Abstract: A moisture-curable semiconductive formulation consisting essentially of a polyethylene-based polymer blend (uncured) and a conventional carbon black. The polyethylene-based polymer blend comprises a mixture of an ethylene/(alkenyl-functional hydrolyzable silane)/(optional olefinic hydrocarbon) copolymer and an ethylene/unsaturated carboxylic ester copolymer that is free of moisture curable groups. We also discovered methods of making and using same, a moisture-cured semiconductive product made therefrom, and articles containing or made from same.

Abstract: A moisture-curable semiconductive formulation consisting essentially of a mixture of an ethylene/(alkenyl-functional hydrolyzable silane)/(optional olefinic hydrocarbon) copolymer and a conventional carbon black. Also discovered methods of making and using same, a moisture-cured semiconductive product made therefrom, and articles containing or made from same.

Abstract: An insulated wire or cable is made by a process comprising the steps of: (A) extruding onto a covered or uncovered metal conductor or optical fiber a composition having a DF measured at 130° C. (60 Hz, 2 kV) or 120° C. (60 Hz, 8 kV) or 100° C. (60 Hz, 8 kV) of ?0.5% and comprising: (1) a high melt strength ethylene-based polymer made in a tubular reactor, and (2) a peroxide, and (B) crosslinking the high melt strength ethylene-based polymer.

Abstract: An extruded foam includes an ethylene-based polymer composition comprising a polymerized ethylene-base monomer with hydrocarbon-based molecules having the following formula (I), where n is from 3 to 160 and m is from 0 to 50.

Abstract: The composition includes: (i) an ethylene-based polymer; (ii) an organic peroxide, (iii) a triorganophosphine, and (iv) a protic acid-source compound (“PASC”) selected from a protic acid, a protic acid-generator compound (“PAGC”), and combinations thereof. The triorganophosphine has the Structure (1): wherein R1, R2, and R3 each is independently selected from a C1-C40 hydrocarbyl group, a C1-C40 heterohydrocarbyl group, and combinations thereof; with the proviso that the phosphorus atom is bound to a carbon atom in each of R1, R2, and R3.

Abstract: According to various embodiments, an extruded foam is formed from a composition comprising from 1 to 99 wt % of a silicone-functionalized polyethylene comprising a reaction product of the polymerization of ethylene and (meth)acrylic ester functionalized polydimethylsiloxane, and a physical blowing agent. The foam has a density of less than or equal to 0.200 g/cm3 as measured in accordance with ASTM D1622-88 at 25° C.

Abstract: An insulated wire or cable is made by a process comprising the steps of: (A) extruding onto a covered or uncovered metal conductor or optical fiber a composition having a DF measured at 130° C. (60 Hz, 2 kV) or 120° C. (60 Hz, 8 kV) or 100° C. (60 Hz, 8 kV) of ?0.5% and comprising: (1) a high melt strength ethylene-based polymer made in a tubular reactor, and (2) a peroxide, and (B) crosslinking the high melt strength ethylene-based polymer.

Abstract: A polymeric composition includes a first ethylene-based polymer having a crystallinity at 110° C. of 25 wt % or greater as measured according to Crystallinity Testing; a second ethylene-based polymer having a crystallinity at 23° C. of 40 wt % or less as measured according to Crystallinity Testing; and 40 wt % or greater of a halogen-free flame retardant filler.

Abstract: Rheology-modified, additive-containing ethylenic polymer compositions are prepared in a continuously operated extruder comprising first, second and third zones by a process comprising the steps of: mixing in the second zone of the extruder an ethylenic polymer and a high-temperature decomposing peroxide at a temperature such that the half-life of the peroxide is equal to or greater than (?) one minute and for a sufficient period of time to modify the rheology of the ethylenic polymer to produce a rheology-modified, melted ethylenic polymer for transfer to the third zone of the extruder; and adding to the third zone one or more additives to the rheology-modified, melted ethylenic polymer to produce the rheology-modified, additive-containing ethylenic polymer.

Abstract: An insulated wire or cable is made by a process comprising the steps of: (A) extruding onto a covered or uncovered metal conductor or optical fiber a composition having a DF measured at 130° C. (60 Hz, 2 kV) or 120° C. (60 Hz, 8 kV) or 100° C. (60 Hz, 8 kV) of ?0.5% and comprising: (1) a high melt strength ethylene-based polymer made in a tubular reactor, and (2) a peroxide, and (B) crosslinking the high melt strength ethylene-based polymer.

Abstract: A polymeric composition includes an ethylene polymer, 0.05 wt % to 0.25 wt % carbon black based on a total weight of the polymeric composition and a polymeric ultraviolet light stabilizer including a hindered amine moiety and having a weight average molecular weight from 5,000 g/mol to 20,000 g/mol as measured according to Gel Permeation Chromatography.

