Abstract: A polyetherimide of improved color and processes for preparing the polyetherimide are disclosed.

Abstract: A method of manufacturing an isolated polyetherimide composition includes combining an as-synthesized polyetherimide comprising units of the formula (I) and a melt-stabilizing amount of a tri(C8-30 acyl) glyceride, an anhydride of the formula (II), or a combination comprising at least one of the foregoing, to provide a mixture; and isolating a polyetherimide composition from the mixture to provide the isolated polyetherimide composition having a change in complex viscosity measured over 30 minutes at 390° C., at a shear rate of 6.28 rad/seconds, strain=5%, and under nitrogen, from +15 to ?20%, preferably from +10 to ?20%, more preferably from +5 to ?20%.

Abstract: A method for producing a reactive intermediate composition, including: reacting a substituted phthalic anhydride of the formula (I) with a diamine of the formula H2N—R—NH2 in the presence of an aromatic dianhydride in an amount of 10 to 50 mole percent based on the total moles of anhydride functionality in the reaction; wherein the reacting is conducted in an aprotic solvent in a reactor, under conditions effective to produce the reactive intermediate composition; and wherein X comprises a halogen or a nitro group, and R comprises a C6-36 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C2-20 alkylene or a halogenated derivative thereof, or a C3-8 cycloalkylene or a halogenated derivative thereof.

Abstract: A method of making a polyetherimide includes forming an intermediate polyetherimide with an anhydride-amine stoichiometry of ?2 to ?40 mol % and melt mixing the intermediate polyetherimide with a bis(ether anhydride) for greater than 3 minutes at a temperature 50 to 225° C. greater than the glass transition temperature of a final polyetherimide to produce the final polyetherimide.

Abstract: A method of making a polyetherimide includes forming a monomer mixture comprising a bis(ether anhydride), a diamine and a volatile organic solvent; removing the volatile organic solvent to form a particulate solid; and melt polymerizing the particulate solid at a temperature 50 to 225° C. greater than the glass transition temperature of the polyetherimide in a single melt mixing device. The polyetherimide has an anhydride-amine stoichiometry and the standard deviation of anhydride-amine stoichiometry is less than 0.4 mol %.

Abstract: A method of making a polyetherimide includes melt mixing a composition comprising an aromatic bis(ether anhydride) and a diamine to form a polyetherimide wherein melt mixing occurs at a temperature 50 to 225° C. greater than the glass transition temperature of the polyetherimide and after the composition attains a weight average molecular weight that is greater than or equal to 20% of the weight average molecular weight of the polyetherimide melt mixing occurs at a pressure less than atmospheric pressure.

Abstract: A polyetherimide of improved color and processes for preparing the polyetherimide are disclosed.

Abstract: A method of manufacturing an isolated polyetherimide composition includes combining an as-synthesized polyetherimide comprising units of the formula (I) and a melt-stabilizing amount of a tri(C8-30 acyl) glyceride, an anhydride of the formula (II), or a combination comprising at least one of the foregoing, to provide a mixture; and isolating a polyetherimide composition from the mixture to provide the isolated polyetherimide composition having a change in complex viscosity measured over 30 minutes at 390° C., at a shear rate of 6.28 rad/seconds, strain=5%, and under nitrogen, from +15 to ?20%, preferably from +10 to ?20%, more preferably from +5 to ?20%.

Abstract: A method for reducing yellowness of a polyetherimide solution, including exposing a first solution including a solvent and a polyetherimide to light under conditions effective to provide a second solution having a yellowness index that is 1 to 100 units less than the yellowness index of the first solution, as determined according to ASTM D1925. Another aspect is a method for reducing yellowness of a polyetherimide solution including acidifying a first solution including a solvent and a polyetherimide to provide a second solution having a pH less than 5 under conditions effective for the second solution to attain a yellowness index that is 1 to 30 units less than the yellowness index of the first solution, as determined according to ASTM D1925. Polyetherimides prepared according to the method, and compositions and articles including the polyetherimide are also described.

