Patents by Inventor Aya Shirai

Aya Shirai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20170168407
    Abstract: The production process of the present invention includes: a first step of heating a dispersion containing an aqueous medium and a binder resin containing a crystalline resin to a temperature higher than or equal to the melting point of the crystalline resin in a step of aggregating and fusing a fine particle of the binder resin containing the crystalline resin to produce a toner base particle; a second step of cooling the dispersion having been heated in the first step and having a temperature higher than the recrystallization temperature Rc of the crystalline resin to a temperature lower than Rc at a temperature-lowering rate of 1° C./min or higher; and a third step of maintaining the dispersion having been cooled in the second step at a temperature higher than or equal to Rc?25° C. and lower than or equal to Rc?5° C. for 30 minutes or longer.
    Type: Application
    Filed: December 6, 2016
    Publication date: June 15, 2017
    Inventors: Junya ONISHI, Shiro HIRANO, Noboru UEDA, Kouji SUGAMA, Aya SHIRAI
  • Patent number: 9625843
    Abstract: An electrostatic image developing toner includes toner particles that contain coloring particles containing a binder resin, a coloring agent and a releasing agent. The binder resin includes an amorphous resin and a crystalline polyester resin. The toner satisfies Relations (1) and (2). ?H1 is the amount of heat absorption based on a melting peak of the crystalline polyester resin in a first heating step. ?H2 is the amount of heat absorption based on a melting peak of the crystalline polyester resin in a second heating step. ?H0 is the value of the amount of heat absorption based on a melting peak of the crystalline polyester resin in the second heating step, multiplied by the ratio of the crystalline polyester introduced in the electrostatic image developing toner. 0.43<?H1/?H0<0.95??Relation (1): 0.45<?H2/?H1<1.
    Type: Grant
    Filed: October 14, 2015
    Date of Patent: April 18, 2017
    Assignee: KONICA MINOLTA, INC.
    Inventors: Aya Shirai, Tatsuya Nagase, Junya Onishi, Tatsuya Fujisaki, Naoya Tonegawa, Junichi Furukawa
  • Publication number: 20170045834
    Abstract: Provided is a toner for developing electrostatic images containing a toner particle. The toner particle contains a binder resin and a release agent. The binder resin contains a vinyl resin component and a crystalline polyester resin component. The vinyl resin component has a structural unit derived from an alkyl (meth)acrylate monomer represented by Formula (1): H2C?CR1—COOR2 ??Formula (1): In Formula (1), R1 represents a hydrogen atom or a methyl group, and R2 represents an alkyl group having 8 to 22 carbon atoms. The crystalline polyester resin component satisfies Formula (2): 5?|Cacid?Calcohol|?12 ??Formula (2): In Formula (2), Calcohol represents the number of carbon atoms of the main chain of a structural unit derived from a polyhydric alcohol and Cacid represents the number of carbon atoms of the main chain of a structural unit derived from a polyvalent carboxylic acid.
    Type: Application
    Filed: July 14, 2016
    Publication date: February 16, 2017
    Inventors: Aya SHIRAI, Shiro HIRANO, Junya ONISHI
  • Publication number: 20170038697
    Abstract: Provided is a toner for developing electrostatic images containing toner particles. The toner particles contain a crystalline resin and an amorphous resin. The amorphous resin contains an amorphous vinyl resin component containing a polymer of monomers having a structure represented by formula (1). The content of a structural unit derived from the monomers in the toner particles is within a range of 2.4 to 13.5 mass %. H2C?CR1—COOR2 ??(1) In formula (1), R1 represents a hydrogen atom or a methyl group and R2 represents a branched alkyl group having a carbon number of 8 or more.
    Type: Application
    Filed: July 19, 2016
    Publication date: February 9, 2017
    Inventors: Junya ONISHI, Shiro Hirano, Aya Shirai
  • Publication number: 20160109818
    Abstract: An electrostatic image developing toner includes toner particles that contain coloring particles containing a binder resin, a coloring agent and a releasing agent. The binder resin includes an amorphous resin and a crystalline polyester resin. The toner satisfies Relations (1) and (2). ?H1 is the amount of heat absorption based on a melting peak of the crystalline polyester resin in a first heating step. ?H2 is the amount of heat absorption based on a melting peak of the crystalline polyester resin in a second heating step. ?H0 is the value of the amount of heat absorption based on a melting peak of the crystalline polyester resin in the second heating step, multiplied by the ratio of the crystalline polyester introduced in the electrostatic image developing toner. 0.43<?H1/?H0<0.95??Relation (1): 0.45<?H2/?H1<1.
