Publication number: 20050258399
Abstract: In the compound of the formula (I), where: R1, R2 are each independently, for example, H or a straight-chain or branched alkyl radical p, q are each independently 0 or 1, i.e. at the value zero, —H is present at the appropriate position instead of —F M1 is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH?CH—, —CF?CF—, —C?C—, —CH2—CH2—CO——O—,—O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(?O)CF?CF— or a single bond A1 is, for example, 1,4-phenylene R5 has the same possible definitions as specified for R1 and R2, with the exception of -M1-A1-R5, but independently of the definition of R1 and R2 X is H, F, OF3, CF3, OCF2H with the following provisos: a) at least one of p, q has to be 1 b) R1 and R2 must not at the same time be H c) R2 and X must not at the same time be H.
Type:
Application
Filed:
April 28, 2005
Publication date:
November 24, 2005
Inventors:
Wolfgang Schmidt, Rainer Wingen, Barbara Hornung
Publication number: 20050255258
Abstract: A compound of the formula (I) is described where: R1 is a) H b) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, in which b1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(?O)O—, —O—C(?O)—, —O—C(?O)—O—, —C(?O)— or —Si(CH3)2— and/or b2) one CH2 group may be replaced by —C?C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl and/or b3) one or more hydrogen atoms may be replaced by F and/or Cl c) -M1-A1-R5 R2 has the same possible definitions as specified for R1, with the exception of H, but independently of the definition of R1 and R5 R5 has the same possible definitions as specified for R1, with the exception of -M1-A1-R5, but independently of the definition of R1 and R3 M1 is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH?CH—, —CF?CF—, —C?C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(?
Type:
Application
Filed:
May 12, 2005
Publication date:
November 17, 2005
Inventors:
Wolfgang Schmidt, Rainer Wingen, Barbara Hornung
Patent number: 6958176
Abstract: Liquid crystal mixture comprising compounds of formula (I) wherein R1: is H or a linear or branched alkyl group or branched alkenyl group R2: stands for a) H or F b) a linear or branched alkyl group or a linear or branched alkenyl group c) a radical wherein R3, R4, R5, R6: are an alkyl group M1, M2: represent independently from another a single bond, —OC(?O), —C(?O)O—, —OCH2—, —NH— A: is a) a linear or branched alkan-?,?-diylgroup or alkene-?,?-diyl group b) the group —C(?Y)— wherein Y is CH-Z with Z being phenylen-1,4-diyl, optionally substituted by one to three halogenatoms, alkyl or alkyloxy groups, c) the group —CHY wherein Y is CH2-Z with Z being phenylen-1,4-diyl, optionally substituted by one to three halogenatoms, alkyl or alkyloxy groups d) a group wherein p, q are 0, 1 or 2; M3 is a single bond or —OC(?O)—, —C(?O)O—, —OCH2—, —CH2O—, —C?C—, —CH2CH2—, —CH2CH2CH2CH2— the radicals are phenylen-1,4-diyl, X is H, OH, a linear or branched alkyl or alkyloxy group, m: is 0 or 1 X and M1-(A
Type:
Grant
Filed:
August 25, 2001
Date of Patent:
October 25, 2005
Inventors:
Ji Li, Toshiaki Nonaka, Ayako Ogawa, Hans-Rolf Dübal, Barbara Hornung, Wolfgang Schmidt, Rainer Wingen
Patent number: 6955838
Abstract: Compounds of the formula (I) where: R1, R2 are each independently a) H b) -M1-A1-R5 c) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, where c1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(?O)O—, —O—C(?O)—, —O—C(?O)—O—, —C(?O)— or —Si(CH3)2—, and/or c2) one CH2 group may be replaced by —C?C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl, and/or c3) one or more hydrogen atoms may be replaced by F and/or Cl, p, q, r are each independently 0 or 1 M1—is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH?CH—, —CF?CF—, —C?C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(?O)CF?CF— or a single bond, A1 is 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl, CN and/or OCF3, or up to three hydrogen atoms may be replaced by fluorine, 1,4-cyclohexylene where one or two hydrogen at
Type:
Grant
Filed:
July 30, 2004
Date of Patent:
October 18, 2005
Assignee:
Clariant International Ltd.
