Abstract: A gas cooled nuclear reactor is permanently deactivated on occurrence of an emergency by pyrolytic deposition of boron or refractory or stable compounds of boron in the fluid channels of the fuel elements of the reactor. The boron is enriched in boron 10. The deposition takes place in so short a time interval as to preclude a major catastrophe by reason of penetration of water into the reactor. Carbon and/or nitrogen-containing boron compounds are injected directly into the reactor or compounds generated by reaction in the working fluid of the reactor between diborane and other boron hydrides with unsaturated compounds, such as acetylene and ammonia flow through the reactor. The compounds are carried by the working fluid through the core and are pyrolized in the heat of the core to produce more stable boron, or boron-carbon and boron-nitrogen compounds or metal borides which adhere to the walls of the channels in the fuel elements, deactivating the core.