Abstract: A polymeric composition includes a silane functionalized polyolefin, a brominated flame retardant having a Temperature of 5% Mass Loss from 300° C. to 700° C. as measured according to Thermogravimetric Analysis, wherein the brominated flame retardant is polymeric and has a weight average molecular weight of from 1,000 g/mol to 30,000 g/mol as measured using Gel Permeation Chromatography, and antimony trioxide. The polymeric composition has an antimony (Sb) to bromine (Br) molar ratio (Sb:Br molar ratio) of 0.35 to 0.98.

Abstract: A method of melt blending a flame-retardant composition includes the steps: (a) heating a polymeric brominated flame retardant to a temperature of 5° C. or greater above the polymeric brominated flame retardants glass transition temperature as measured by Differential Scanning calorimetry, wherein the polymeric brominated flame retardant has a Temperature of 5% Mass Loss from 300° C. to 700° C. as measured according to Thermogravimetric Analysis; (b) mixing a polyolefin into the polymeric brominated flame retardant after step (a); and (c) mixing an inorganic filler into the polyolefin and polymeric brominated flame retardant after step (b) to form the flame-retardant composition.

Abstract: Rheology-modified, additive-containing ethylenic polymer compositions are prepared in a continuously operated extruder comprising first, second and third zones by a process comprising the steps of: mixing in the second zone of the extruder an ethylenic polymer and a high-temperature decomposing peroxide at a temperature such that the half-life of the peroxide is equal to or greater than one minute and for a sufficient period of time to modify the rheology of the ethylenic polymer to produce a rheology-modified, melted ethylenic polymer for transfer to the third zone of the extruder; and adding to the third zone one or more additives to the rheology-modified, melted ethylenic polymer to produce the rheology-modified, additive-containing ethylenic polymer.

Abstract: A polymeric composition includes 10 wt % to 80 wt % of a silane-grafted ethylene polymer based on a total weight of the polymeric composition. The silane-grafted ethylene polymer has a silane content of 0.40 mol % to 1.50 mol % based on a total moles of the silane-grafted ethylene polymer and the ethylene polymer used to make the silane-grafted ethylene polymer has a polar comonomer content of less than 15 wt % based on a total weight of the ethylene polymer. The polymeric composition also includes 10 wt % to 80 wt % of a flame-retardant filler based on a total weight of the polymeric composition.

Abstract: A polymeric composition includes a silane functionalized polyolefin; a brominated flame retardant having a Temperature of 5% Mass Loss from 350° C. to 500° C. and from 2 wt % to 50 wt % Retained Mass at 650° C., wherein the 5% Mass Loss and Retained Mass at 650° C. are measured according to Thermogravimetric Analysis; and antimony trioxide, wherein the polymeric composition has an antimony (Sb) to bromine (Br) molar ratio (Sb:Br molar ratio) of greater than 0.0 to 0.35. A coated conductor may be formed using the polymeric composition.

Abstract: An encapsulant film is made from a composition comprising (A) a non-polar ethylene-based polymer having a density of 0.850 g/cc to 0.890 g/cc; (B) an organic peroxide; (C) a silane coupling agent; and (D) a co-agent comprising triallyl phosphate.

Abstract: The process disclosed includes an extruder under extrusion conditions at a temperature from 50° C. to 250° C., and a polymer composition. The polymer composition includes (A) greater than or equal to 5 wt % of a silane functionalized olefin-based polymer with first melting temperature, Tm1, (B) optionally, a nonsilane functionalized polyolefin, with second melting temperature, Tm2, (C) a highly effective silanol condensation catalyst (HEC), (D) a permeability modifier, and (E) optionally, a scorch inhibitor. The process includes introducing a physical blowing agent into the polymer composition to form a foamable composition. The foamable composition is cooled to a foaming temperature from 10° C. less than to 10° C. greater than Tm1. The foamable composition from an extruder exit die to form a foam composition. The foam composition is moisture cured to form a crosslinked foam composition having a density from 0.010 g/cc to 0.200 g/cc, and a gel content from 5% to 100%.

Abstract: A polymeric composition includes a silane functionalized polyolefin, a brominated flame retardant having a Temperature of 5% Mass Loss from 350° C. to 500° C. and from 2 wt % to 50 wt % Retained Mass at 650° C. The 5% Mass Loss and Retained Mass at 650° C. are measured according to Thermogravimetric Analysis. The polymeric composition also includes a zinc (Zn) flame retardant synergist. The polymeric composition is free of antimony trioxide and has a zinc to bromine (Br) molar ratio (Zn:Br molar ratio) of greater than 0.0 to 0.160.

Abstract: A process of melt compounding a polyolefin formulation comprising a ethylenic-based (co)polymer, an antioxidant, and from 0.15 to 1.00 weight percent of an organic peroxide having a 1-hour half-life temperature of less than or equal to 155 degrees Celsius (° C.) and/or a 10-hour half-life temperature of less than or equal to 135° C. Also, intermediate compositions having a modified rheology and crosslinked polyolefin products made therefrom; methods of making and using same; and articles containing same.