Inventors:
Rainer Wingen, Barbara Hornung, Wolfgang Schmidt
Publication number: 20050098762
Abstract: Compounds of the formula (I) where: R1, R2 are each independently a) H b) -M1-A1-R5 c) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or astraight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, where c1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(?O)O—, —O—C(?O)—, —O—C(?O)—O—, —C(?O)— or —Si(CH3)2—, and/or c2) one CH2 group may be replaced by —C?C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl, and/or c3) one or more hydrogen atoms may be replaced by F and/or Cl, p, q, r are each independently 0 or 1 M1—is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH?CH—, —CF?CF—, —C?C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(?O)CF?CF— or a single bond, A1 is 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl, CN and/or OCF3, or up to three hydrogen atoms may be replaced by fluorine, 1,4-cyclohexylene where one or two hydrogen
Type:
Application
Filed:
July 30, 2004
Publication date:
May 12, 2005
Inventors:
Rainer Wingen, Barbara Hornung, Wolfgang Schmidt
Publication number: 20050056812
Abstract: Compounds of the general formula (I) where: R1, R2 are each independently a) H b) -M1-A1-R5 c) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, where c1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(?O)O—, —O—C(?O)—, —O—C(?O)—O—, —C(?O)— or —Si(CH3)2—, and/or c2) one CH2 group may be replaced by —C?C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl, and/or c3) one or more hydrogen atoms may be replaced by F and/or Cl, p, q are each independently 0 or 1 G1-G2 is —CH2CH—, —CH?C—, —CH2CH2CH— or —CH?CH—CH— M1 is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH?CH—, —CF?CF—, —C?C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(?O)CF?CF— or a single bond, A1 is 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl, CN and/or OCF3, or up to three hydrogen atoms may be replaced
Type:
Application
Filed:
July 30, 2004
Publication date:
March 17, 2005
Inventors:
Rainer Wingen, Barbara Hornung, Wolfgang Schmidt
Patent number: 6759103
Abstract: The invention relates to compounds of the formula (I) and also liquid-crystal mixtures comprising these compounds, and their use in liquid-crystal displays:
in which
R1 is H, F, CF3, OCF3, OCF2H, OCFH2, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical,
R2 is H, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical,
M1 and M2 are —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —OCF2—, —CF2O—, —C≡C—, —CH2CH2—, —CF2CF2—, —CF═CF—C(═O)O— or a single bond
A1 and A2 are &agr;-1,4-diyl, unsubstituted or mono- or disubstituted by F; where &agr; is: phenylene cyclohexane, 1-cyclohexene,
or 1,3-dioxane-2,5-diyl
m and n are zero or 1; m+n=0 or 1
L1, L2, L3, L4 and L5 are H or F.
Type:
Grant
Filed:
September 12, 2002
Date of Patent:
July 6, 2004
Assignee:
Clariant Financi (BVI) Limited
Inventors:
Barbara Hornung, Wolfgang Schmidt, Rainer Wingen
Patent number: 6737125
Abstract: Compounds of the formula (I), liquid-crystal mixtures comprising these compounds, and their use in liquid-crystal displays:
in which
R1 is H, F, CF3, OCF3, OCF2H, OCFH2, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical;
R2 is H, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical
M1 is —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —OCF2—, —CF2O—, —C≡C—, —CH2CH2—, —CF2CF2—, —CF═CFC(═O)O— or a single bond
M2 is —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —CH2CH2—, —CF2CF2— or a single bond;
A1 and A2 are &agr;-1,4-diyl, unsubstituted or mono- or disubstituted by F; where &agr; is: phenylene, cyclohexane, 1-cyclohexene or 1,3-dioxane-2,5-diyl;
m and n are zero or 1; m+n=0 or 1
L1, L2, L3, L4 and L5 are H or F.
Type:
Grant
Filed:
September 12, 2002
Date of Patent:
May 18, 2004
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Barbara Hornung, Wolfgang Schmidt, Rainer Wingen
Patent number: 6670514
Abstract: Compounds of the formula (I)
in which:
R1 is H, F, CF3, OCF3, OCF2H, OCFH2, an alkyl radical or an alkenyl radical;
R2 is H, an alkyl radical or alkyloxy radical or an alkenyl or alkenyloxy radical;
G2—G1 is —CH═CH—, —CH2CH2—, —CF═CH—, —CH═CF—, —CF═CF—, —CH2—, —CF2—;
M1, M2 are each, independently of one another, —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —OCF2—, —CF2O—, —C≡C—, —CH2CH2—, —CF2CF2— or a single bond;
A1, A2 are each, independently of one another, phenylene-1,4-diyl, unsubstituted, monosubstituted or disubstituted by F, cyclohexane-1,4-diyl, 1,3-dioxan-2,5-diyl;
m, n are each, independently of one another, zero or 1; m+n=0 or 1;
The invention furthermore provides a liquid-crystal mixture comprising one or more compounds of the formula (I
Type:
Grant
Filed:
August 8, 2002
Date of Patent:
December 30, 2003
Assignee:
Clariant Finance (BVI) Limited
Inventors:
Rainer Wingen, Barbara Hornung, Wolfgang Schmidt