Abstract: A process for synthesizing a Mn4+ doped phosphor includes contacting a precursor of formula I, Ax(M1?z,Mnz)Fy??I at an elevated temperature with a fluorine-containing oxidizing agent in gaseous form to form the Mn4+ doped phosphor; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and 0.03?z?0.10.

Abstract: A process for fabricating a LED lighting apparatus includes disposing a composite coating on a surface of a LED chip. The composite coating comprises a first composite layer having a manganese doped phosphor of formula I and a first binder, and a second composite layer comprising a second phosphor composition and a second binder. The first binder, the second binder or both include a poly(meth)acrylate. Ax[MFy]:Mn4+??(I) wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7.

Abstract: A process for synthesizing a Mn4+ doped phosphor includes contacting a precursor of formula I, at an elevated temperature with a fluorine-containing oxidizing agent in gaseous form to form the color stable Mn4+ doped phosphor; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and amount of Mn ranges from about 0.9 wt % to about 4 wt %, based on total weight.

Abstract: Heavily phosphor loaded LED packages having higher stability and a method for increasing the stability of heavily phosphor loaded LED packages. The silicone content of the packages is increased by decreasing the amount of one phosphor of the blend or by increasing the thickness of the silicone phosphor blend layer.

Abstract: Heavily phosphor loaded LED packages having higher stability and a method for increasing the stability of heavily phosphor loaded LED packages. A silicone overlayer is provided on the phosphor silicone blend layer.

Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+??I wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.

Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+ wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.

Abstract: A process for synthesizing a color stable Mn4+ doped phosphor includes contacting a precursor of formula I, in gaseous form at an elevated temperature with a fluorine-containing oxidizing agent to form the color stable Mn4+ doped phosphor Ax[MFy]:Mn4+??I wherein A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.

Abstract: A color stable Mn4+ doped phosphor of formula I, Ax[MFy]:Mn4+??I wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and wherein % intensity loss of the phosphor after exposure to light flux of at least 80 w/cm2 at a temperature of at least 50° C. for at least 21 hours is ?4%.

Abstract: Embodiments of a lighting apparatus with a light source using one or more light emitting diodes (LEDs) to generate light. In one embodiment, the lighting apparatus comprises a light diffusing assembly that generates an optical intensity profile consistent with incandescent lamps. The light diffusing assembly comprises an envelope and a reflector element having frusto-conical member and an aperture element disposed therein. The lighting apparatus can also comprise a heat dissipating assembly with a plurality of heat dissipating elements disposed radially about the envelope. In one example, the heat dissipating elements are spaced apart from the envelope to promote convective heat dissipation.

Abstract: Embodiments of a lighting apparatus with a light source using one or more light emitting diodes (LEDs) to generate light. In one embodiment, the lighting apparatus comprises a light diffusing assembly that generates an optical intensity profile consistent with incandescent lamps. The light diffusing assembly comprises an envelope and a reflector element having frusto-conical member and an aperture element disposed therein. The lighting apparatus can also comprise a heat dissipating assembly with a plurality of heat dissipating elements disposed annularly about the envelope. In one example, the heat dissipating elements are spaced apart from the envelope to promote convective heat dissipation.

Abstract: A light emitting apparatus is provided. The light emitting apparatus includes a light transmissive envelope, a light source being in thermal communication with a heat sink, and a plurality of heat fins in thermal communication with the heat sink and extending in a direction such that the heat fins are adjacent the light transmissive envelope. The plurality of heat fins comprises a carbon nanotube filled polymer composite.

Abstract: Embodiments of a lamp are described that use light emitting diodes (LEDs) to generate an intensity distribution that is consistent with incandescent lamps. In one embodiment, the lamp comprises a diffuser having a spheroid geometry with a light reflective upper portion and a light transmissive lower portion. The lamp also includes a thermal management system with a plurality of optically active heat dissipating elements disposed annularly about the diffuser. In one example, the heat dissipating elements are spaced apart from the diffuser to promote convective heat dissipation.

Abstract: The disclosure provides a light-transmissive glass halogen filament tube with a filament light source having a coil concentricity ratio of not greater than 20% disposed therein, the filament tube having a multi-layer optical interference coating deposited on the outer surface thereof that transmits visible radiation from about 400-750 nm and reflects infra red radiation from about 800-2500 nm back to the filament for re-absorption, the coated filament tube exhibiting an LPW gain of at least 26%.

Abstract: Embodiments of a lighting apparatus with a light source using one or more light emitting diodes (LEDs) to generate light. In one embodiment, the lighting apparatus comprises a light diffusing assembly that generates an optical intensity profile consistent with incandescent lamps. The light diffusing assembly comprises an envelope and a reflector element having frusto-conical member and an aperture element disposed therein. The lighting apparatus can also comprise a heat dissipating assembly with a plurality of heat dissipating elements disposed annularly about the envelope. In one example, the heat dissipating elements are spaced apart from the envelope to promote convective heat dissipation.

Abstract: Disclosed herein are optical interference multilayer coatings employing a high refractive index material comprising a NbTaZr oxide. Such coatings provide enhanced retention of favorable optical and physical properties at high temperatures. Also disclosed herein are lamps comprising a light-transmissive envelope, at least a portion of the surface of the light-transmissive envelope being provided with the optical interference multilayer coating noted above. Such coatings, when used on lamps, may advantageously offer improved energy efficiencies for such lamps.

Abstract: A light emitting apparatus is provided. The light emitting apparatus includes a light transmissive envelope, a light source being in thermal communication with a heat sink, and a plurality of heat fins in thermal communication with the heat sink and extending in a direction such that the heat tins are adjacent the light transmissive envelope. The plurality of heat fins comprises a carbon nanotube filled polymer composite.

Abstract: The disclosure provides a light-transmissive glass halogen filament tube with a filament light source having a coil concentricity ratio of not greater than 20% disposed therein, the filament tube having a multi-layer optical interference coating deposited on the outer surface thereof that transmits visible radiation from about 400-750 nm and reflects infra red radiation from about 800-2500 nm back to the filament for re-absorption, the coated filament tube exhibiting an LPW gain of at least 26%.

Abstract: Disclosed herein are optical interference multilayer coatings employing a high refractive index material comprising a NbTaZr oxide. Such coatings provide enhanced retention of favorable optical and physical properties at high temperatures. Also disclosed herein are lamps comprising a light-transmissive envelope, at least a portion of the surface of the light-transmissive envelope being provided with the optical interference multilayer coating noted above. Such coatings, when used on lamps, may advantageously offer improved energy efficiencies for such lamps.