Patents by Inventor Armelle Sigwald
Armelle Sigwald has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230323101Abstract: The invention relates to a polypropylene composition comprising: (a) a first metallocene-catalyzed polypropylene (RPP-A) which is homopolymer, or a random copolymer of propylene and of a co-monomer; and (b) a second metallocene-catalyzed polypropylene (RPP-B) which is a random copolymer of propylene and of a co-monomer; wherein said polypropylene composition has:- a total co-monomer content of at least 1.1% by weight relative to the total weight of said polypropylene composition, as determined by 13C NMR analysis, said co-monomer being an alpha-olefin different from propylene;- a melting temperature Tm of at least 130° C., measured by DSC; - a crystallization temperature Tc of at least 95.0° C., measured by DSC; - a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) [Mw/Mn] of at least 4.50;- a ratio of z-average molecular weight (Mz) to weight average molecular weight (Mw) [Mz/Mw] of at least 2.10; and- a co-monomer distribution ratio R(Mz)/R(Mn) higher than 0.Type: ApplicationFiled: October 14, 2021Publication date: October 12, 2023Applicant: TOTALENERGIES ONETECH BELGIUMInventors: Thomas COUSTHAM, Alain STANDAERT, Aurélien VANTOMME, Armelle SIGWALD
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Patent number: 11692087Abstract: The invention relates to a process and an installation to produce a monovinylaromatic polymer (3) comprising post-consumer recycled polystyrene (PCR-PS) wherein the process comprises the steps of mixing the PCR-PS (5) and the monovinylaromatic monomer (7) within a dissolver (9) to dissolve the PCR-PS (5) in the monovinylaromatic monomer (7) so as to produce a polymerization mixture (13); and a step of filtering the polymerization mixture (13) that includes continuously redirecting at least a part of the stream of the filtered polymerization mixture (17) back to the dissolver (9) and mixing it with the polymerization mixture (13) so as to continuously reduce the content of insoluble material in the polymerization mixture (13) contained in the dissolver (9).Type: GrantFiled: August 17, 2021Date of Patent: July 4, 2023Assignee: TOTALENERGIES ONETECH BELGIUMInventors: Jose-Maria Pere, Antonio Guinovart, Armelle Sigwald, Laetitia Urbanczyk, Martine Slawinski, Pascal Charlier, Elodie Perche, Serge Eon, Thierry Marcoux, Matthieu Adam-Berret
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Publication number: 20220315749Abstract: The present invention is related to a process for the production of a vinyl aromatic (co)polymer comprising the steps of: a) mixing a fraction (A) comprising one or more monomers selected from the group consisting of styrene, alpha-methyl styrene, acrylonitrile, methyl (meth)acrylate, (meth)acrylic acid and butadiene with a fraction (B) comprising post-consumer recycled vinyl aromatic (co)polymer, wherein the weight ratio of fraction (B) to fraction (A) is comprised between 0.01/1 and 1/1, preferably between 0.05/1 and 0.Type: ApplicationFiled: August 12, 2020Publication date: October 6, 2022Inventors: Jean-Claude Deleye, Magali Vachaudez, Armelle Sigwald, Elodie Perche, Gabriela Quevedo Silvetti
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Publication number: 20220186009Abstract: The invention relates to a polypropylene composition comprising: (A) a first polypropylene which is a metallocene-catalyzed homopolymer, or a metallocene-catalyzed random copolymer of propylene and of a co-monomer having at most 0.5% by weight of co-monomer content, relative to the total weight of the random copolymer, as determined by 13C NMR analysis; and (B) a second polypropylene which is a metallocene-catalyzed random copolymer of propylene and of a co-monomer; wherein said polypropylene composition is as defined in claim 1. The present invention also relates to a process for the preparation of said polypropylene composition. The present invention also relates to an article comprising said polypropylene composition.Type: ApplicationFiled: April 10, 2020Publication date: June 16, 2022Inventors: Thomas Coustham, Aurélien Vantomme, Armelle Sigwald, Alain Standaert
