Patents by Inventor Arnaud Cadix
Arnaud Cadix has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Publication number: 20240182778Abstract: A viscoelastic surfactant formulation may include a zwitterionic surfactant with a general formula (I): where A is a C or SO, E1 is a linear or branched, saturated or unsaturated hydrocarbon chain having 1 to 4 carbon atoms, R1 and R2 are selected from alkyl groups of from 1 to about 4 carbon atoms, and R3 is a linear or branched, saturated or unsaturated alkyl chain having less than 22 carbon atoms or is —(CH2)n NHC(O)—R4, where R4 is a linear or branched, saturated or unsaturated alkyl chain having less than 22 carbon atoms and n ranges from 1 to 6; a synergistic co-surfactant containing a primary, secondary, or tertiary amine; amido group; amine oxide; or combinations thereof; and at least one miscible solvent.Type: ApplicationFiled: November 22, 2023Publication date: June 6, 2024Applicant: ENERGY SOLUTIONS (US) LLCInventors: Ahmed I. Rabie, Arnaud Cadix, Rose Ndong, Pascal Herve, Qi Qu, Jian Zhou
-
Patent number: 11912934Abstract: The instant invention friction reducer formulation comprising friction reducer polymers such as PAM within the dispersed phase of an inverse emulsion containing a composition C which comprises a mixture of: —at least an alkanolamide emulsifier; and —a block copolymer comprising: —a hydrophilic block A comprising units deriving from a mono-alpha-ethylenically-unsaturated monomers; and —a hydrophobic block B.Type: GrantFiled: March 11, 2020Date of Patent: February 27, 2024Assignee: RHODIA OPERATIONSInventors: Helène Martin, Patrick Moreau, Arnaud Cadix
-
Patent number: 11787992Abstract: This invention relates to the field of techniques for treating subterranean formations with gels during an oil or gas exploration or production operation, i.e., during drilling, completion, or hydraulic fracking processes. The invention relates in particular to a system making it possible to limit or even inhibit the phenomena known as loss of fluids (wager and/or gas) in an underground formation, particularly in a zone where the temperature is high. More particularly, the invention relates to a suspension (S) comprising: an aqueous phase containing salts; and within said aqueous phase, particles (p) based on associative polymers (P).Type: GrantFiled: March 3, 2020Date of Patent: October 17, 2023Assignee: ENERGY SOLUTIONS (US) LLCInventors: Arnaud Cadix, David James Wilson
-
Patent number: 11753493Abstract: The present invention relates to the preparation of polymers that are of use in particular as a rheology agent, and are suitable for use in very concentrated saline media, which comprises a step of micellar radical polymerization in which are brought into contact, in an aqueous medium: —hydrophilic monomers; —hydrophobic monomers in the form of a micellar solution, containing micelles comprising these hydrophobic monomers; —a radical polymerization initiator; and —preferably an agent for controlling radical polymerization, wherein said micelles comprise at least one surfactant of amphoteric nature. The polymers obtained according to the invention are in particular of use for enhanced oil recovery.Type: GrantFiled: September 15, 2020Date of Patent: September 12, 2023Assignee: ENERGY SOLUTIONS (US) LLCInventors: David James Wilson, Mikel Morvan, Max Chabert, Arnaud Cadix
-
Patent number: 11649390Abstract: The present invention relates to the use of sequential copolymers (P), comprising at least one chain (C) capable of being obtained by micellar polymerization, for keeping solid particles (p) in suspension in a fluid (F) where said chain (C) is soluble.Type: GrantFiled: June 3, 2016Date of Patent: May 16, 2023Assignee: Energy Solutions (US) LLCInventors: Arnaud Cadix, David James Wilson, Lingjuan Shen
-
Patent number: 11548956Abstract: The present invention relates to the field of oil extraction. More specifically, it relates to a particular polymerization process, which provides access to formulations of polymers that may be used in particular for modifying rheology and fluid loss control during extraction operations and that have a better heat stability.Type: GrantFiled: April 10, 2019Date of Patent: January 10, 2023Assignee: RHODIA OPERATIONSInventors: Arnaud Cadix, David James Wilson
-
Patent number: 11485901Abstract: Polymeric systems useful for maintaining particle dispersions for extended periods of time.Type: GrantFiled: November 28, 2017Date of Patent: November 1, 2022Assignee: RHODIA OPERATIONSInventors: Lingjuan Shen, Qi Qu, Jian Zhou, Arnaud Cadix, Ruela Pabalan, Subramanian Kesavan, David James Wilson
-
