is a phenyl group, the total of carbon atoms must be at least nine. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites and may be copolymerized in Ziegler-Natta catalyst systems.
    Type: Grant
    Filed: August 5, 1992
    Date of Patent: November 30, 1993
    Assignee: Aristech Chemical Corporation
    Inventors: Mary K. Haus, Andrew J. Sivak
  • Patent number: 5248737
    Abstract: Mono and diallyl amines are silylated to protect them from reacting with high activity Ziegler-Natta catalysts so they may be copolymerized with propylene; also disclosed are copolymers of such amines with propylene and their hydrolyzed or alcoholyzed counterparts.
    Type: Grant
    Filed: August 5, 1992
    Date of Patent: September 28, 1993
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo, William L. Krayer
  • Patent number: 5239030
    Abstract: Mono and diallyl amines are silylated to protect them from reacting with high activity Ziegler-Natta catalysts so they may be copolymerized with propylene; copolymers of such amines with propylene and their hydrolyzed or alcholyzed counterparts; also the amine monomers disclosed.
    Type: Grant
    Filed: October 16, 1989
    Date of Patent: August 24, 1993
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo, William L. Krayer
  • Patent number: 5206323
    Abstract: Silyl derivatives of eugenol include compositions of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from linear, branched, and cyclic hydrocarbon groups having a total of from one to about eight carbon atoms, except that where one of R.sup.1, R.sup.2 or R.sup.3 is a phenyl group, the total of carbon atoms must be at least nine. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites and may be copolymerized in Ziegler-Natta catalyst systems.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: April 27, 1993
    Inventors: Mary K. Hays, Andrew J. Sivak
  • Patent number: 5200542
    Abstract: Mono and diallyl amines are silylated to protect them from reacting with high activity Ziegler-Natta catalysts so they may be copolymerized with propylene; copolymers of such amines with propylene and their hydrolyzed or alcholyzed counterparts; also the amine monomers disclosed.
    Type: Grant
    Filed: August 6, 1992
    Date of Patent: April 6, 1993
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullo, William L. Krayer
  • Patent number: 5110971
    Abstract: Silyl derivatives of eugenol include compositions of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from linear, branched, and cyclic hydrocarbon groups having a total of from one to about eight carbon atoms, except that where one of R.sup.1, R.sup.2 or R.sup.3 is a phenyl group, the total of carbon atoms must be at least nine. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites and may be copolymerized in Ziegler-Natta catalyst systems.
    Type: Grant
    Filed: September 5, 1990
    Date of Patent: May 5, 1992
    Assignee: Aristech Chemical Corporation
    Inventors: Mary K. Haus, Andrew J. Sivak
  • Patent number: 5008421
    Abstract: Silyl derivatives of 2,6 dimethyl, 4-allyl phenol include compositions of the formula ##STR1## where R.sup.1, R.sup.2, and R.sup.3 are independently selected from alkyl and phenyl groups having up to about eight carbon atoms and/or are connected to form one or more rings. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites in high molecular weight copolymers.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: April 16, 1991
    Assignee: Aristech Chemical Corporation
    Inventors: George L. Brownell, Mary K. Hays, Andrew J. Sivak
  • Patent number: 4970329
    Abstract: Silyl derivatives of 2-allyl phenol include compositions of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from alkyl and phenyl groups having up to about twelve carbon atoms. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites by Ziegler-Natta catalyst systems.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: November 13, 1990
    Assignee: Aristech Chemical Corporation
    Inventors: Andrew J. Sivak, Leonard A. Cullop
  • Patent number: 4916248
    Abstract: Silyl derivatives of 2,6 dimethyl, 4-allyl phenol include compositions of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from alkyl and phenyl groups having up to about eight carbon atoms. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites in high molecular weight copolymers.
    Type: Grant
    Filed: July 5, 1989
    Date of Patent: April 10, 1990
    Assignee: Aristech Chemical Corporation
    Inventors: George L. Brownell, Mary K. Hays, Andrew J. Sivak
  • Patent number: 4786717
    Abstract: Aluminum alkyls are deactivated in a spent hydrocarbon carrier for an olefin polymerization system by the addition of effective amounts of triglycerides.
    Type: Grant
    Filed: November 10, 1986
    Date of Patent: November 22, 1988
    Assignee: Aristech Chemical Corporation
    Inventors: Randall K. Bretches, Andrew J. Sivak, Russell L. Stainfield