Abstract: A method of preparing a polyetherimide and an improved polyetherimide are disclosed. Low color polyetherimides are disclosed along with process improvements which produce the reduced color of the final product polymers.

Abstract: A polyetherimide of improved color and processes for preparing the polyetherimide are disclosed.

Abstract: A method for producing a reactive intermediate composition, including: reacting a substituted phthalic anhydride of the formula (I) with a diamine of the formula H2N—R—NH2 in the presence of an aromatic dianhydride in an amount of 10 to 50 mole percent based on the total moles of anhydride functionality in the reaction; wherein the reacting is conducted in an aprotic solvent in a reactor, under conditions effective to produce the reactive intermediate composition; and wherein X comprises a halogen or a nitro group, and R comprises a C6-36 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C2-20 alkylene or a halogenated derivative thereof, or a C3-8 cycloalkylene or a halogenated derivative thereof.

Abstract: A polyetherimide of improved color and processes for preparing the polyetherimide are disclosed.

Abstract: A method for reducing yellowness of a polyetherimide solution, including exposing a first solution including a solvent and a polyetherimide to light under conditions effective to provide a second solution having a yellowness index that is 1 to 100 units less than the yellowness index of the first solution, as determined according to ASTM D1925. Another aspect is a method for reducing yellowness of a polyetherimide solution including acidifying a first solution including a solvent and a polyetherimide to provide a second solution having a pH less than 5 under conditions effective for the second solution to attain a yellowness index that is 1 to 30 units less than the yellowness index of the first solution, as determined according to ASTM D1925. Polyetherimides prepared according to the method, and compositions and articles including the polyetherimide are also described.

Abstract: A method is disclosed for the manufacture of a bis(phthalimide), and polyetherimides derived therefrom, by reacting a phthalic anhydride having the formula with an organic diamine having the formula H2N—R—NH2, in a solvent, at a temperature from 140° C. to 220° C., and a pressure from 0 psig to 100 psig, in the presence or absence of a phase transfer catalyst, to form a bis(phthalimide) having the formula wherein a polyetherimide polymer is added either before or after the imidization reaction, to produce a bis(phthalimide) composition having a percent solids content of 18% to 30%, which bis(phthalimide) composition has a viscosity of less than 4000 cP at a shear rate of less than 30 sec?1 and temperaturefrom 140° C. to 180° C. as measured in a spindle viscometer.

Abstract: A polyetherimide of improved color and processes for preparing the polyetherimide are disclosed.

Abstract: A polyetherimide of improved color and processes for preparing the polyetherimide are disclosed.

Abstract: A method of preparing a polyetherimide and an improved polyetherimide are disclosed. Low color polyetherimides are disclosed along with process improvements which produce the reduced color of the final product polymers.

Abstract: The present invention relates to various embodiments of a system and method for separating polymer from a solvent. In one embodiment a system for separating polymer from a solvent comprises an extrusion apparatus includes a hollow member having a first end portion, a second end portion, and a feed port between the first end portion and the second end portion. The extrusion apparatus includes a back flash vent port disposed upstream of the feed port and a forward flash vent port disposed downstream of the feed port. The extrusion apparatus further includes a vent insert located at the forward flash vent port, a screw disposed inside the hollow member, and an internal superheating section disposed between the feed port and the downstream vent opening of the hollow member such that the length of the internal superheating section is greater than about four times the diameter, 4D, of the hollow member.

Abstract: The present invention provides a method of separating a polymer from a solvent comprising introducing a superheated polymer-solvent mixture into an extruder, and isolating a polymer product, said extruder being equipped with at least one vent operated at subatmospheric pressure and at least one vent operated at about atmospheric pressure, said extruder having a screw diameter D, said extruder being operated at a feed rate FR and at a screw speed RPM such that a devolatilization performance ratio (DPR) given by Equation (I) DPR=FR/RPM??Equation (I) is selected from a predetermined set of devolatilization performance ratios which correlate with a target characteristic of the polymer product.