Abstract: A method for removing a metal from a carbonaceous electrode includes providing a regeneration solution that includes an acid, an oxidizing agent, or a combination thereof. The method further includes applying the regeneration solution to the carbonaceous electrode, and oxidizing the metal on the surface of the carbonaceous electrode. The method also includes collecting the oxidized metal in the regeneration solution.

Abstract: The present invention is directed to an electrochemical device for at least partially removing or reducing a target ionic species from an aqueous solution using faradic immobilization, the electrochemical device including at least one first electrode and at least one second electrode with different void fraction and surface area properties, due to differences in void fraction (also referred to as void ratio) of the at least one first and the at least one second electrode, water flows through an electrode with a high porosity, while the aqueous solution does not flow through an electrode with a low porosity. The asymmetry of the electrodes provides a desired voltage distribution across the device, which equates to a different voltage at each electrode, to control the speciation of the target ionic species at the anode and the cathode.

Abstract: The present invention is directed to an electrochemical device for at least partially removing or reducing a target ionic species from an aqueous solution using faradaic immobilization, the electrochemical device including at least one first electrode and at least one second electrode with different void fraction and surface area properties, due to differences in void fraction (also referred to as void ratio) of the at least one first and the at least one second electrode, water flows through an electrode with a high porosity, while the aqueous solution does not flow through an electrode with a low porosity. The asymmetry of the electrodes provides a desired voltage distribution across the device, which equates to a different voltage at each electrode, to control the speciation of the target ionic species at the anode and the cathode.

Abstract: Applicant's faradic porosity cell combines adsorption (physical and capacitive) and faradic immobilization of a target species by optimizing electrode porosity, applied E, and Pourbaix operating regions. The optimization parameters are (i) physical adsorption; (ii) capacitive adsorption; (iii) electrochemical pH modulation; (iv) electrochemical peroxide (H2O2) generation; (v) electrodeposition (e.g., electroplating, electrophoretic deposition); (vi) electrochemical oxidation or reduction; (vii) precipitation; (viii) pore mouth diameter profile, and (ix) electrode spacing, and (xi) flow-by vs. flow-through vs. carbon block cell design.

Abstract: The present invention relates to methods for improving carbon capture by providing particles within an amine solvent. The particles provide for increased turbulence at the interface between the counter-flowing gas and solvent, which allows for increased amine and carbamate salt diffusion between the liquid film and bulk.

Abstract: Applicant's faradic porosity cell combines adsorption (physical and capacitive) and faradic immobilization of a target species by optimizing electrode porosity, applied E, and Pourbaix operating regions. The optimization parameters are (i) physical adsorption; (ii) capacitive adsorption; (iii) electrochemical pH modulation; (iv) electrochemical peroxide (H2O2) generation; (v) electrodeposition (e.g., electroplating, electrophoretic deposition); (vi) electrochemical oxidation or reduction; (vii) precipitation; (viii) pore mouth diameter profile, and (ix) electrode spacing, and (xi) flow-by vs. flow-through vs. carbon block cell design.

Abstract: The present invention relates to a molten metal battery of liquid bismuth and liquid tin electrodes and a eutectic electrolyte. The electrodes may be coaxial and coplanar. The eutectic electrolyte may be in contact with a surface of each electrode. The eutectic electrolyte may comprise ZnCl2:KCl.

Abstract: Disclosed are activated carbon electrodes fabricated according to a “pore mouth diameter mixture profile” that is optimized for a given electrochemical application. In a given pore mouth diameter mixture profile, the pore mouth diameter and conductivity of activated carbon are tightly controlled and provide unexpected long-term charging/discharging (aka “cycling”) performance. A given “pore mouth diameter mixture profile” optimizes a mixture of pore mouth diameters for a given electrochemical application, such as energy storage, desalination, deionization, hydrolysis, and dialysis, inter alia.

Abstract: The present invention relates to methods for improving carbon capture using entrained catalytic-particles within an amine solvent. The particles are functionalized and appended with a CO2 hydration catalyst to enhance the kinetics of CO2 hydration and improve overall mass transfer of CO2 from an acid gas.

Abstract: A method of increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

Abstract: Disclosed are activated carbon electrodes fabricated according to a “pore mouth diameter mixture profile” that is optimized for a given electrochemical application. In a given pore mouth diameter mixture profile, the pore mouth diameter and conductivity of activated carbon are tightly controlled and provide unexpected long-term charging/discharging (aka “cycling”) performance. A given “pore mouth diameter mixture profile” optimizes a mixture of pore mouth diameters for a given electrochemical application, such as energy storage, desalination, deionization, hydrolysis, and dialysis, inter alia.

Abstract: A method and catalysts for increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

Abstract: The present invention relates to a method and system for removing nitrosamines from amine-based carbon capture systems by circulating waterwash through a filter of activated carbon. Nitrosamine emission control strategies are critical for the success of amine-based carbon capture as the technology approaches industrial-scale deployment. Waterwash systems are used to control volatile and aerosol emissions, including nitrosamines, from carbon capture plants, but it is still necessary to remove or destroy nitrosamines in the circulating waterwash to prevent their subsequent emissions into the environment. The circulation of the water over a sorbent bed of activated carbon provides a cost-effective approach to selectively remove nitrosamines from the waterwash effluent to reduce the environmental impact associated with amine-based carbon capture.

Abstract: The present invention relates to methods for improving carbon capture using entrained catalytic-particles within an amine solvent. The particles are functionalized and appended with a CO2 hydration catalyst to enhance the kinetics of CO2 hydration and improve overall mass transfer of CO2 from an acid gas.

Abstract: The present invention relates to methods for improving carbon capture by providing particles within an amine solvent. The particles provide for increased turbulence at the interface between the counter-flowing gas and solvent, which allows for increased amine and carbamate salt diffusion between the liquid film and bulk.

Abstract: The present invention relates to a molten metal battery of liquid bismuth and liquid tin electrodes and a eutectic electrolyte. The electrodes may be coaxial and coplanar. The eutectic electrolyte may be in contact with a surface of each electrode. The eutectic electrolyte may comprise ZnCl2:KCl.

Abstract: A method of increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

Abstract: A solvent for removal of an acid gas from a fluid stream includes a promoter amine with a pKa of between 6.5 and 10.5 and a tertiary amine with a pKa of between 8.5 and 10.5.

Abstract: A method of increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

Abstract: A novel transition metal trimer compound/catalyst is disclosed. A method of increasing the overall mass transfer rate of acid gas scrubbing solvents utilizing that catalyst is also provided.