Abstract: A method for the material-removing machining of a workpiece by laser beam pulses. The laser beam pulses are directed to impact points on the surface of a volume to be removed of the workpiece in order to cut away material from the volume to be removed. Cutting away the volume to be removed results in a new contour surface to be produced on the workpiece. An impact angle of the laser beam pulses relative to the contour surface to be produced is set in accordance with a predefined condition during the removal of at least part of the volume to be removed that directly adjoins the contour surface to be produced. According to this condition, the impact angle is the same as a threshold angle (as), or somewhat smaller. The threshold angle corresponds to the impact angle at which an effective laser energy density at the impact point of the laser beam pulses on the contour surface to be produced is equal to a threshold fluence.

Abstract: A process to produce a workpiece surface or a groove inner surface on a rod-shaped, especially cylindrical workpiece. From the workpiece, a rotary tool is supposed to be produced. The material removal is done using laser beam pulses, which are directed through a deflection device onto points of incidence within a pulse area with a specified outside contour on the workpiece. Multiple machine axis drives position the workpiece and the deflection device relative to one another so that the pulse area is oriented essentially at right angles to the emission direction of the laser beam pulses and at right angles to the section of the tool surface that has already been produced and that borders the pulse area. While the material is being removed, the at least one machine axis drive moves the pulse area relative to the workpiece along a specified path of motion while maintaining the orientation.

Abstract: The laser machining equipment for etching grooves in a wall of a mechanical part, in particular of a connecting rod for a spark ignition engine, is provided with a fibre optic laser device and arranged to supply laser pulses. The fibre optic laser device is controlled so that said laser pulses have a peak power of more than 400 W and at least two times greater than the maximum mean power of said laser device and in that the duration of said laser pulses is below or within the nanosecond range (1 ns to 1000 ns). According to a first embodiment, the fibre optic laser device is controlled in a quasi continuous wave (QCW) mode. According to a second preferred embodiment, the fibre optic laser device is controlled in a Q-switch mode. The selected operating modes increase machining efficiency and produce a groove with an optimum transverse profile, particularly with a small mean radius of curvature at the bottom of the groove which then allows precise subsequent fracturing of the mechanical part with less force.

Abstract: A process to produce a workpiece surface or a groove inner surface on a rod-shaped, especially cylindrical workpiece. From the workpiece, a rotary tool is supposed to be produced. The material removal is done using laser beam pulses, which are directed through a deflection device onto points of incidence within a pulse area with a specified outside contour on the workpiece. Multiple machine axis drives position the workpiece and the deflection device relative to one another so that the pulse area is oriented essentially at right angles to the emission direction of the laser beam pulses and at right angles to the section of the tool surface that has already been produced and that borders the pulse area. While the material is being removed, the at least one machine axis drive moves the pulse area relative to the workpiece along a specified path of motion while maintaining the orientation.

Abstract: A laser machining equipment for etching grooves in a wall of a mechanical part, or in a connecting rod for a spark ignition engine, includes a fiber optic laser device arranged to supply laser pulses. The fiber optic laser device is controlled so that laser pulses have a peak power of more than 400 W and at least two times greater than maximum mean power of the laser device, and duration of the laser pulses is below or within the nanosecond range of 1 ns to 1000 ns. The fiber optic laser device can be controlled in a quasi continuous wave (QCW) mode, or can be controlled in a Q-switch mode. The selected operating modes increase machining efficiency and produce a groove with an optimum transverse profile, particularly with a small mean radius of curvature at a bottom of the groove which then allows precise subsequent fracturing of the mechanical part with less force.

Abstract: A laser machining method includes A) generating, by a laser source, a laser beam having an initial wavelength between 700 and 1200 nanometers of laser pulses; B) doubling frequency of one part of the laser beam by a non-linear crystal; C) varying power throughout each emitted laser pulse so that the power profile has a maximum peak power or part of the pulse with a maximum power in an initial sub-period, and throughout an intermediate sub-period of longer duration than the initial sub-period, a lower power than the maximum power. The maximum power value is at least two times higher than the mean power throughout the laser pulse and an increase time to maximum power from a start of each laser pulse is less than 0.3 milliseconds. The machining method can concern welding highly reflective metals, copper, gold, silver, or an alloy including one of these metals.

