Abstract: A strength additive composition for papermaking processes using high-kappa furnish is disclosed. The composition comprises an aqueous media and a glyoxalated polyacrylamide (gPAM) resin having a weight average molecular weight (Mw) of at least about 5 MDa, a radius of gyration (Rg) of at least about 150 nm, and a structural density (Rg/Mw) of less than about 15 nm/Mda. A method of preparing the composition is also disclosed, and may be carried out in situ during a papermaking process (i.e., as an on-site method). A process of forming paper with the composition is also disclosed, and comprises combining the composition with an aqueous suspension of cellulosic fibers, forming the cellulosic fibers into a sheet, and drying the sheet to produce a paper.

Abstract: A drainage-optimized additive composition for papermaking is disclosed. The composition comprises an aqueous media and a glyoxalated polyacrylamide (gPAM) resin having a weight average molecular weight (Mw) of at least about 5 MDa. The composition comprises from about 1.95 to about 2.45 wt. % of the gPAM resin. A method of preparing the composition is also disclosed, and comprises preparing a cationic acrylamide (cAM) prepolymer having at least one predetermined property, and selectively glyoxalating the cAM prepolymer by controlling the concentration of the cAM prepolymer in the aqueous media during glyoxalation in relation to the predetermined property. The method may be carried out in situ during a papermaking process (i.e., as an on-site method). A process of forming paper with the composition also disclosed, and comprises combining the composition with the aqueous suspension of cellulosic fibers, forming the cellulosic fibers into a sheet, and drying the sheet to produce a paper.