Patents by Inventor Asao Harashima
Asao Harashima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8835555Abstract: The present invention has an objective to easily obtain an emulsion exhibiting superior storage stability, and in particular, an emulsion of a polyorganosiloxane. The present invention provides a method for producing an emulsion characterized by obtaining an emulsion by emulsifying a mixture of an oil and a surfactant, obtained by synthesizing the surfactant in the oil. In particular, the method is suitably used for the preparation of an emulsion of an organopolysiloxane (A) which is usually difficult to be stably emulsified. A silicone-based surfactant (B), and in particular, a silicone-based surfactant having a small degree of polymerization of a siloxane chain such as a trisiloxane is synthesized in an oil. Thereby, an emulsion exhibiting superior storage stability can be produced.Type: GrantFiled: December 21, 2009Date of Patent: September 16, 2014Assignee: Dow Corning Toray Co. Ltd.Inventors: Kazuhiko Kojima, Tsutomu Naganawa, Asao Harashima
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Publication number: 20120035275Abstract: The present invention has objectives to provide an emulsion suitable as a cosmetic raw material and to easily obtain the aforementioned emulsion of organopolysiloxane exhibiting superior storage stability. The present invention provides an emulsion comprising (A) an organopolysiloxane, (B) a methyl polyglycerol-modified silicone-based surfactant having a specified structure, and (C) an aqueous medium, and provides a method for producing an emulsion characterized by obtaining an emulsion by emulsifying a mixture of (A) a organopolysiloxane and (B) a silicone-based surfactant, which is obtained by synthesizing the silicone-based surfactant of component (B) in the component (A).Type: ApplicationFiled: December 21, 2009Publication date: February 9, 2012Inventors: Kazuhiko Kojima, Tsutomu Naganawa, Asao Harashima, Tadashi Okawa
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Publication number: 20110257274Abstract: The present invention has an objective to easily obtain an emulsion exhibiting superior storage stability, and in particular, an emulsion of a polyorganosiloxane. The present invention provides a method for producing an emulsion characterized by obtaining an emulsion by emulsifying a mixture of an oil and a surfactant, obtained by synthesizing the surfactant in the oil. In particular, the method is suitably used for the preparation of an emulsion of an organopolysiloxane (A) which is usually difficult to be stably emulsified. A silicone-based surfactant (B), and in particular, a silicone-based surfactant having a small degree of polymerization of a siloxane chain such as a trisiloxane is synthesized in an oil. Thereby, an emulsion exhibiting superior storage stability can be produced.Type: ApplicationFiled: December 21, 2009Publication date: October 20, 2011Inventors: Kazuhiko Kojima, Tsutomu Naganawa, Asao Harashima
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Patent number: 5929163Abstract: A silicone gel composition that contains(a) a silicone oil,(b) a polyoxyalkylene group-containing organopolysiloxane with the formula ##STR1## wherein R is the methyl or phenyl group; A is the methyl group, phenyl group, or polyoxyalkylene groups with the formula--C.sub.3 H.sub.6 O(C.sub.2 H.sub.4 O).sub.a (C.sub.3 H.sub.6 O).sub.b R'wherein R' is the hydrogen atom, an acyl group, or alkyl groups having 1 to 4 carbon atoms, a is an integer with a value of 5 to 50, and b is an integer with a value of 5 to 50;m is an integer with a value of 50 to 1,000; andn is an integer with a value of 1 to 40,and (c) water.Type: GrantFiled: April 29, 1993Date of Patent: July 27, 1999Assignee: Dow Corning Toray Silicone Co., LTD.Inventor: Asao Harashima
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Patent number: 5837793Abstract: There is disclosed a silicone rubber powder prepared from a curable silicone composition, said powder comprising a polyorganosiloxane drain having at least one silicon-bonded polyoxyalkylene group of the formula--R.sup.1 (OR.sup.2).sub.m OR.sup.3wherein R.sup.1 is an alkylene radical, R.sup.2 is an alkylene radical, R.sup.3 is selected from the group consisting of hydrogen and alkyl radicals and m is an integer having a value of 2 to 100. The rubber powder is preferably prepared by curing the above silicone composition to form a cured silicone rubber and then pulverizing the silicone rubber.Type: GrantFiled: March 17, 1997Date of Patent: November 17, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Asao Harashima, Yoshitsugu Morita, Ryuji Tachibana
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Patent number: 5696192Abstract: A polyoxyalkylene-modified organopolysiloxane that generates almost no odor with the passage of time, and a method for preparation of the polyoxyalkylene-modified organopolysiloxane. This organopolysiloxane bears polyoxyalkylene bonded to silicon across alkylene, and contains 5-1,000 ppm by weight of an antioxidant. It also has a peroxide value not exceeding 5 meq/kg, and a total content of aldehyde plus ketone not exceeding 100 ppm.Type: GrantFiled: November 15, 1996Date of Patent: December 9, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventor: Asao Harashima