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Patent number: 11236221Abstract: The present invention relates to a polyethylene resin suitable for preparing moulded articles, such as caps and closures. The invention provides in particular a polyethylene resin comprising at least two polyethylene fractions A and B, wherein said polyethylene resin has a melt index (MI2), of at least 3.0 g/10 min to at most 5.5 g/10 min as measured according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg, and a density of at least 0.955 g/cm3 to at most 0.965 g/cm3 as measured according to ISO 1183 at 23° C., and a molecular weight distribution Mw/Mn which is at most 7.0, as determined by gel permeation chromatography, with Mw being the weight-average molecular weight and Mn being the number-average molecular weight; and wherein said polyethylene fraction A has a high load melt index (HLMI), as measured according to ISO 1133:1997 condition G at 190° C. and under a load of 21.6 kg, of at least 10.5 and a melt index (MI2) of at least 0.5 g/10 min to at most 1.Type: GrantFiled: November 12, 2018Date of Patent: February 1, 2022Assignee: Total Research & Technology FeluyInventors: David Ribour, Alain Standaert, Armelle Sigwald, Aurélien Vantomme
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Patent number: 11208504Abstract: The present invention relates to an injection-molded article, comprising at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the at least one metallocene-catalyzed polyethylene resin comprises: at least 40% to at most 50% by weight of polyethylene fraction A based on the total weight of the at least one metallocene-catalyzed polyethylene resin, wherein fraction A has a melt index MI2 of at least 100.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg; and wherein the at least one metallocene-catalyzed polyethylene resin has a density of at least 0.940 g/cm3 to at most 0.950 g/cm3 as measured on pellets according to ISO 1183 at 23° C.; a melt index MI2 of at least 1.4 g/10 min to at most 2.5 g/10 min as measured on pellets according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg.Type: GrantFiled: July 11, 2018Date of Patent: December 28, 2021Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Jean-Léon Gielens, Armelle Sigwald, Christopher Willocq
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Patent number: 11193006Abstract: The invention relates to a composition comprising a rubber-modified monovinylaromatic polymer comprising: 70 wt % or more of a monovinylaromatic polymer matrix, from 2 to 12 wt % of at least one rubber, and from 0.1 to 3.4 wt % of metallocene-catalyzed poly-alpha-olefins (mPAO) all based on the total weight of the rubber-modified monovinylaromatic polymer, with the mPAO having a kinematic viscosity of at least 950 mm2/s at 40° C. and at most 2,000 mm2/s at 40° C. as measured according to ISO 3104. The invention also relates to articles made from such composition and to the process to produce said composition and said articles.Type: GrantFiled: August 31, 2017Date of Patent: December 7, 2021Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Serge Eon, Vinciane Jonnieaux, Armelle Sigwald
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Publication number: 20210371636Abstract: The invention relates to a process and an installation to produce a monovinylaromatic polymer (3) comprising post-consumer recycled polystyrene (PCR-PS) wherein the process comprises the steps of mixing the PCR-PS (5) and the monovinylaromatic monomer (7) within a dissolver (9) to dissolve the PCR-PS (5) in the monovinylaromatic monomer (7) so as to produce a polymerization mixture (13); and a step of filtering the polymerization mixture (13) that includes continuously redirecting at least a part of the stream of the filtered polymerization mixture (17) back to the dissolver (9) and mixing it with the polymerization mixture (13) so as to continuously reduce the content of insoluble material in the polymerization mixture (13) contained in the dissolver (9).Type: ApplicationFiled: August 17, 2021Publication date: December 2, 2021Inventors: Jose-Maria Pere, Antonio Guinovart, Armelle Sigwald, Laetitia Urbanczyk, Martine Slawinski, Pascal Charlier, Elodie Perche, Serge Eon, Thierry Marcoux, Matthieu Adam-Berret