Abstract: The laser device (22) is formed by a stack of laser diodes (4) arranged on plates (6) formed of a material that is electrically conductive and a good heat conductor. In order to obtain a high level of heat evacuation efficiency towards the cooling body (10) and to prevent electric short-circuiting problems, each plate has at the bottom end (24) thereof, an electrically insulating layer deposited on the surface thereof prior to being fixed to the cooling body by a securing material (26) that is preferably a good heat conductor, formed in particular by a braze layer. According to the invention, the insulating layer covers the end face of each plate and also goes up along the lateral faces of the latter over a certain height. The securing material is arranged under the end of the plate and also partially covers the insulating layer along the lateral faces of the plate.

Abstract: The laser machining device is provided for drilling holes in components of a fluid injection device, particularly for injecting fuel into a combustion engine. The laser resonator is formed by an optically pumped diode laser solid state active medium. The resonator is arranged for supplying primary pulses in the microsecond range. Modulation means are arranged between the resonator and a machining head for modulating the amplitude of the primary pulses supplied by the resonator, so as to obtain a secondary pulse train of smaller length for each of said pulses.

Abstract: The laser device (22) is formed by a stack of laser diodes (4) arranged on plates (6) formed of a material that is electrically conductive and a good heat conductor. In order to obtain a high level of heat evacuation efficiency towards the cooling body (10) and to prevent electric short-circuiting problems, each plate has at the bottom end (24) thereof, an electrically insulating layer deposited on the surface thereof prior to being fixed to the cooling body by a securing material (26) that is preferably a good heat conductor, formed in particular by a braze layer. According to the invention, the insulating layer covers the end face of each plate and also goes up along the lateral faces of the latter over a certain height. The securing material is arranged under the end of the plate and also partially covers the insulating layer along the lateral faces of the plate.

Abstract: The laser machining device is provided for drilling holes in components of a fluid injection device, particularly for injecting fuel into a combustion engine. The laser resonator is formed by an optically pumped diode laser solid state active medium. The resonator is arranged for supplying primary pulses in the microsecond range. Modulation means are arranged between the resonator and a machining head for modulating the amplitude of the primary pulses supplied by the resonator, so as to obtain a secondary pulse train of smaller length for each of said pulses.

Abstract: The device is provided with at least one laser diode (2) and two electric connecting members for connection to an electric power supply (8) for supplying said at least one laser diode. It includes two elements (14, 16) which can be elastically deformed or moved, which are conductive electrically and arranged in a base electrically insulated from the two connecting members. The two elastically deformable or moveable elements are electrically connected and arranged so as to abut against two respective contact surfaces (34, 36) of the two connecting members when the device is not connected to said power supply by means of an external connector (40) which is complementary to the two electric connecting members. The two elastically deformable or moveable elements are respectively separated from the two connecting members when the external connector is introduced or are able to be respectively separated from said two connecting members when the external connector is introduced.

Abstract: Compounds having a 16-membered macrolide ring, and related to the milbemycins and avermectins, with substituents at positions 5.13, 25 and optionally also 23, have acaricidal, insecticidal and anthelmintic properties. They are useful for treating various pests in plants and animals.

Abstract: The present invention relates to a one-step microbial process for the preparation of 13.beta.-hydroxy- or 14,15-epoxy-milbemycins of the following formulae I and II ##STR1## in which R.sub.1 and R.sub.1 ' represent methyl, ethyl, isopropyl or sec.-butyl or represent the group ##STR2## in which X represents methyl, ethyl or isopropyl, and A and A' represent the group ##STR3## in which R.sub.2 represents hydrogen, --C(O)-CH.sub.2 O-C(O)-CH.sub.2 CH.sub.2 -COOH or --C(O)-CH.sub.2 CH.sub.2 -COOH, or mixtures of compounds of the formulae I and II, which process comprises bringing a milbemycin of the formula III ##STR4## dissolved in a liquid phase, in which R.sub.3 represents R.sub.1 or R.sub.1 ' and R.sub.4 represents A or A', and R.sub.1, R.sub.1 ', A and A' have the meanings given for formulae I and II, into contact with a microorganism that is capable of 13.beta.-hydroxylation or 14,15-epoxidation or of both reactions, or into contact with active constituents thereof.

Abstract: Compounds having a 16-membered macrolide ring, and related to the milbemycins and avermectins, with substituents at positions 5, 13, 25 and optionally also 23, have acaricidal, insecticidal and anthelmintic properties. They are useful for treating various pests in plants and animals.

