Abstract: Disclosed are MOFs containing nucleophilic transition metal hydroxide (M-OH) groups. In certain embodiments, these MOFs can include a plurality of metal ions, each coordinated with one or more hydroxide ligands and one or more backbone ligands. In certain embodiments, the MOFs can comprise Kuratowski cluster-based secondary building units (SBUs). These MOFs can exhibit excellent performance for low pressure CO2 capture via a CO2/HCO3? fixation mechanism in which cooperative inter-cluster hydrogen bonding interactions enhance CO2 capture performance. Also provided are methods of making MOFs including one or more metal hydroxide moieties, as well as methods of using these MOFs to capture an acidic gas (e.g., CO2, SO2, NO2, or acetylene).

Abstract: Disclosed are MOFs containing nucleophilic transition metal hydroxide (M-OH) groups. In certain embodiments, these MOFs can include a plurality of metal ions, each coordinated with one or more hydroxide ligands and one or more backbone ligands. In certain embodiments, the MOFs can comprise Kuratowski cluster-based secondary building units (SBUs). These MOFs can exhibit excellent performance for low pressure CO2 capture via a CO2/HCO3? fixation mechanism in which cooperative inter-cluster hydrogen bonding interactions enhance CO2 capture performance. Also provided are methods of making MOFs including one or more metal hydroxide moieties, as well as methods of using these MOFs to capture an acidic gas (e.g., CO2, SO2, NO2, or acetylene).