Patent number: 11427747Abstract: The present invention relates to the use of a sequenced polymer as an agent for monitoring the filtrate in a fluid injected under pressure into an oil rock, wherein the fluid comprises solid particles and/or is brought into contact with solid particles within the oil rock after being injected, the polymer comprising at least three blocks, including: at least one first block which is adsorbed, preferably irreversibly, onto at least some of the particles (p); a second block (B) having a composition other than that of the first and a mean molecular weight of more than 10,000 g/mol, and which is soluble in the fluid (F); and at least one third block of type (A) or type (B).Type: GrantFiled: September 15, 2020Date of Patent: August 30, 2022Assignee: RHODIA OPERATIONSInventors: Arnaud Cadix, David James Wilson
-
Publication number: 20220177774Abstract: The instant invention friction reducer formulation comprising friction reducer polymers such as PAM within the dispersed phase of an inverse emulsion containing a composition C which comprises a mixture of: —at least an alkanolamide emulsifier; and —a block copolymer comprising: —a hydrophilic block A comprising units deriving from a mono-alpha-ethylenically-unsaturated monomers; and —a hydrophobic block B.Type: ApplicationFiled: March 11, 2020Publication date: June 9, 2022Inventors: Helène MARTIN, Patrick MOREAU, Arnaud CADIX
-
Publication number: 20220169911Abstract: This invention relates to the field of techniques for treating subterranean formations with gels during an oil or gas exploration or production operation, i.e., during drilling, completion, or hydraulic fracking processes. The invention relates in particular to a system making it possible to limit or even inhibit the phenomena known as loss of fluids (wager and/or gas) in an underground formation, particularly in a zone where the temperature is high. More particularly, the invention relates to a suspension (S) comprising: an aqueous phase containing salts; and within said aqueous phase, particles (p) based on associative polymers (P).Type: ApplicationFiled: March 3, 2020Publication date: June 2, 2022Applicant: RHODIA OPERATIONSInventors: Arnaud Cadix, David James Wilson
-
Patent number: 11345845Abstract: The present invention relates to the use of a sequenced polymer as an agent for monitoring the filtrate and the rheology of a fluid injected under pressure into an oil rock, wherein the fluid comprises solid particles and/or is brought into contact with solid particles within the oil rock after being injected, the polymer comprising: a first block which is adsorbed onto at least some of the particles; and a second block having a composition other than that of the first block and a mean molecular weight of more than 10,000 g/mol, for example more than 100,000 g/mol, and which is soluble in the fluid.Type: GrantFiled: May 12, 2020Date of Patent: May 31, 2022Assignee: RHODIA OPERATIONSInventors: Arnaud Cadix, David James Wilson
-
Patent number: 11312894Abstract: The present invention relates to the use of a combination of block polymers and particular compositions in a fluid injected under pressure into an oil-bearing rock, where: the fluid comprises solid particles and/or is brought into contact with solid particles within the oil-bearing rock following the injection thereof, the combination comprises (i) a polymer comprising: —a first block that is adsorbed on at least a portion of the particles; and —a second block, having a composition different from that of the first, and having a weight-average molecular weight of greater than 10 000 g/mol, for example greater than 100 000 g/mol, and that is soluble in the fluid; (ii) particles suitable for providing a gas barrier effect, preferably a latex and/or silica particles.Type: GrantFiled: March 30, 2018Date of Patent: April 26, 2022Assignee: RHODIA OPERATIONSInventor: Arnaud Cadix
-
Publication number: 20220010086Abstract: Modification of the rheology of a liquid medium, aqueous or nonaqueous, with polymers in the form of specific particles obtained by grinding (micronizing) a porous macrogel, itself prepared by a process comprising a radical polymerization step which comprises reacting in the presence of pore formers monomers containing monomers bearing at least two ethylenic unsaturations, typically in combination with monomers bearing a single ethylenic unsaturation; a polymerization initiator; and optionally a polymerization control agent. These polymer particles keep other particles in suspension within the liquid medium, and also the stabilized suspensions are obtained.Type: ApplicationFiled: November 13, 2019Publication date: January 13, 2022Applicant: RHODIA OPERATIONSInventors: Arnaud Cadix, David James Wilson
-
Patent number: 11198809Abstract: The present invention relates to the use of amphiphilic sequenced copolymers as an agent for controlling the filtrate in a fluid (F) injected under pressure into an underground formation, comprising—at least one chain (C) soluble in the fluid (F); and—at least one block (B) that is insoluble in the fluid (F).Type: GrantFiled: June 2, 2016Date of Patent: December 14, 2021Assignee: RHODIA OPERATIONSInventors: Arnaud Cadix, David James Wilson