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Patent number: 11124638Abstract: The invention relates to a process and an installation to produce a monovinylaromatic polymer (3) comprising post-consumer recycled polystyrene (PCR-PS) wherein the process comprises the steps of mixing the PCR-PS (5) and the monovinylaromatic monomer (7) within a dissolver (9) to dissolve the PCR-PS (5) in the monovinylaromatic monomer (7) so as to produce a polymerization mixture (13); and a step of filtering the polymerization mixture (13) that includes continuously redirecting at least a part of the stream of the filtered polymerization mixture (17) back to the dissolver (9) and mixing it with the polymerization mixture (13) so as to continuously reduce the content of insoluble material in the polymerization mixture (13) contained in the dissolver (9).Type: GrantFiled: February 28, 2018Date of Patent: September 21, 2021Assignee: Total Research & Technology FeluyInventors: Jose-Maria Pere, Antonio Guinovart, Armelle Sigwald, Laetitia Urbanczyk, Martine Slawinski, Pascal Charlier, Elodie Perche, Serge Eon, Thierry Marcoux, Matthieu Adam-Berret
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Publication number: 20210147586Abstract: The present invention relates to an injection-molded article, comprising at least one metallocene-catalyzed polyethylene resin comprising at least two metallocene-catalyzed polyethylene fractions A and B, wherein the at least one metallocene-catalyzed polyethylene resin comprises: at least 40% to at most 50% by weight of polyethylene fraction A based on the total weight of the at least one metallocene-catalyzed polyethylene resin, wherein fraction A has a melt index MI2 of at least 100.0 g/10 min as determined according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg; and wherein the at least one metallocene-catalyzed polyethylene resin has a density of at least 0.940 g/cm3 to at most 0.950 g/cm3 as measured on pellets according to ISO 1183 at 23° C.; a melt index MI2 of at least 1.4 g/10 min to at most 2.5 g/10 min as measured on pellets according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg.Type: ApplicationFiled: July 11, 2018Publication date: May 20, 2021Inventors: Aurélien Vantomme, Jean-Léon Gielens, Armelle Sigwald, Christopher Willocq
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Publication number: 20200385554Abstract: The present invention relates to a polyethylene resin suitable for preparing moulded articles, such as caps and closures. The invention provides in particular a polyethylene resin comprising at least two polyethylene fractions A and B, wherein said polyethylene resin has a melt index (MI2), of at least 3.0 g/10 min to at most 5.5 g/10 min as measured according to ISO 1133, condition D, at 190° C. and under a load of 2.16 kg, and a density of at least 0.955 g/cm3 to at most 0.965 g/cm3 as measured according to ISO 1183 at 23° C., and a molecular weight distribution Mw/Mn which is at most 7.0, as determined by gel permeation chromatography, with Mw being the weight-average molecular weight and Mn being the number-average molecular weight; and wherein said polyethylene fraction A has a high load melt index (HLMI), as measured according to ISO 1133:1997 condition G at 190° C. and under a load of 21.6 kg, of at least 10.5 and a melt index (MI2) of at least 0.5 g/10 min to at most 1.Type: ApplicationFiled: November 12, 2018Publication date: December 10, 2020Inventors: David Ribour, Alain Standaert, Armelle Sigwald, Aurélien Vantomme
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Publication number: 20200291207Abstract: The invention relates to a composition comprising a rubber-modified monovinylaromatic polymer comprising: 70 wt % or more of a monovinylaromatic polymer matrix, from 2 to 12 wt % of at least one rubber, and from 0.1 to 3.4 wt % of metallocene-catalyzed poly-alpha-olefins (mPAO) all based on the total weight of the rubber-modified monovinylaromatic polymer, with the mPAO having a kinematic viscosity of at least 950 mm2/s at 40° C. and at most 2,000 mm2/s at 40° C. as measured according to ISO 3104. The invention also relates to articles made from such composition and to the process to produce said composition and said articles.Type: ApplicationFiled: August 31, 2017Publication date: September 17, 2020Inventors: Aurélien Vantomme, Serge Eon, Vinciane Jonnieaux, Armelle Sigwald
