Abstract: A water-based barrier coating composition is disclosed that has improved barrier performance and enhanced stability. The water-based coating composition comprises a polymeric binder and an amine stabilizer, wherein the pH of the composition is equal to or greater than the pKa of the amine stabilizer. When desired, the disclosed coating composition may further include standard low-cost fillers, layered fillers capable of being at least partially exfoliated, nanoparticle fillers, or mixtures thereof. A multilayer product comprising a layer of the disclosed water-based coating composition is also disclosed that has enhanced oxygen barrier performance.

Abstract: A pigment-based, ink jet ink composition is disclosed which is characterized by water and accent marker resistance and by high optical density and acuity of the print. Such improvements are achieved (without loss of print quality, jetting properties, storage stability, reliability, and drying time) by adding to the ink a polymer comprised of the polymerizable half-ester of an aliphatic, nonionic surfactant, and a monomer, preferably chosen from the group of styrene, acrylic acid, and butyl acrylate.

Abstract: A process for emulsion polymerization to form a latex having a particle size greater than about 0.5 micrometers by charging to a reaction vessel under agitation a reaction mixture including water, emulsifiers at an initial concentration slightly greater than or equal to the critical micelle concentration, a protective colloid, ethylenically unsaturated monomers, and an ionically balanced combination of an anionic and a cationic water soluble free radical initiator or a nonionic initiator; reacting the mixture to form an emulsion of polymerized monomer; and adding additional monomer, emulsifier, and protective colloid and a water soluble chain transfer agent to the reactor while continuing to agitate the mixture under conditions such that the emulsifier concentration does not exceed that at which new polymeric nuclei are formed.