Abstract: An ink jettable 3-D material composition includes a reversible polymer material, which can reversibly transition between a liquid state and a solid state by reversible cyclo-addition reactions, wherein upon cooling, the reversible polymer material transitions from a liquid state to a solid state by reversible cyclo-addition reactions within a time period of less than about 10 seconds.

Abstract: There is described a transfer member or blanket for use in aqueous ink jet printer. The transfer member includes a surface layer having a surface roughness (Ra) of from about 50 nm to about 5 microns. The surface layer has a surface energy between 8 mN/m2 and 30 mN/m2. The surface layer includes an elastomeric matrix having a plurality texture particles dispersed therein. The weight percent of the texture particles in the surface layer is from about 0.2 weight percent to about 20 weight percent.

Abstract: There is described a transfer member or blanket for use in aqueous ink jet printer. The transfer member includes a non-woven polymer fiber matrix and a polymer dispersed throughout the non-woven polymer fiber matrix. The polymer fiber matrix has a first surface energy and the polymer has a second surface energy. The difference between the first surface energy and the second surface energy is from about 30 mJ/m2 to about 5 mJ/m2.

Abstract: Described herein is a transfer member for use in aqueous ink jet printer. The transfer member includes a surface layer of a cross-linked polydiphenylsiloxane network formed from a silanol terminated dialkylsiloxane-diphenylsiloxane copolymer and a trialkoxy- or trihydroxysilane terminated polydialkylsiloxane. The diphenylsiloxane moieties are from about 5 weight percent to about 80 weight percent of the network. The trialkoxy- or trihydroxysilane terminated polydialkylsiloxane are from about 1 weight percent to about 60 weight percent of the network. All silane molecules are bonded together via silicon oxide (Si—O—Si) linkages in a single system. The network is insoluble in solvents selected from the group consisting of: ketones, chlorinated solvents and ethers.

Abstract: The present disclosure provides a transparent cross-linked siloxane composition. The composition is a polymerization product of a mixture of a difunctional alkoxysilane precursor materials and a monofunctional alkoxysilane material. The monofunctional alkoxysilane material is from about 1 weight percent to about 50 weight percent of the composition. The mole ratio of the monofunctional alkoxysilane materials to difunctional alkoxysilane precursor materials is from 1 to 4 to about 1 to 1.

Abstract: A crosslinked siloxane composition contains the polymerization product of a mixture containing from about 2 to about 12 alkoxysilane precursor materials, where at least one of the alkoxysilane precursor materials is a hydrophilic alkoxysilane precursor material, and at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material. A method of printing an image to a substrate involves applying an inkjet ink to an intermediate transfer member using an inkjet printhead, spreading the ink onto the transfer member, inducing a property change of the ink, and transferring the ink to a substrate, where the intermediate transfer member comprises a crosslinked siloxane composition containing the polymerization product of a mixture comprising from about 2 to about 12 alkoxysilane precursor materials, where at least one of the precursor materials is hydrophilic and at least one is hydrophobic.

Abstract: The present disclosure provides an ink jet print head face plate. The ink jet print head face plate includes a face plate; and a siloxyfluorocarbon networked polymer disposed on the face plate. The siloxyfluorocarbon networked polymer is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials, wherein at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material; and at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material. The siloxyfluorocarbon networked polymer is insoluble in solvents selected from the group consisting of ketones, chlorinated solvents and ethers.

Abstract: There is provided a crosslinked siloxane composition. The crosslinked siloxane composition is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials. At least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material. In addition at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material.

Abstract: Described is provided a composition of matter that includes a layer having a metal coated non-woven polymer fiber mesh. The metal coated non-woven polymer fiber mesh has pores of a size of from about 1 micron to about 50 microns, and a fluoropolymer dispersed on and throughout the metal coated non-woven polymer fiber mesh. A method of manufacturing is also provided.

Abstract: A fuser member including a substrate and a release layer disposed on the substrate is described. The release layer includes a metal coated non-woven polymer fiber mesh wherein the metal coated non-woven polymer fiber mesh has pores of a size of from about 1 microns to about 50 microns and a fluoropolymer dispersed on and throughout the polymer matrix. A method of manufacturing the fuser member is also provided.

Abstract: Described is a fuser member including a substrate and a release layer disposed on the substrate. The release layer includes a fluoropolymer having a plurality of metal fibers having a diameter of from about 5 nanometers to about 20 microns dispersed throughout the fluoropolymer. A method of manufacturing the fuser member is also provided.