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Publication number: 20200190308Abstract: The invention relates to compositions comprising a rubber-modified monovinylaromatic polymer comprising 70 wt % or more of a monovinylaromatic polymer matrix, based on the total weight of the rubber-modified monovinylaromatic polymer, and from 0.5 to 20 wt % of at least one rubber, and from 0.1 to 4.8 wt % of at least one biopolymer based on the total weight of the rubber-modified monovinylaromatic polymer wherein at least one biopolymer is selected from poly(?-hydroxyacids) and/or polyhydroxyalkanoates, and any combination thereof; and from 0.1 to 6.0 wt % of a plasticizer being selected from a mineral oil and/or polyisobutene as based on the total weight of the composition. The invention also relates to articles made from these compositions.Type: ApplicationFiled: September 5, 2017Publication date: June 18, 2020Inventors: Jérôme Thierry-Mieg, Serge Eon, Vinciane Jonnieaux, Armelle Sigwald, Aurélien Vantomme, Mazad Khan-Jeaudeen, Elodie Perche, Antonio Guinovart
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Publication number: 20200062944Abstract: The invention relates to a process and an installation to produce a monovinylaromatic polymer (3) comprising post-consumer recycled polystyrene (PCR-PS) wherein the process comprises the steps of mixing the PCR-PS (5) and the monovinylaromatic monomer (7) within a dissolver (9) to dissolve the PCR-PS (5) in the monovinylaromatic monomer (7) so as to produce a polymerization mixture (13); and a step of filtering the polymerization mixture (13) that includes continuously redirecting at least a part of the stream of the filtered polymerization mixture (17) back to the dissolver (9) and mixing it with the polymerization mixture (13) so as to continuously reduce the content of insoluble material in the polymerization mixture (13) contained in the dissolver (9).Type: ApplicationFiled: February 28, 2018Publication date: February 27, 2020Inventors: Jose-Maria Pere, Antonio Guinovart, Armelle Sigwald, Laetitia Urbanczyk, Martine Slawinski, Pascal Charlier, Elodie Perche, Serge Eon, Thierry Marcoux, Matthieu Adam-Berret
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Patent number: 10053522Abstract: A metallocene-catalyzed polyethylene resin having a multimodal molecular weight and composition distribution, comprising from 45% by weight to 75% by weight of a low density fraction, said fraction having a density below or equal to 918 g/cm3 as measured following the method of standard test ISO 1183 at a temperature of 23° C., wherein the density of the polyethylene resin is from 0.920 to 0.945 g/cm3, wherein the Mw/Mn of the polyethylene is of from 2.8 to 6, wherein the melt index MI2 of the polyethylene resin of from 0.1 to 5 g/10 min measured following the method of standard test ISO 1133 Condition D at a temperature of 190° C. and under a load of 2.16 kg; and wherein the composition distribution breadth index (CDBI) of the polyethylene resin is below 70%, as analyzed by quench TREF (temperature rising elution fractionation) analysis.Type: GrantFiled: July 6, 2012Date of Patent: August 21, 2018Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Pierre Bernard, Jacques Michel, Christopher Willocq, Armelle Sigwald
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Publication number: 20140127427Abstract: A metallocene-catalyzed polyethylene resin having a multimodal molecular weight and composition distribution, comprising from 45% by weight to 75% by weight of a low density fraction, said fraction having a density below or equal to 918 g/cm3 as measured following the method of standard test ISO 1183 at a temperature of 23° C., wherein the density of the polyethylene resin is from 0.920 to 0.945 g/cm3, wherein the Mw/Mn of the polyethylene is of from 2.8 to 6, wherein the melt index MI2 of the polyethylene resin of from 0.1 to 5 g/10 min measured following the method of standard test ISO 1133 Condition D at a temperature of 190° C. and under a load of 2.16 kg; and wherein the composition distribution breadth index (CDBI) of the polyethylene resin is below 70%, as analyzed by quench TREF (temperature rising elution fractionation) analysis.Type: ApplicationFiled: July 6, 2012Publication date: May 8, 2014Inventors: Aurelien Vantomme, Pierre Bernard, Jacques Michel, Christopher Willocq, Armelle Sigwald