Abstract: A system for isolating a greenhouse gas from an exhaust gas includes a vessel having an inlet to receive an exhaust gas, and an outlet to discharge a process stream, an adsorbent contained in the vessel to selectively adsorb the greenhouse gas from the exhaust gas under suitable conditions, and a heat source to heat the adsorbent and desorb the adsorbed greenhouse gas therefrom to produce a process stream of greenhouse gas for release through the outlet.

Abstract: A system for isolating a greenhouse gas from an exhaust gas includes a vessel having an inlet to receive an exhaust gas, and an outlet to discharge a process stream, an adsorbent contained in the vessel to selectively adsorb the greenhouse gas from the exhaust gas under suitable conditions, and a heat source to heat the adsorbent and desorb the adsorbed greenhouse gas therefrom to produce a process stream of greenhouse gas for release through the outlet.

Abstract: A protected solid adsorbent is disclosed that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.

Abstract: A method of utilizing waste heat to create a pressurized working fluid is disclosed. The method includes providing a vessel containing a sorbent system, introducing a feed of waste heat to a heat exchanger external to the vessel to heat a feed of working fluid, introducing the heated working fluid from the heat exchanger to the vessel to obtain pressurized working fluid, and directing the pressurized working fluid from the vessel to a work component. The method is particularly suited to make use of waste heat an industrial process, (e.g., a chemical processing or petrochemical refining operation) in which low grade heat source(s) are used to drive the sorption system.

Abstract: The present application provides a protected solid adsorbent that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.

Abstract: Methods, apparatus, and systems for removing contaminant in a fluid (e.g., chemical and petrochemical gas streams) using nanostructures of a sorbent material coated on plates such as a silicon wafer. A plurality of such coated plates can be assembled to form a sorption structure having channels between the plates. When a fluid containing the contaminant is directed through the channels, the contaminant is adsorbed by the nanostructures of the sorbent material.

Abstract: A sorption system is disclosed that includes a sorbent material and a fluid, in which the sorbent material and fluid in combination have a pressure index of at least 1.2.

Abstract: A system for removing polar components from a process stream in a refinery process without cooling the stream is disclosed. The stream is fed to a first adsorber unit to remove contaminants containing sulfur from the stream at substantially the same elevated temperature. The stream is processed within the first adsorber unit by exposing the stream to at least one of a metal oxide and a mixed metal oxide to remove the sulfur containing contaminants and produce a metal sulfide and a desulfurized stream. The desulfurized stream is then fed through a second adsorber unit to remove contaminants containing nitrogen from the stream at substantially the same elevated temperature. The stream is processed within the second adsorber unit by exposing the stream to at least one of a molecular sieve and zeolites to remove nitrogen containing contaminants from the stream.

Abstract: A process for removing polar components from a process stream in a refinery process without cooling the process stream. The process stream is fed to a first adsorber unit to remove contaminants containing sulfur at substantially the same elevated temperature by exposing the process stream to a metal oxide and/or a mixed metal oxide to remove the sulfur containing contaminants and produce a metal sulfide and a desulfurized process stream. The metal sulfide may be regenerated by exposing it to a stream of oxygen and the desulfurized process stream exposed to the regenerated metal/mixed metal oxide to remove moisture from the stream. The stream is then processed within a second adsorber unit to remove nitrogen containing contaminants at substantially the same elevated temperature by exposing the stream to a molecular sieve and/or zeolite.

Abstract: A gas transport system including a conduit (e.g., a pipeline) containing a feed of a gas at a first temperature and first pressure, a source of a refrigerant from an adsorption system in thermal communication with the conduit to cool the feed of gas to a reduced temperature, and at least one compressor to receive the cooled feed of gas and increase the amount of cooled feed of gas to a second pressure, in which the second pressure is greater than the first pressure.

Abstract: A system for isolating a greenhouse gas from an exhaust gas includes a vessel having an inlet to receive an exhaust gas, and an outlet to discharge a process stream, an adsorbent contained in the vessel to selectively adsorb the greenhouse gas from the exhaust gas under suitable conditions, and a heat source to heat the adsorbent and desorb the adsorbed greenhouse gas therefrom to produce a process stream of greenhouse gas for release through the outlet.

Abstract: Methods, apparatus, and systems for removing contaminant in a fluid (e.g., chemical and petrochemical gas streams) using nanostructures of a sorbent material coated on plates such as a silicon wafer. A plurality of such coated plates can be assembled to form a sorption structure having channels between the plates. When a fluid containing the contaminant is directed through the channels, the contaminant is adsorbed by the nanostructures of the sorbent material.

Abstract: The disclosed subject matter relates to process modifications and apparatus designs that are conducive towards minimizing temperature swings (?T) useful to yield operating pressures that provide work and/or refrigeration (e.g., electricity and/or refrigeration) in sorption systems. Such process modifications and designs are particularly suited to make use of waste heat in industrial process, (e.g., a chemical processing or petrochemical refining operation) in which low grade heat source(s) are used to drive the sorption system.

Abstract: The present application provides a sorption system for generating power and chilling that includes at least one absorber to absorb a working fluid in a liquid sorbent, a pump in fluid communication with the absorber to yield a feed of pressurized liquid sorbent and absorbed working fluid, a heat source to heat the feed of pressurized liquid sorbent and absorbed working fluid to yield a feed of working fluid at a supercritical state, a generator in fluid communication with the feed of working fluid at a supercritical state to yield power and a feed of working fluid in an at least partially condensed state, and an evaporator in fluid communication with the feed of working fluid in the at least partially condensed state to yield chilling and uncondensed working fluid. Additional systems and method for the generating power and chilling are provided.

Abstract: The present application provides a protected solid adsorbent that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.

Abstract: The present invention relates to process modifications and apparatus designs that are conducive towards minimizing temperature swings (?T) useful to yield operating pressures that provide work and/or refrigeration (e.g., electricity and/or refrigeration) in sorption systems. Such process modifications and designs are particularly suited to make use of waste heat an industrial process, (e.g., a chemical processing or petrochemical refining operation) in which low grade heat source(s) are used to drive the sorption system.

Abstract: A method of utilizing waste heat to create a pressurized working fluid is disclosed. The method includes providing a vessel containing a sorbent system, introducing a feed of waste heat to a heat exchanger external to the vessel to heat a feed of working fluid, introducing the heated working fluid from the heat exchanger to the vessel to obtain pressurized working fluid, and directing the pressurized working fluid from the vessel to a work component. The method is particularly suited to make use of waste heat an industrial process, (e.g., a chemical processing or petrochemical refining operation) in which low grade heat source(s) are used to drive the sorption system.

Abstract: A multi-layer membrane structure including a crosslinked polymeric membrane, such as a crosslinked polyvinyl sulfate membrane or a crosslinked copolymer polyvinyl sulfate and polyvinyl alcohol membrane, is provided. The membrane structure is suitable for use in an acid environment, and is suitable for recovering acid from a feed mixture comprising acid, hydrocarbons and water.

Abstract: A cross-linked polyvinyl sulfate, copolymer of polyvinyl sulfate and polyvinyl alcohol, or Nafion® membrane is used for recovering sulfuric acid from a feed mixture comprising predominantly acid and water under reverse osmosis conditions wherein sulfuric acid is enriched in the retentate stream and water is removed in the permeate stream.

Abstract: A crosslinked polymeric membrane, such as a crosslinked polyvinyl sulfate membrane or a crosslinked copolymer polyvinyl sulfate and polyvinyl alcohol membrane, is provided. The membrane is suitable for use in an acid environment, and is suitable for recovering acid from a feed mixture comprising acid, hydrocarbons and water.