Patents by Inventor Bruce P. Thill

Bruce P. Thill has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5780376
    Abstract: Organoclay compositions which comprise the reaction product of a smectite-type clay having an ion exchange capacity of at least 50 meq. wt. per 100 g. clay (active basis), and mixture of a quaternary ammonium compound and a chain transfer agent which is a thiol, .alpha.-methylketone, .alpha.-methylalcohol or a halogen compound are useful agents for use in the processes for the preparation of thermoplastic materials.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: July 14, 1998
    Assignees: Southern Clay Products, Inc., The Dow Chemical Company
    Inventors: Antonio Gonzales, Kevin L. Nichols, Clois E. Powell, Bruce P. Thill
  • Patent number: 5426171
    Abstract: A composition of matter comprising 25 to 99 parts by weight thermoplastic resin and 75 to 1 part by weight solid reinforcing agent having a surface coating of a polar group functionalized polyarylene ether.
    Type: Grant
    Filed: November 5, 1993
    Date of Patent: June 20, 1995
    Assignee: The Dow Chemical Company
    Inventors: Yi-Bin Huang, Bruce P. Thill
  • Patent number: 5391603
    Abstract: A composition of matter comprising:A) from 25 to 90 parts by weight of a syndiotactic, vinylaromatic thermoplastic resin,B) from 1 to 50 parts by weight of a rubbery, impact absorbing domain forming polymer,C) from 0.1 to 30 parts by weight of a nucleator for the syndiotactic, vinylaromatic thermoplastic resin,D) from 0 to 90 parts by weight of an mineral, glass, ceramic, polymeric or carbon reinforcing agent, andE) from 0 to 90 parts by weight of one or more polyarylene ethers or polar group modified polyarylene ethers.
    Type: Grant
    Filed: April 21, 1993
    Date of Patent: February 21, 1995
    Assignee: The Dow Chemical Company
    Inventors: Thomas E. Wessel, Bruce P. Thill, Yi-Bin Huang
  • Patent number: 5008347
    Abstract: Polyalkyloxazoline-polycarbonate-polyalkyloxazoline triblock copolymers are prepared by a novel process, and are useful as compatibilizing agents in polycarbonate/polyamide resin blends.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: April 16, 1991
    Assignee: The Dow Chemical Company
    Inventors: Bruce P. Thill, Bruce A. King
  • Patent number: 4954579
    Abstract: Polyalkyloxazoline-polycarbonate-polyalkyloxazoline triblock copolymers are prepared by a novel process, and are useful as compatibilizing agents in polycarbonate/polyamide resin blends.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: September 4, 1990
    Assignee: The Dow Chemical Company
    Inventors: Bruce P. Thill, Bruce A. King
  • Patent number: 4883836
    Abstract: Polyalkyloxazolines are useful as compatibilizing agents in polycarbonate/polyamide resin blends.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: November 28, 1989
    Assignee: The Dow Chemical Company
    Inventor: Bruce P. Thill
  • Patent number: 4741970
    Abstract: A thermoplastic laminate structure consisting of a plurality of layers wherein at least one of the layers is the adhesive polymeric blend. The adhesive polymeric blend comprises a dispersed phase of poly-2-oxazoline and a glycol and a continuous phase of grafted polypropylene. The preferred poly-2-oxazoline is poly-2-ethyl-2-oxazoline and the preferred glycols are polyalkylene glycols. The grafted polypropylene comprises from about 50 to 80 percent by weight of the total polymeric blend. The grafted polypropylene contains from about 0.1 to about 5 percent by weight total polymer of a graft portion derived from an .alpha.,.beta.-ethylenically unsaturated carboxylic acid or an unsaturated cyclic anhydride wherein said glycol is in slight excess to the graft, i.e., molar ratio of glycol to graft is 1.1 to about 1.5:1.
    Type: Grant
    Filed: January 12, 1987
    Date of Patent: May 3, 1988
    Assignee: The Dow Chemical Company
    Inventors: William J. Fairchok, Thomas O. Ginter, Bruce P. Thill, Thomas T. Chiu
  • Patent number: 4694050
    Abstract: A process for absorbing polar materials using a crosslinked polymeric composition such as poly-2-ethyloxazoline and ethyleneamine tetracetic acid. The crosslinked polymeric composition swells into a gel-like mass in the presence of polar materials to entrap them.