Abstract: A fuser member including a substrate and a release layer disposed on the substrate is provided. The fuser member includes a substrate and a release layer disposed on the substrate. The release layer includes non-woven polymer fibers having graphene particles dispersed along the fibers. A method of manufacturing the release layer is provided.

Abstract: An intermediate transfer member containing a thermally conductive nanofiller dispersed in a polymer base, a method of forming the intermediate transfer member, and a method of printing an image to a substrate using the intermediate transfer member.

Abstract: An intermediate transfer member containing a layer of a siloxyfluorocarbon networked polymer. A method of preparing an intermediate transfer member including mixing a coating solution containing siloxyfluorocarbon precursor materials; applying the coating solution as a sol on a substrate; curing the coating solution on the substrate to form an intermediate transfer member containing a layer of a siloxyfluorocarbon networked polymer. The surface free energy of the intermediate transfer member may be from about 10 mN/m to about 40 mN/m. A method of printing an image to a substrate includes applying an inkjet ink to an intermediate transfer member containing a layer of a siloxyflurocarbon networked polymer; spreading the ink onto the intermediate transfer member; inducing a property change of the ink; and transferring the ink to a substrate.

Abstract: A formulation composition for preparing a print head face plate coating includes a sol containing a mixture of monomers including at least one fluoroalkoxysilane monomer; a solvent; a catalyst; and water. The formulation composition is stable towards gelation for more than 1.5 hours. A method of preparing a print head involves preparing a formulation composition containing a sol prepared from a mixture of monomers including at least one fluoroalkoxysilane monomer, a solvent, a catalyst, and water; applying the formulation composition as a sol on a surface of the print head; and curing the formulation composition to form a crosslinked siloxane layer on the print head. A method of printing involves using the print head to apply inkjet ink to a substrate.

Abstract: A crosslinked siloxane composition contains the polymerization product of a mixture containing from about 2 to about 12 alkoxysilane precursor materials, where at least one of the alkoxysilane precursor materials is a hydrophilic alkoxysilane precursor material, and at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material. A method of printing an image to a substrate involves applying an inkjet ink to an intermediate transfer member using an inkjet printhead, spreading the ink onto the transfer member, inducing a property change of the ink, and transferring the ink to a substrate, where the intermediate transfer member comprises a crosslinked siloxane composition containing the polymerization product of a mixture comprising from about 2 to about 12 alkoxysilane precursor materials, where at least one of the precursor materials is hydrophilic and at least one is hydrophobic.

Abstract: A method of preparing a reinforced fluoropolymer composite is presented, which includes reacting a surface of a nanocrystalline cellulose with a fluorinated electrophile to form a fluoro-functionalized nanocrystalline in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates, and contacting the fluoro-functionalized nanocrystalline cellulose with a fluoropolymer to form a fluoropolymer composite. Also presented is a method of preparing fluoro-functionalized nanocrystalline cellulose, including reacting a surface of a nanocrystalline cellulose with a fluorinated electrophile forming fluoro-functionalized nanocrystalline cellulose in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates, precipitating the fluoro-functionalized nanocrystalline cellulose and isolating and purifying the fluoro-functionalized nanocrystalline cellulose.

Abstract: The present teachings include a coating composition of a powder of fluorine containing particles, aerogel particles and poly(alkylene carbonate). A method of making a fuser member and the fuser member resulting therefrom is also provided.

Abstract: A reinforced fluoropolymer composite is presented, which includes a fluoropolymer and a fluoro-functionalized nanocrystalline cellulose in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates. The fluoro-functionalized nanocrystalline cellulose may be used to produce stable dispersions with fluoropolymers exhibiting enhanced adhesion between the nanocrystalline particles and fluoropolymer in a composite material, and decreased surface free energy of the cellulose surface.

Abstract: A method of preparing a reinforced fluoropolymer composite is presented, which includes reacting a surface of a nanocrystalline cellulose with a fluorinated electrophile to form a fluoro-functionalized nanocrystalline in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates, and contacting the fluoro-functionalized nanocrystalline cellulose with a fluoropolymer to form a fluoropolymer composite. Also presented is a method of preparing fluoro-functionalized nanocrystalline cellulose, including reacting a surface of a nanocrystalline cellulose with a fluorinated electrophile forming fluoro-functionalized nanocrystalline cellulose in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates, precipitating the fluoro-functionalized nanocrystalline cellulose and isolating and purifying the fluoro-functionalized nanocrystalline cellulose.