    Type: Application
    Filed: October 14, 2015
    Publication date: April 21, 2016
    Inventors: Aya SHIRAI, Tatsuya NAGASE, Junya ONISHI, Tatsuya FUJISAKI, Naoya TONEGAWA, Junichi FURUKAWA
  • Patent number: 9316937
    Abstract: Provided is a toner for electrostatic image development that has good low-temperature fixability, also has long-term heat-resistant storage stability and can form an image with unevenness in gloss suppressed. The toner for electrostatic image development includes toner particles. The toner particles have a domain-matrix structure in which a first domain phase including a crystalline polyester resin A and a second domain phase including a crystalline polyester resin B are dispersed in a matrix phase including a vinyl resin. The average diameter of the first domain phase is 400 to 900 nm, and the average diameter of the second domain phase is 10 to 200 nm. The melting point of the crystalline polyester resin A and the melting point of the crystalline polyester resin B are each 95° C. or lower.
    Type: Grant
    Filed: June 23, 2014
    Date of Patent: April 19, 2016
    Assignee: KONICA MINOLTA, INC.
    Inventors: Taiki Amemiya, Kaori Matsushima, Junya Onishi, Aya Shirai, Takaki Kawamura
  • Patent number: 9256149
    Abstract: Provided is a toner for electrostatic image development having low-temperature fixability and providing stability of glossiness for various types of paper. The toner for electrostatic image development includes toner particles having a domain-matrix structure. In the domain-matrix structure, a domain phase including a crystalline polyester resin having a melting point of 40 to 90° C. and a domain phase including a vinyl resin B having a weight average molecular weight of 250,000 to 400,000 are dispersed in a matrix phase including a vinyl resin A having a weight average molecular weight of 10,000 to 50,000.
    Type: Grant
    Filed: June 9, 2014
    Date of Patent: February 9, 2016
    Assignee: KONICA MINOLTA, INC.
    Inventors: Kaori Matsushima, Masahiro Matsuoka, Aya Shirai, Takaki Kawamura, Taiki Amemiya
  • Patent number: 9256146
    Abstract: Provided is a toner for electrostatic image development, having low-temperature fixability and long-term stable charge property and also having heat-resistant storage stability. The toner for electrostatic image development includes toner particles containing a binder resin. The binder resin has a domain-matrix structure in which a crystalline polyester resin is dispersed as a domain phase in a matrix phase formed of an amorphous vinyl polymer formed using at least a vinyl-based monomer. The amorphous vinyl polymer has a carboxy group concentration of not less than 0.2 mmol/g and not more than 1.0 mmol/g, and the crystalline polyester resin has an ester group concentration of not less than 0.1 mmol/g and not more than 7.1 mmol/g.
    Type: Grant
    Filed: March 17, 2014
    Date of Patent: February 9, 2016
    Assignee: KONICA MINOLTA, INC.
    Inventors: Takaki Kawamura, Hiroshi Nagasawa, Kaori Matsushima, Masahiro Matsuoka, Aya Shirai, Taiki Amemiya
  • Publication number: 20150370188
    Abstract: A toner for developing an electrostatic image includes a toner particle. The toner particle contains a binder resin and a release agent. The binder resin contains an amorphous resin and a crystalline polyester resin. The toner satisfies the following formulae (1) and (2). In the formulae (1) and (2), Tmc (° C.) represents a melting peak temperature derived from the crystalline polyester resin and Tmw (° C.) represents a melting peak temperature derived from the release agent in a heating process in differential scanning calorimetry of the toner. Tmc>75(° C.)??Formula (1) |Tmw?Tmc|<10(° C.
    Type: Application
    Filed: May 29, 2015
    Publication date: December 24, 2015
    Inventors: Kaori MATSUSHIMA, Shiro HIRANO, Aya SHIRAI, Kouji SEKIGUCHI, Takaki KAWAMURA, Kazumi IMAE
  • Patent number: 9217942
    Abstract: Disclosed is a toner for electrostatic image development that has excellent low-temperature fixability and also has sufficient heat-resistant storage stability. The toner for electrostatic image development includes toner particles containing an amorphous resin including amorphous resins A and B and a crystalline polyester resin. The toner particles have a domain-matrix structure in which a domain phase including fine core particles of the crystalline polyester resin is dispersed in a matrix phase formed of the amorphous resin A composed of a vinyl-based polymer. The surface of the fine core particles of the crystalline polyester resin is coated with the amorphous resin B composed of a vinyl-based polymer.