Abstract: The present invention relates to novel compounds of the formula ##STR1## wherein R.sub.1 is hydrogen, a silyl group or an acyl group,R.sub.2 is methyl, ethyl, is propyl or sec-butyl, and R is hydrogen, unsubstituted or substituted straight chain or branched C.sub.1 -Cl.sub.18 alkyl, an unsubstituted or substituted cycloaliphatic group containing 3 to 10 carbon atoms, unsubstituted or substituted C.sub.2 -C.sub.6 alkenyl, unsubstituted or substituted C.sub.2 -C.sub.6 -alkynyl, unsubstituted or substituted phenyl or unsubstituted or substituted benzyl. These compounds posseses advantageous pesticidal properties and are suitable in particular for controlling pests in agriculture and the storage sector.

Abstract: Novel compounds of formula I ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.7, R.sup.8 and R.sup.9, independently of the others, is H or halogen,R.sup.4 is H, R.sup.10 CO-- or R.sup.11 NHCO-- wherein R.sup.10 is a C.sub.1 -C.sub.4 alkyl group which is unsubstituted or substituted by one to three identical or different substituents selected from the group consisting of halogen, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 - acyloxy and --COOG, wherein G is H, an alkali metal cation or an alkaline earth metal cation, and R.sup.11 is an unsubstituted or halo-substituted C.sub.1 -C.sub.4 alkyl or phenyl group,each of R.sup.5 and R.sup.6, independently of the other, is H, halogen, alkyl or haloalkyl andX is O, S(O)n or NH wherein n is 0, 1 or 2, the preparation of the novel compounds and their use against parasites in and on productive livestock and against insect pests, and novel starting materials and their preparation.

Abstract: Derivatives of milbemycins D, A.sub.3 and A.sub.4 and of the corresponding sec-butyl compound have a halogen atom at the 13-position; at the 5-position, they have an oxygen (keto) atom, an oxime group or a substituted oxime group. They may be prepared from known compounds by any appropriate combination of halogenation, ketonization and oximation.

Abstract: The present invention relates to novel 5-oximino-13.beta.-carbonylthiomilbemycin derivatives of formula I, to their preparation and to the use thereof for controlling pests. The invention further relates to pesticidal compositions which contain at least one of these compounds as active ingredient. The novel compounds have the general formula I ##STR1## wherein R.sub.1 is hydrogen or an alkyl, cycloalkyl or acyl group,R.sub.2 is methyl, ethyl, isopropyl or sec-butyl, or is the ##STR2## group, wherein X is methyl, ehtyl or isopropyl, and R is hydrogen or an unsubstituted or substituted straight chain or branched C.sub.1 -C.sub.18 alkyl group, an unsubstituted or substituted cycloaliphatic group of 3 to 10 carbon atoms, an unsubstituted or substituted C.sub.2 -C.sub.6 alkenyl group, an unsubstituted or substituted C.sub.2 -C.sub.6 alkynyl group, an unsubstituted or substituted phenyl group or an unsubstituted or substituted benzyl group.

Abstract: Novel compounds of the formula ##STR1## in which R.sub.1 is a hydrogen or a silyl or acyl group, R.sub.2 is methyl, ethyl, isopropyl or sec.-butyl and R is hydrogen, unsubstituted or substituted, linear or branched-chain C.sub.1 -C.sub.18 -alkyl groups, unsubstituted or substituted cycloaliphatic groups having 3 to 10 carbon atoms, unsubstituted or substituted C.sub.2 -C.sub.6 -alkenyl groups, unsubstituted or substituted C.sub.2 -C.sub.6 -alkynyl groups, unsubstituted or substituted phenyl groups or unsubstituted or substituted benzyl groups. The active compounds possess advantageous pesticidal properties. They are particularly suitable for the control of pests in agriculture and the management of stored products.

Abstract: The invention relates to parasiticidally and insecticidally highly active compounds of formula I ##STR1## wherein R is C.sub.1 -C.sub.10 alkyl;R.sub.1 is hydrogen, a silyl group or a sugar residue; andR.sub.2 is methyl, ethyl, isopropyl or sec-butyl, and to the preparation thereof starting from suitably substituted 15-ester or 13.beta.-ester milbemycins.