    Type: Grant
    Filed: October 15, 1985
    Date of Patent: September 15, 1987
    Assignee: The Dow Chemical Company
    Inventors: William J. Fairchok, Ralph E. Friedrich, Bruce P. Thill, Mark J. McKinley
  • Patent number: 4582877
    Abstract: A polymeric composition comprising a poly-2-oxazoline reacted by transamidation with a carboxylic acid, anhydride, salts of a carboxylic acid or combination thereof which can be blended with another polymeric composition to form a water wettable blend. In another aspect, the poly-2-oxazoline is crosslinked with a polybasic carboxylic acid by transamidation. The crosslinked polymeric composition is useful as an absorbent for polar materials.
    Type: Grant
    Filed: July 27, 1984
    Date of Patent: April 15, 1986
    Assignee: The Dow Chemical Company
    Inventors: William J. Fairchok, Bruce P. Thill, Ralph E. Friedrich, Mark J. McKinley
  • Patent number: 4332916
    Abstract: Increased ion exchange capacity per unit weight of substrate is achieved upon using as the substrate regenerated cellulose sponge instead of cotton fabric. A water soluble crosslinkable polymeric material having ion ion exchange sites, such as polyvinyl phosphate or polyethylenimine, and a suitable crosslinking agent are dissolved in water. The sponge is wetted with the solution and dried and cured at about 100 degrees to 145 degrees C. to crosslink the polymer to the substrate. The so-prepared ion exchange composition is immersed in a flowing stream of dilute aqueous solution of heavy metal ions or otherwise contacted with such solution to effect separation and concentration of such cations.
    Type: Grant
    Filed: September 21, 1972
    Date of Patent: June 1, 1982
    Assignee: The Dow Chemical Company
    Inventor: Bruce P. Thill
  • Patent number: 4245063
    Abstract: A thermosetting powder coating composition is disclosed herein. The composition comprises a solid pulverulent mixture of (A) a substantially linear vinyl addition interpolymer having a plurality of pendant 2-oxazoline and/or 2-oxazine groups, a number average molecular weight of from about 5,000 to about 25,000, and a melting point of from about 60.degree. C. to 90.degree. C., and (B) a solid polycarboxylic acid melting in the range of 70.degree. C. to 175.degree. C. which is included in an amount of from 0.75 to 1.25 carboxy equivalents per pendant oxazoline or oxazine group on the interpolymer. The utility of the above composition as a powder coating is further enhanced by inclusion of a plasticizer (e.g., a long chain monocarboxylic acid) and in practice, the powder compositions also normally include pigments and minor amounts of flow control agents. The instant powder coatings are applied by conventional techniques and cured at temperatures normally in the range of from about 150.degree. C. to about 200.
    Type: Grant
    Filed: October 16, 1978
    Date of Patent: January 13, 1981
    Assignee: The Dow Chemical Company
    Inventors: Bruce P. Thill, Donald A. Tomalia
  • Patent number: 4016171
    Abstract: 2-Vinyl-2-oxazolines are prepared in the novel process comprising reacting (1) an N-(2-haloalkyl)-3-halopropionamide with (2) at least 2 equivalents of an inorganic base per mole of (1). The process is conducted under substantially anhydrous conditions and in the presence of an alkylene glycol or a polyalkylene glycol.
    Type: Grant
    Filed: September 14, 1972
    Date of Patent: April 5, 1977
    Assignee: The Dow Chemical Company
    Inventors: Bruce P. Thill, Janet N. Paige
  • Patent number: 4016192
    Abstract: Ethylenically-unsaturated products are obtained by (a) reacting acrylic acid and 2-oxazoline or a 2-alkyl or aryl-2-oxazoline in an inert liquid reaction medium and (b) recovering the desired product from (a) by heating the reaction mixture under reduced pressure to strip away the liquid diluent and volatile components, thus leaving the desired product as a non-volatile residue. The reaction products can be cross-linked by conventional techniques (e.g. freeradical initiation) to form useful coatings and adhesives. For example, the product produced by heating equal molar amounts of acrylic acid and 2-ethyl-2-oxazoline in benzene gave an ethylenically-unsaturated oligomeric product having a number average molecular weight of 253 and a weight average molecular weight of 460 in approximately 95 percent yield.
    Type: Grant
    Filed: December 30, 1974
    Date of Patent: April 5, 1977
    Assignee: The Dow Chemical Company
    Inventors: Donald A. Tomalia, Bruce P. Thill, Thomas W. Regulski