    Type: Grant
    Filed: May 21, 2014
    Date of Patent: December 22, 2015
    Assignee: KONICA MINOLTA, INC.
    Inventors: Aya Shirai, Hiroshi Nagasawa, Kaori Matsushima, Masahiro Matsuoka, Takaki Kawamura, Taiki Amemiya
  • Publication number: 20150177632
    Abstract: An electrostatic image developing toner includes a toner particle having a core-shell structure including a core portion containing a first polyester resin A, and a shell layer containing a second polyester resin B, the shell layer coating the core portion, wherein the second polyester resin B has at least a meta-phenylene skeleton, and the following relational expression (1) is satisfied: relational expression (1): 0?a<b, where a represents a content rate (mass %) of a meta-phenylene skeleton in the first polyester resin A, and b represents a content rate (mass %) of the meta-phenylene skeleton in the second polyester resin B.
    Type: Application
    Filed: December 4, 2014
    Publication date: June 25, 2015
    Inventors: Kazumi IMAE, Tatsuya FUJISAKI, Kouji SUGAMA, Kaori MATSUSHIMA, Junya ONISHI, Aya SHIRAI, Takaki KAWAMURA
  • Patent number: 8993208
    Abstract: A foil transferring method employing an electrophotography is disclosed, in which a toner used for forming a foil transferring layer contains at least a vinyl based resin and a polyester based resin as a binder resin and an amount of the vinyl based resin is 50 to 95% by weight based on the total amount of the binder resin.
    Type: Grant
    Filed: April 4, 2012
    Date of Patent: March 31, 2015
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Asao Matsushima, Tatsuya Nagase, Yasuko Uchino, Aya Shirai, Ryuichi Hiramoto, Michiyo Fujita
  • Publication number: 20150017584
    Abstract: Provided is a toner for electrostatic image development that has good low-temperature fixability, also has long-term heat-resistant storage stability and can form an image with unevenness in gloss suppressed. The toner for electrostatic image development includes toner particles. The toner particles have a domain-matrix structure in which a first domain phase including a crystalline polyester resin A and a second domain phase including a crystalline polyester resin B are dispersed in a matrix phase including a vinyl resin. The average diameter of the first domain phase is 400 to 900 nm, and the average diameter of the second domain phase is 10 to 200 nm. The melting point of the crystalline polyester resin A and the melting point of the crystalline polyester resin B are each 95° C. or lower.
    Type: Application
    Filed: June 23, 2014
    Publication date: January 15, 2015
    Inventors: Taiki AMEMIYA, Kaori Matsushima, Junya Onishi, Aya Shirai, Takaki Kawamura
  • Publication number: 20140377699
    Abstract: Provided is a toner for electrostatic image development having low-temperature fixability and providing stability of glossiness for various types of paper. The toner for electrostatic image development includes toner particles having a domain-matrix structure. In the domain-matrix structure, a domain phase including a crystalline polyester resin having a melting point of 40 to 90° C. and a domain phase including a vinyl resin B having a weight average molecular weight of 250,000 to 400,000 are dispersed in a matrix phase including a vinyl resin A having a weight average molecular weight of 10,000 to 50,000.
    Type: Application
    Filed: June 9, 2014
    Publication date: December 25, 2014
    Inventors: Kaori MATSUSHIMA, Masahiro Matsuoka, Aya Shirai, Takaki Kawamura, Taiki Amemiya
  • Publication number: 20140356780
    Abstract: Provided is a toner for electrostatic image development that has low-temperature fixability and long-term stable electrification performance, also has heat-resistant storage stability, and can suppress the occurrence of unevenness in gloss. Also provided is a production process of the toner. The toner for electrostatic image development includes toner particles having a domain-matrix structure. In the toner particles, a crystalline polyester resin and an amorphous resin including an amorphous polyester segment and a polymerized vinyl segment that are chemically bonded are dispersed as domain phases in a matrix phase formed of a vinyl resin.
    Type: Application
    Filed: May 28, 2014
    Publication date: December 4, 2014
    Applicant: Konica Minolta, Inc.
