Abstract: Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below where Rx is cationic initiator residue; Ra is a polyolefin group; R1 and R2 are each, independently in each —(CR1R2) unit, H, alkyl, alkoxy, or alkylaryl; R3 and R4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.

Abstract: Bismaleimide (BMI) and cyanate ester (CE) thermosets were developed for use as high temperature encapsulants and adhesives. These materials must withstand prolonged exposures to large thermal gradients while maintaining good structural integrity, minimal mass losses and outgassing. Bismaleimide and cyanate ester thermosets exhibit superior thermal performance compared to most epoxies and can often tolerate long exposures to temperatures >200° C. without undergoing significant degradation. In addition to excellent stability at elevated temperatures, uncured resins can have good processing attributes, such as, low viscosities and long working times. In particular, specific combinations of BMI and CE resins can provide significantly better thermal performance than the current standard epoxy system in addition to having excellent processing capabilities.

Abstract: Nanocomposite anticorrosion coating can be achieved by depositing alternating, multilayers of a cross-linkable polymer and dispersed and aligned inorganic platelets followed by cross-linking of the cross-linkable polymer. The cross-linkable polymer can be an externally cross-linkable polymer that is cross-linked by diffusing a cross-linking agent into the deposited multilayer coating. Alternately, the cross-linkable polymer can be a functionalized cross-linkable polymer that is cross-linked by self-curing, thermal heat curing, or light (e.g., UV) following deposition of the multilayer coating.

Abstract: The invention is directed to a method of controlled conversion of thermosetting resins and additive manufacturing thereof by selective laser sintering. Partial curing of a thermosetting formulation can be used to increase the Tg of the resin and minimize the additional cure needed to cross-link a printed object. After printing, the partially cured material is finally cured via a slow temperature ramp maintained just below the material's evolving Tg.

Abstract: The invention is directed to a method of controlled conversion of thermosetting resins and additive manufacturing thereof by selective laser sintering. Partial curing of a thermosetting formulation can be used to increase the Tg of the resin and minimize the additional cure needed to cross-link a printed object. After printing, the partially cured material is finally cured via a slow temperature ramp maintained just below the material's evolving Tg.

Abstract: Nanocomposite anticorrosion coating can be achieved by depositing alternating, multilayers of a cross-linkable polymer and dispersed and aligned inorganic platelets followed by cross-linking of the cross-linkable polymer. The cross-linkable polymer can be an externally cross-linkable polymer that is cross-linked by diffusing a cross-linking agent into the deposited multilayer coating. Alternately, the cross-linkable polymer can be a functionalized cross-linkable polymer that is cross-linked by self-curing, thermal heat curing, or light (e.g., UV) following deposition of the multilayer coating.

Abstract: Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below where Rx is cationic initiator residue; Ra is a polyolefin group; R1 and R2 are each, independently in each —(CR1R2) unit, H, alkyl, alkoxy, or alkylaryl; R3 and R4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.

Abstract: Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below where Rx is cationic initiator residue; Ra is a polyolefin group; R1 and R2 are each, independently in each —(CR1R2) unit, H, alkyl, alkoxy, or alkylaryl; R3 and R4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.

Abstract: Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below where Rx is cationic initiator residue; Ra is a polyolefin group; R1 and R2 are each, independently in each —(CR1R2) unit, H, alkyl, alkoxy, or alkylaryl; R3 and R4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.