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Patent number: 5628989Abstract: Antiperspirant/deodorants contain 5-90 wt % of spheroid silicone rubber powders with average particle sizes of 0.1-200 .mu.m and JIS A hardness of the silicone rubber forming said powder is 35-80. They spread well, are smooth, and have a dry feel when used.Type: GrantFiled: June 12, 1995Date of Patent: May 13, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Asao Harashima, Yoshitsugu Morita, Ryuji Tachibana
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Patent number: 5328683Abstract: A water repellent powdered material and a method of making the powder in which the powdered material is mixed with an organic solvent solution of a triorganosiloxysilicic acid having the formula (R.sub.3 SiO.sub.1/2).sub.2 nSiO.sub.2 in which R is a monovalent hydrocarbon radical such as alkyl, aryl, and alkenyl; and n is an integer having a value of one to five; with the acid being present in an amount of from 0.1 to 20 parts by weight per one hundred parts by weight of the powdered material. The powder can be used to formulate cosmetic foundations.Type: GrantFiled: July 6, 1993Date of Patent: July 12, 1994Assignee: Dow Corning Toray Silicone Co., Ltd.Inventor: Asao Harashima
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Patent number: 5320796Abstract: A method for producing powder mixtures capable of inducing an even more intimate, microhomogeneous intermixing in a heterogeneous powder composed of at least two types of powders. The method is effective even for the mixing of an aggregable powder and a nonaggregable powder. According to the method, a heterogeneous powder composed of at least two type of powders that have been preliminarily mixed by stirring is introduced into an inlet while a rotating axle is turning and is axially transported within a cylinder by a screw. As the heterogeneous powder passes between rotating disks and fixed disks, it is subjected to a highly efficient mixing by compression and shear forces due to a sliding-shear action exerted between depressions and elevations installed on the opposing surfaces of the rotating disks and fixed disks. The mixture passes in sequence through multiple stages of the rotating and fixed disks. A powder mixture, which has been microhomogeneously interdispersed, is discharged from the outlet.Type: GrantFiled: April 29, 1993Date of Patent: June 14, 1994Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Asao Harashima, Kaoru Kunimatsu, Atsushi Sasaki, Ryuji Tachibana
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Patent number: 5045584Abstract: A polish including a film forming wax material and an organopolysiloxane elastomer. The elastomer is in the form of particles mixed with the film forming wax. The particles are spherical and have an average diameter of from about 0.3 um to about 30 um. The polish contains at least one additive selected from the group consisting of organic solvents, silicone oils, and surfactants. The film forming wax material may be one of carnauba wax, montan wax, candelilla wax, ceresin wax, paraffin waxes, and beeswax.Type: GrantFiled: November 3, 1989Date of Patent: September 3, 1991Assignee: Toray Silicone Company, LimitedInventors: Atushi Sasaki, Asao Harashima, Keiji Yoshida
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Patent number: 4980167Abstract: The cosmetic composition of the present invention exhibits excellent lubricancy since it contains silicone rubber powder containing 0.50-80 wt % of silicone oil. When it is coated on the skin, no foreign sensations or irritations are reported. A smooth and moist texture is obtained.Type: GrantFiled: January 24, 1990Date of Patent: December 25, 1990Assignee: Dow Corning Toray Silicone Company, Ltd.Inventors: Asao Harashima, Keiji Yoshida
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Patent number: 4517150Abstract: What is disclosed is a method of producing molded polyurethane articles by a reaction injection molding process which includes mixing one or more polyols, polyisocyanates and catalysts with an organopolysiloxane containing at least one --COOA group, wherein A is an alkali metal, and molding the curing the mixture.Type: GrantFiled: December 23, 1983Date of Patent: May 14, 1985Assignee: Toray Silicone Company, Ltd.Inventors: Asao Harashima, Takashi Nakamura, Keiichi Kishimoto
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Patent number: 4450152Abstract: A composition, used to groom hair, consisting essentially of an organopolysiloxane having at least one alkylamino substituent and at least one substituent selected from the group consisting of oxyalkylene, polyoxyalkylene, and hydroxyalkyl groups, said organopolysiloxane having a viscosity range of 1 to 100,000 centistokes at 25.degree. C., is disclosed.Type: GrantFiled: June 10, 1982Date of Patent: May 22, 1984Assignee: Toray Silicone Company, Ltd.Inventors: Isao Ona, Asao Harashima, Masaru Ozaki, Yoichiro Taki