    Inventors: Takaki Kawamura, Kaori Matsushima, Aya Shirai, Taiki Amemiya
  • Patent number: 8900786
    Abstract: A plurality of image parts, each having a different gloss level, are formed on the same recording material by electrophotographic technology. The plurality of gloss levels are visually recognized due to the plurality of image parts. The image forming method includes: developing electrostatic latent images on respective image carriers using a high softening point clear toner and a low softening point clear toner, to form a toner image by the high softening point clear toner and a toner image by the low softening point clear toner; transferring the toner images onto a recording material; and heat-fixing the toner image for low gloss and the toner image for high gloss transferred and formed onto the recording material, wherein a softening point Tm(a) of the high softening point clear toner and a softening point Tm(b) of the low softening point clear toner satisfy Tm(a)?Tm(b)>6° C.
    Type: Grant
    Filed: June 14, 2013
    Date of Patent: December 2, 2014
    Assignee: Konica Minolta, Inc.
    Inventors: Yoshiyasu Matsumoto, Aya Shirai, Ryuichi Hiramoto, Taiki Amemiya
  • Publication number: 20140349231
    Abstract: Disclosed is a toner for electrostatic image development that has excellent low-temperature fixability and also has sufficient heat-resistant storage stability. The toner for electrostatic image development includes toner particles containing an amorphous resin including amorphous resins A and B and a crystalline polyester resin. The toner particles have a domain-matrix structure in which a domain phase including fine core particles of the crystalline polyester resin is dispersed in a matrix phase formed of the amorphous resin A composed of a vinyl-based polymer. The surface of the fine core particles of the crystalline polyester resin is coated with the amorphous resin B composed of a vinyl-based polymer.
    Type: Application
    Filed: May 21, 2014
    Publication date: November 27, 2014
    Applicant: Konica Minolta, Inc.
    Inventors: Aya SHIRAI, Hiroshi Nagasawa, Kaori Matsushima, Masahiro Matsuoka, Takaki Kawamura, Taiki Amemiya
  • Patent number: 8867978
    Abstract: A method of forming an image comprising the steps of: forming an image on an image support to obtain an original image, and forming a gloss adjusting layer comprising a clear toner-fixed image comprising a clear toner on the original image, wherein the gloss adjusting layer comprises an aggregate of gloss adjusting units, wherein the gloss adjusting units each comprise a section where the clear toner is attached and a section where the clear toner is unattached, wherein a borderline between the section where the clear toner is attached and the section where the clear toner is unattached comprises a straight line.
    Type: Grant
    Filed: December 28, 2011
    Date of Patent: October 21, 2014
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Michiyo Fujita, Tatsuya Nagase, Asao Matsushima, Yasuko Uchino, Aya Shirai, Ryuichi Hiramoto
  • Patent number: 8867979
    Abstract: Provided are an image forming method by which an image in which arbitrary glossiness is adjusted to any section is formed, and an image forming apparatus thereof. It is a feature that an image forming method possesses the steps of forming a gloss adjusting layer possessing a gloss adjusting toner-fixed image formed with a gloss adjusting toner, on an image support, and forming a toner-fixed image obtained from a toner, on the gloss adjusting layer, wherein the gloss adjusting layer possesses an aggregate of gloss adjusting units; the gloss adjusting units each possess a section where the gloss adjusting toner is attached and another section where the gloss adjusting toner is unattached; and a borderline between the section and the another section is a straight line.
    Type: Grant
    Filed: December 29, 2011
    Date of Patent: October 21, 2014
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Michiyo Fujita, Tatsuya Nagase, Asao Matsushima, Yasuko Uchino, Aya Shirai, Ryuichi Hiramoto
  • Patent number: 8844832
    Abstract: The non-contact information recording medium is made by forming the antenna circuit and connecting it to the IC module through connection terminals at the same time. This provides a high degree of freedom of patterning of the antenna circuit. The antenna circuit is formed on a recording substrate, in which an IC module has been embedded. A foil-bonding resin layer is formed on the connection terminals of the recording substrate, with a toner containing a binder resin by an electrophotographic method. Then a conductive foil is brought into contact with the foil-bonding resin layer to bond the foil to the resin layer, to connect the antenna circuit to the connection terminals and form the antenna circuit composed of the conductive foil.
    Type: Grant
    Filed: June 26, 2012
    Date of Patent: September 30, 2014
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Yoshiyasu Matsumoto, Ryuichi Hiramoto, Aya Shirai, Asao Matsushima, Ken Ohmura