-
Patent number: 11168026Abstract: The present invention relates to the use of a block polymer as fluid loss control agent in a fluid injected under pressure into an oil-bearing rock, where: the fluid comprises solid particles and/or is brought into contact with solid particles within the oil-bearing rock subsequent to its injection, the polymer comprises: a first block which is adsorbed on at least a portion of the particles; and a second block with a composition distinct from that of the first and with a weight-average molecular weight of greater than 10 000 g/mol, for example of greater than 100 000 g/mol, and which is soluble in the fluid.Type: GrantFiled: October 3, 2014Date of Patent: November 9, 2021Assignee: RHODIA OPERATIONSInventors: Arnaud Cadix, David James Wilson
-
Publication number: 20210115165Abstract: The present invention relates to the field of oil extraction. More specifically, it relates to a particular polymerization process, which provides access to formulations of polymers that may be used in particular for modifying rheology and fluid loss control during extraction operations and that have a better heat stability.Type: ApplicationFiled: April 10, 2019Publication date: April 22, 2021Inventors: Arnaud CADIX, David James WILSON
-
Publication number: 20210095180Abstract: The present invention relates to the use of a combination of block polymers and particular compositions in a fluid injected under pressure into an oil-bearing rock, where: the fluid comprises solid particles and/or is brought into contact with solid particles within the oil-bearing rock following the injection thereof, the combination comprises (i) a polymer comprising: —a first block that is adsorbed on at least a portion of the particles; and —a second block, having a composition different from that of the first, and having a weight-average molecular weight of greater than 10 000 g/mol, for example greater than 100 000 g/mol, and that is soluble in the fluid; (ii) particles suitable for providing a gas barrier effect, preferably a latex and/or silica particles.Type: ApplicationFiled: March 30, 2018Publication date: April 1, 2021Inventor: Arnaud CADIX
-
Publication number: 20200407480Abstract: The present invention relates to the preparation of polymers that are of use in particular as a rheology agent, and are suitable for use in very concentrated saline media, which comprises a step of micellar radical polymerization in which are brought into contact, in an aqueous medium: —hydrophilic monomers; —hydrophobic monomers in the form of a micellar solution, containing micelles comprising these hydrophobic monomers; —a radical polymerization initiator; and —preferably an agent for controlling radical polymerization, wherein said micelles comprise at least one surfactant of amphoteric nature. The polymers obtained according to the invention are in particular of use for enhanced oil recovery.Type: ApplicationFiled: September 15, 2020Publication date: December 31, 2020Inventors: David James WILSON, Mikel MORVAN, Max CHABERT, Arnaud CADIX
-
Publication number: 20200407624Abstract: The present invention relates to the use of a sequenced polymer as an agent for monitoring the filtrate in a fluid injected under pressure into an oil rock, wherein the fluid comprises solid particles and/or is brought into contact with solid particles within the oil rock after being injected, the polymer comprising at least three blocks, including: at least one first block which is adsorbed, preferably irreversibly, onto at least some of the particles (p); a second block (B) having a composition other than that of the first and a mean molecular weight of more than 10,000 g/mol, and which is soluble in the fluid (F); and at least one third block of type (A) or type (B).Type: ApplicationFiled: September 15, 2020Publication date: December 31, 2020Inventors: Arnaud CADIX, David James WILSON
-
Patent number: 10815413Abstract: The present invention relates to the formation of a gel within a medium M, in particular within an underground formation, which comprises the following steps: (EI) a basic compound C is added to a fluid latex L comprising dispersed particles of a polymer P, bearing ester side functions, said basic compound C being added in an amount suitable for hydrolysing at least one part of said ester side functions into carboxylic acid and/or alcohol functions, as a result of which a modified latex L? is obtained, the viscosity of which gradually increases with time from the addition of the compound C up to the formation of a gel; then (E2) the resulting modified latex is introduced into the medium M before the formation of the gel and the gel is left to form within the medium M.Type: GrantFiled: April 18, 2013Date of Patent: October 27, 2020Assignee: RHODIA OPERATIONSInventors: Arnaud Cadix, Chi-Thanh Vuong